N,N-dimethyl-1-(naphthalen-1-yl)methanamine
- Product Name
- N,N-dimethyl-1-(naphthalen-1-yl)methanamine
- CAS No.
- 16413-71-1
- Chemical Name
- N,N-dimethyl-1-(naphthalen-1-yl)methanamine
- Synonyms
- Naftifine Impurity;Naftifine Impurity 6;Naphthotifen Impurity 9;1-[(Dimethylamino)methyl]naphthalene;1-Naphthalenemethanamine, N,N-dimethyl-;N,N-dimethyl-1-(naphthalen-1-yl)methanamine
- CBNumber
- CB13049597
- Molecular Formula
- C13H15N
- Formula Weight
- 185.26
- MOL File
- 16413-71-1.mol
N,N-dimethyl-1-(naphthalen-1-yl)methanamine Property
- Boiling point:
- 148-152 °C(Press: 16 Torr)
- Density
- 1.028±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- pka
- 8+-.0.28(Predicted)
Safety
- HS Code
- 2921490090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
N-Bromosuccinimide Price
- Product number
- D458050
- Product name
- N,N-Dimethyl-1-(naphthalen-1-yl)methanamine
- Packaging
- 50mg
- Price
- $55
- Updated
- 2021/12/16
- Product number
- A197368
- Product name
- N,N-Dimethyl-1-(naphthalen-1-yl)methanamine
- Purity
- 97%
- Packaging
- 250mg
- Price
- $56
- Updated
- 2021/12/16
- Product number
- A197368
- Product name
- N,N-Dimethyl-1-(naphthalen-1-yl)methanamine
- Purity
- 97%
- Packaging
- 1g
- Price
- $112
- Updated
- 2021/12/16
- Product number
- CM233477
- Product name
- N,N-Dimethyl-1-(naphthalen-1-yl)methanamine
- Purity
- 97%
- Packaging
- 1g
- Price
- $204
- Updated
- 2021/12/16
- Product number
- 16413711
- Product name
- N,N-Dimethyl-1-(naphthalen-1-yl)methanamine
- Packaging
- 1g
- Price
- $210
- Updated
- 2021/12/16
N,N-dimethyl-1-(naphthalen-1-yl)methanamine Chemical Properties,Usage,Production
Uses
N,N-Dimethyl-1-(naphthalen-1-yl)methanamine is a useful reactant in organic synthesis.
Synthesis Reference(s)
Tetrahedron Letters, 25, p. 2535, 1984 DOI: 10.1016/S0040-4039(01)81224-7
Synthesis
68-12-2
86-52-2
16413-71-1
Sodium hydroxide (3.0 eq.), NHC-Pd(II)-Im complex 1 (1.0 mol%), water (1.0 mL), 1-chloromethylnaphthalene (0.8 mmol), and N,N-dimethylformamide (2.0 eq.) were sequentially added to the Schlenk reaction tube under nitrogen protection. The reaction mixture was stirred at 50 °C for 3 hours. After completion of the reaction, it was cooled to room temperature and the reaction mixture was extracted with ethyl acetate, the extract was washed with saturated brine and dried with anhydrous sodium sulfate. The solvent was removed by concentration under reduced pressure and the resulting crude product was purified by rapid column chromatography on silica gel (eluent: petroleum ether/ethyl acetate=5:1) to afford the pure N,N-dimethyl-1-(naphthalen-1-yl)methylamine (4t). The product was a colorless liquid with the following NMR hydrogen spectrum (300 MHz, CDCl3) data: δ 8.24 (d, J = 7.8 Hz, 1H), 7.83-7.75 (m, 2H), 7.51-7.36 (m, 4H), 3.79 (s, 2H), 2.27 (s, 6H); NMR carbon spectrum (75 MHz, CDCl3) data are as follows: δ 134.6, 133.8, 132.4, 128.4, 127.9, 127.4, 125.9, 125.5, 125.0, 124.4, 62.4, 45.6.
References
[1] Journal of Chemical Research, 2013, vol. 37, # 10, p. 611 - 614
[2] Tetrahedron, 2014, vol. 70, # 4, p. 880 - 885
N,N-dimethyl-1-(naphthalen-1-yl)methanamine Preparation Products And Raw materials
Raw materials
Preparation Products
N,N-dimethyl-1-(naphthalen-1-yl)methanamine Suppliers
- Tel
- 400-6009262 15618770481
- Fax
- 021-64823266
- yhx@titansci.com
- Country
- China
- ProdList
- 14101
- Advantage
- 59
- Tel
- 13524892556
- Fax
- (86) 21 51969655， QQ： 263541193
- sales-cn@potentpharm.com
- Country
- China
- ProdList
- 1011
- Advantage
- 55
- Tel
- 0371-88888888 272369594
- Fax
- QQ:272369594
- 2723695949@qq.com
- Country
- China
- ProdList
- 4981
- Advantage
- 50
- Tel
- 18210788515; 18210788515
- Fax
- 18210788515
- zhuzixin999@163.c0m
- Country
- China
- ProdList
- 4995
- Advantage
- 55
- Tel
- 025-66061636 19370895928
- Fax
- (3)02557626880
- qqyang@aikonchem.com
- Country
- China
- ProdList
- 15813
- Advantage
- 58
- Tel
- 18689416704
- Fax
- QQ 3008233717
- angelng@dmstandards.com
- Country
- China
- ProdList
- 9927
- Advantage
- 12
- Tel
- 400-820-6829
- sales@mitachieve.com
- Country
- China
- ProdList
- 8860
- Advantage
- 58
- Tel
- 021-58432009 400-005-6266
- Fax
- 021-58436166
- marketing@energy-chemical.com
- Country
- China
- ProdList
- 44918
- Advantage
- 58
- Tel
- 400-6005915
- sales@picasso-e.com
- Country
- China
- ProdList
- 39653
- Advantage
- 58
- Tel
- 531-87153728 13805401165
- xufeng192@126.com
- Country
- China
- ProdList
- 5857
- Advantage
- 58
View Lastest Price from N,N-dimethyl-1-(naphthalen-1-yl)methanamine manufacturers
- Product
- Naftifine Impurity 16413-71-1
- Price
- US $0.00-0.00/mg
- Min. Order
- 10mg
- Purity
- 95
- Supply Ability
- 1000000
- Release date
- 2025-02-14