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PHENYLSELENYL BROMIDE

Product Name
PHENYLSELENYL BROMIDE
CAS No.
34837-55-3
Chemical Name
PHENYLSELENYL BROMIDE
Synonyms
bromoselenobenzene;Phenylbromoselenium;Phenylbromo selenide;Phenylseleno bromide;PHENYLSELENYL BROMIDE;BENZENESELENYL BROMIDE;Phenylselenium bromide;PHENYLSELENENYL BROMIDE;phenylselenohypobromite;BENZENESELENENYL BROMIDE
CBNumber
CB1360840
Molecular Formula
C6H5BrSe
Formula Weight
235.97
MOL File
34837-55-3.mol
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PHENYLSELENYL BROMIDE Property

Melting point:
58-62 °C (lit.)
Boiling point:
107-108 °C/15 mmHg (lit.)
Flash point:
107-108°C/15mm
storage temp. 
2-8°C
solubility 
Soluble in toluene, very faint turbidity.
form 
solid
color 
Orange to Brown to Dark purple
Odor
unpleasant smell.
Sensitive 
Moisture Sensitive
BRN 
2039772
Exposure limits
ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3
InChI
InChI=1S/C6H5BrSe/c7-8-6-4-2-1-3-5-6/h1-5H
InChIKey
LCEFEIBEOBPPSJ-UHFFFAOYSA-N
SMILES
[Se](C1=CC=CC=C1)Br
CAS DataBase Reference
34837-55-3(CAS DataBase Reference)
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Safety

Hazard Codes 
T,N
Risk Statements 
23/25-33-50/53
Safety Statements 
20/21-28-45-60-61
RIDADR 
UN 2928 6.1/PG 2
WGK Germany 
3
10-21
HazardClass 
6.1
PackingGroup 
II
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H290May be corrosive to metals

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
243965
Product name
Phenylselenyl bromide
Purity
98%
Packaging
5g
Price
$103.55
Updated
2025/07/31
Sigma-Aldrich
Product number
243965
Product name
Phenylselenyl bromide
Purity
98%
Packaging
25g
Price
$295
Updated
2025/07/31
TCI Chemical
Product number
P1322
Product name
Phenylselenenyl Bromide
Purity
>97.0%(T)
Packaging
5g
Price
$133
Updated
2025/07/31
TCI Chemical
Product number
P1322
Product name
Phenylselenenyl Bromide
Purity
>97.0%(T)
Packaging
25g
Price
$457
Updated
2025/07/31
TRC
Product number
P336825
Product name
Phenylselenyl bromide
Packaging
10g
Price
$415
Updated
2021/12/16
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PHENYLSELENYL BROMIDE Chemical Properties,Usage,Production

Chemical Properties

dark brownish to black crystals

Uses

Employed in the synthesis of enones by selenenylation of α-cyano ketones with lithium naphthalenide. Phenylselenyl bromide was used in the preparation of exo-2-methyl-7-phenylselenyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione and endo-2-methyl-7-phenylselanyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione.

Synthesis

Phenylselenyl Bromide can be quantitatively prepared in situ by treatment of Diphenyl Diselenide with an equimolar amount of Bromine.

Purification Methods

Distil it in a vacuum, recrystallise it from pet ether, CHCl3 (EtOH free), or Et2O (cooling mixture) to give dark red or orange crystals. These sublime at 25o/0.001mm [Behaghel et al. Chem Ber 65 815 1932, Pitteloud & Petrzilka Helv Chim Acta 62 1319 1979]. [Beilstein 6 III 1111.] HIGHLY TOXIC.

PHENYLSELENYL BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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PHENYLSELENYL BROMIDE Suppliers

Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd
Tel
0431-80514535 19917294565
Email
et@chemextension.com
Country
China
ProdList
5061
Advantage
58
Chongqing Botao Biotechnology Co., LTD
Tel
15223382610
Email
danny@chemdad.com
Country
China
ProdList
2032
Advantage
58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14101
Advantage
59
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
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View Lastest Price from PHENYLSELENYL BROMIDE manufacturers

Career Henan Chemical Co
Product
Phenylselenyl bromide 34837-55-3
Price
US $9.80/KG
Min. Order
1KG
Purity
≥98%
Supply Ability
20 tons
Release date
2020-01-09

34837-55-3, PHENYLSELENYL BROMIDERelated Search:


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  • Selenium Compounds
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