Application Preparation
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METHYL NONAFLUOROBUTYL ETHER

Application Preparation
Product Name
METHYL NONAFLUOROBUTYL ETHER
CAS No.
163702-07-6
Chemical Name
METHYL NONAFLUOROBUTYL ETHER
Synonyms
HFE-7100;METHOXYPERFLUOROBUTANE;METHYL PERFLUOROBUTYL ETHER;3m Novec 7100;METHOXYNONAFLUOROBUTANE;Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxy-;Novec HFE 730;Methoxyperfluoro-n-butane;methoxy nonafluorobutanes;1-(METHOXY)NONAFLUOROBUTANE
CBNumber
CB1328596
Molecular Formula
C5H3F9O
Formula Weight
250.06
MOL File
163702-07-6.mol
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METHYL NONAFLUOROBUTYL ETHER Property

Melting point:
-135 °C (lit.)
Boiling point:
60 °C (lit.)
Density 
1.529 g/mL at 20 °C 1.52 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.3(lit.)
Flash point:
-18℃
storage temp. 
2-8°C
BRN 
8768491
InChI
InChI=1S/C5H3F9O/c1-15-5(13,14)3(8,9)2(6,7)4(10,11)12/h1H3
InChIKey
OKIYQFLILPKULA-UHFFFAOYSA-N
SMILES
C(F)(F)(F)C(F)(F)C(F)(F)C(F)(F)OC
LogP
4.670 (est)
CAS DataBase Reference
163702-07-6(CAS DataBase Reference)
EPA Substance Registry System
Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxy- (163702-07-6)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
23-24/25
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29091990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H332Harmful if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
464309
Product name
Methoxyperfluorobutane
Purity
99%, mixture of n- and iso-butyl isomers
Packaging
100ml
Price
$95.8
Updated
2024/03/01
Sigma-Aldrich
Product number
464309
Product name
Methoxyperfluorobutane
Purity
99%, mixture of n- and iso-butyl isomers
Packaging
500ml
Price
$332
Updated
2024/03/01
TCI Chemical
Product number
M1345
Product name
Methyl Nonafluorobutyl Ether
Purity
>98.0%(GC)
Packaging
25g
Price
$33
Updated
2021/12/16
TCI Chemical
Product number
M1345
Product name
Methyl Nonafluorobutyl Ether
Purity
>98.0%(GC)
Packaging
500g
Price
$233
Updated
2021/12/16
Sigma-Aldrich
Product number
65139
Product name
Nonafluorobutyl methyl ether
Purity
puriss., ≥99.0% (total assay of isomers, GC)
Packaging
250ml
Price
$238
Updated
2024/03/01
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METHYL NONAFLUOROBUTYL ETHER Chemical Properties,Usage,Production

Application

Methyl Perfluorobutyl Ether is a clear, colorless, low-odor, non-toxic, non-corrosive, non-flammable liquid substance with a chemical formula of C5H3F9O and a molecular weight of 250.06. Since it has low flammability, relatively low vapor pressure, low heat of vaporization, and low surface tension, it is considered to replace the chlorine-containing cleaning solvents such as 1,1,1-trichloroethane, CFC-113 (CF2ClCFCl2), and HCFC-141b (CH3CFCl2). Besides, it is a fluorinated ether solvent that is very compatible with many other ingredients, and is thought to have good sliding properties and serve as a good solvent in oil-based formulas.

Preparation

Because methyl perfluorobutyl ether contains perfluoroalkyl group (Rf) on one side and alkyl group (R) on the other side of ether linkage, it cannot be synthesized by selective partial fluorination of its hydrocarbon precursors. Instead, they may be prepared by coupling reactions of two reactants having Rf and R, coupling reactions of two reactants having Rf and R, respectively.

Chemical Properties

Clear colorless liquid

Uses

Nonafluorobutyl methyl ether (Methyl Nonafluorobutyl Ether, MFE) may be used to compose mixed-solvent electrolytes. Flash point, conductivity and NMR spectra of these solvent mixtures have been investigated.

Uses

Methoxyperfluorobutane can be used as a solvent:

  • In the synthesis of various aryl fluoride derivatives via electrophilic fluorination of aryl and heteroaryl Grignard reagents.
  • In grafting of fluorinated diblock copolymers onto silica particles.

General Description

consists of two inseparable isomers (CF3)2CFCF2OCH3 and CF3(CF2)3OCH3 with almost identical properties

METHYL NONAFLUOROBUTYL ETHER Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL NONAFLUOROBUTYL ETHER Suppliers

Apollo Scientific Ltd.
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United Kingdom
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Leancare Ltd.
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Fisher Scientific Uk Ltd.
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Cenik Chemicals
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Manchester Organics
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Biosynth Carbosynth
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Key Organics Ltd.
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VWR International
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View Lastest Price from METHYL NONAFLUOROBUTYL ETHER manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
Methyl Nonafluorobutyl Ether 163702-07-6
Price
US $55.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 tons
Release date
2024-11-21
Shenzhen Huayi Brothers Technology Co.,Ltd
Product
Methyl nonafluorobutyl ether3M7100HFE 7100;Novec 7100;Novec HFE 730 163702-07-6
Price
US $0.00-0.00/KG
Min. Order
25KG
Purity
99.99%
Supply Ability
20 TONS
Release date
2024-11-16
Hebei Weibang Biotechnology Co., Ltd
Product
METHYL NONAFLUOROBUTYL ETHER 163702-07-6
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100 mt
Release date
2024-11-13

163702-07-6, METHYL NONAFLUOROBUTYL ETHERRelated Search:


  • 1H,1H,1H-NONAFLUORO-2-OXAHEXANE
  • 1-(METHOXY)NONAFLUOROBUTANE
  • METHYL NONAFLUOROBUTYL ETHER
  • METHYL PERFLUOROBUTYL ETHER
  • METHOXYPERFLUOROBUTANE
  • Methoxyperfluoro-n-butane
  • 2-bromo-1-[4-(2-bromo-1-oxopropyl)-1-piperazinyl]-1-propanone
  • Methoxyperfluorobutane 99%, mixture of n- and iso-butyl isomers
  • Methyl nonafluorobutyl ether (NOVEC 7100
  • Methyl Perfluorobutyl Ether (NOVEC 7100
  • 3m Novec 7100
  • Methyl 1,1,2,2,3,3,4,4,4-nonafluorobutyl ether
  • Methyl Perfluorobutyl Ether Nonafluorobutyl Methyl Ether Perfluorobutyl Methyl Ether
  • HFE-7100
  • PERFLUOROBUTYL METHYL ETHER
  • NONAFLUOROBUTYL METHYL ETHER
  • 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxy-butan
  • Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxy-
  • 1,1,1,2,2,3,3,4,4-NONAFLUORO-4-METHOXY-BUTANE
  • 1-(Methoxy)nonafluorobutane Methyl nonafluorobutyl ether
  • methoxy nonafluorobutanes
  • HFE-7100, Methoxynonafluorobutane, Methoxyperfluorobutane, Nonafluorobutyl methyl ether, Nonafluoromethoxybutane
  • METHOXYNONAFLUOROBUTANE
  • MethylNonafluorobutylEther&gt
  • Methyl Nonafluorobutyl Ether (mixture of isomers)
  • Butane,1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxy-,98%
  • METHYL NONAFLUOROBUTYL ETHER ISO 9001:2015 REACH
  • 3M-7100 METHYL NONAFLUOROBUTYL ETHER
  • Equivalent replacement 3M HFE-7100
  • Methyl nonafluorobutyl ether 3M7100HFE 7100
  • Novec HFE 730
  • 163702-07-6
  • CH3OCF2RRCF2CF2CF3orCFCF32