Sodium fluoromethanesulfinate
- Product Name
- Sodium fluoromethanesulfinate
- CAS No.
- 1661836-10-7
- Chemical Name
- Sodium fluoromethanesulfinate
- Synonyms
- fluoromethanesulfinate;Sodiumfluoromethanesulfinate;fluoromethanesulfinic acid, sodium salt;Methanesulfinic acid, 1-fluoro-, sodium salt;Methanesulfinic acid, 1,1-difluoro-, sodium salt (1:1)
- CBNumber
- CB13368795
- Molecular Formula
- CH2FNaO2S
- Formula Weight
- 120.0785532
- MOL File
- 1661836-10-7.mol
Sodium fluoromethanesulfinate Property
- storage temp.
- 2-8°C, stored under nitrogen
- Appearance
- Off-white to light yellow Solid
- InChI
- InChI=1S/CH3FO2S.Na/c2-1-5(3)4;/h1H2,(H,3,4);/q;+1/p-1
- InChIKey
- VWVSSKREIDWEJT-UHFFFAOYSA-M
- SMILES
- [Na+].C(F)S([O-])=O
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- ING0016067
- Product name
- SODIUM FLUOROMETHANESULFINATE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $456.68
- Updated
- 2021/12/16
Sodium fluoromethanesulfinate Chemical Properties,Usage,Production
Uses
Sodium fluoromethanesulfinate is used as efficient radical fluoroalkylating reagents,it is able to react with conjugated N-arylsulfonated amides to yield the desired fluoroalkylamides.
Reactions
Ref. 1) He, Z.; Tan, P.; Ni, C.; Hu, J. Org. Lett. 2015, 17, 1838 –1841. (The invention of HCF2SO2Na and H2CFSO2Na as radical fluoroalkylation reagents)
2) Dai, P.; Yu, X.; Teng, P.; Zhang, W.-H.; Deng, C. Org. Lett. 2018, 20, 6901-6905.
3) Zhang, W. et al. Nat. Commun. 2020, 11, art. no. 638. (HCF2SO2Na was referred to as Hu’s reagent)
Sodium fluoromethanesulfinate Preparation Products And Raw materials
Raw materials
Preparation Products
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