PHENYLSELENYL BROMIDE

Product Name: PHENYLSELENYL BROMIDE
CAS No.: 34837-55-3
Chemical Name: PHENYLSELENYL BROMIDE
Synonyms: bromoselenobenzene;Phenylbromoselenium;Phenylbromo selenide;Phenylseleno bromide;PHENYLSELENYL BROMIDE;BENZENESELENYL BROMIDE;Phenylselenium bromide;PHENYLSELENENYL BROMIDE;phenylselenohypobromite;BENZENESELENENYL BROMIDE
CBNumber: CB1360840
Molecular Formula: C6H5BrSe
Formula Weight: 235.97
MOL File: 34837-55-3.mol

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PHENYLSELENYL BROMIDE Property

Melting point:: 58-62 °C (lit.)
Boiling point:: 107-108 °C/15 mmHg (lit.)
Flash point:: 107-108°C/15mm
storage temp.: 2-8°C
solubility: Soluble in toluene, very faint turbidity.
form: solid
color: Orange to Brown to Dark purple
Odor: unpleasant smell.
Sensitive: Moisture Sensitive
BRN: 2039772
Exposure limits: ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3
InChIKey: LCEFEIBEOBPPSJ-UHFFFAOYSA-N
CAS DataBase Reference: 34837-55-3(CAS DataBase Reference)

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Safety

Hazard Codes: T,N
Risk Statements: 23/25-33-50/53
Safety Statements: 20/21-28-45-60-61
RIDADR: UN 2928 6.1/PG 2
WGK Germany: 3
F: 10-21
HazardClass: 6.1
PackingGroup: II
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H290May be corrosive to metals

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 243965
Product name: Phenylselenyl bromide
Purity: 98%
Packaging: 5g
Price: $106
Updated: 2024/03/01

Sigma-Aldrich

Product number: 243965
Product name: Phenylselenyl bromide
Purity: 98%
Packaging: 25g
Price: $286
Updated: 2024/03/01

TCI Chemical

Product number: P1322
Product name: Phenylselenenyl Bromide
Purity: >97.0%(T)
Packaging: 5g
Price: $126
Updated: 2024/03/01

TCI Chemical

Product number: P1322
Product name: Phenylselenenyl Bromide
Purity: >97.0%(T)
Packaging: 25g
Price: $432
Updated: 2024/03/01

Alfa Aesar

Product number: A11906
Product name: Phenylselenenyl bromide, 98%
Packaging: 1g
Price: $18.65
Updated: 2024/03/01

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PHENYLSELENYL BROMIDE Chemical Properties,Usage,Production

Chemical Properties

dark brownish to black crystals

Uses

Employed in the synthesis of enones by selenenylation of α-cyano ketones with lithium naphthalenide. Phenylselenyl bromide was used in the preparation of exo-2-methyl-7-phenylselenyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione and endo-2-methyl-7-phenylselanyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione.

Synthesis

Phenylselenyl Bromide can be quantitatively prepared in situ by treatment of Diphenyl Diselenide with an equimolar amount of Bromine.

Purification Methods

Distil it in a vacuum, recrystallise it from pet ether, CHCl3 (EtOH free), or Et2O (cooling mixture) to give dark red or orange crystals. These sublime at 25o/0.001mm [Behaghel et al. Chem Ber 65 815 1932, Pitteloud & Petrzilka Helv Chim Acta 62 1319 1979]. [Beilstein 6 III 1111.] HIGHLY TOXIC.

PHENYLSELENYL BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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PHENYLSELENYL BROMIDE Suppliers

Americas 1 Belgium 2 China 67 Europe 1 Germany 2 India 5 Japan 2 Switzerland 1 United Kingdom 4 United States 12 Global 97

Accela ChemBio Inc.

Tel: +1-858-6993322
Fax: (+1)-858-876-1948
Email: info@accelachem.com
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Aladdin Scientific

Tel: +1-+1(833)-552-7181
Email: sales@aladdinsci.com
Country: United States
ProdList: 52924
Advantage: 58

United States Biological

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Riedel-de Haen AG

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TCI America

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ProdList: 6909
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Alfa Aesar

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ProdList: 6814
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HONEST JOY HOLDINGS LIMITED

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Advance Scientific & Chemical

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Chemiplus Corporation

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Spectrum Chemicals & Laboratory Products

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ProdList: 6699
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Prime Organics, Inc.

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Aithaca Chemical Corp.

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Country: United States
ProdList: 1684
Advantage: 30

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View Lastest Price from PHENYLSELENYL BROMIDE manufacturers

Career Henan Chemical Co

Product: Phenylselenyl bromide 34837-55-3
Price: US $9.80/KG
Min. Order: 1KG
Purity: ≥98%
Supply Ability: 20 tons
Release date: 2020-01-09

34837-55-3, PHENYLSELENYL BROMIDERelated Search:

MOLYBDENUM(V) CHLORIDE Tetramethylammonium chloride Selenium Benzene

Phenylselenenylbromide,98%

Benzeneselenenic acid bromide

Phenylbromo selenide

Phenylbromoselenium

Phenylseleno bromide

Phenylselenyl bromide,98%

Benzeneselenenyl bromide, Benzeneselenyl bromide

Phenylselenyl bromide,Benzeneselenenyl bromide, Benzeneselenyl bromide

Phenylselenyl broMide, 98% 25GR

Phenylselenyl broMide, 98% 5GR

phenyl hypobroMoselenoite

Phenylselenyl broMide 98%

BENZENESELENENYL BROMIDE

BENZENESELENYL BROMIDE

PHENYLSELENENYL BROMIDE

PHENYLSELENYL BROMIDE

bromoselenobenzene

Phenylselenium bromide

PhenylselenenylBromide&gt

phenylselenohypobromite

34837-55-3

C6H5BrSe

C6H5SeBr

Organic Building Blocks

Building Blocks

Selenium Compounds

Classes of Metal Compounds

Se (Selenium) Compounds

Semimetal Compounds

Classes of Metal Compounds

Se (Selenium) Compounds

Semimetal Compounds