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ABIETIC ACID

Product Name
ABIETIC ACID
CAS No.
514-10-3
Chemical Name
ABIETIC ACID
Synonyms
Abietate;ROSIN ACID;ABIETIC ACID, TECH., 70%;OdoM;NSC 25149;abieticaci;SYLVIC ACID;ABIETIC ACID;abietinicacid;l-abieticacid
CBNumber
CB1381555
Molecular Formula
C20H30O2
Formula Weight
302.45
MOL File
514-10-3.mol
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ABIETIC ACID Property

Melting point:
139-142 °C (lit.) 150-165 °C
Boiling point:
440℃
alpha 
D24 -106° (c = 1 in abs alc)
Density 
1.06
refractive index 
1.4800 (estimate)
Flash point:
208℃
storage temp. 
2-8°C
solubility 
Soluble in alcohols, acetone and ethers
pka
pK1:7.62 (25°C)
form 
Crystals and Chunks
color 
Yellow-brownish
Odor
at 100.00?%. mild acetic
optical activity
[α]20/D 85±10°, c = 1% in ethanol
Water Solubility 
Soluble in acetone, petroleum ether, diethyl ether and ethanol. Insoluble in water.
Sensitive 
Air Sensitive
Merck 
14,7
BRN 
2221451
Exposure limits
NIOSH: TWA 0.1 mg/m3
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
LogP
6.460
CAS DataBase Reference
514-10-3(CAS DataBase Reference)
EPA Substance Registry System
Abietic acid (514-10-3)
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Safety

Hazard Codes 
Xi,N
Risk Statements 
36/37/38-50-50/53
Safety Statements 
26-36
RIDADR 
UN 3077 9/PG 3
WGK Germany 
3
RTECS 
TP8580000
10-23
TSCA 
Yes
HazardClass 
9
PackingGroup 
III
HS Code 
29162090
Toxicity
LD50 ivn-mus: 180 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H400Very toxic to aquatic life

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P273Avoid release to the environment.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
00010
Product name
Abietic acid
Purity
technical, ~75% (GC)
Packaging
25g
Price
$97.6
Updated
2024/03/01
Sigma-Aldrich
Product number
00010
Product name
Abietic acid
Purity
technical, ~75% (GC)
Packaging
100g
Price
$171
Updated
2024/03/01
TCI Chemical
Product number
A0001
Product name
Abietic Acid
Purity
>80.0%(GC)
Packaging
25g
Price
$52
Updated
2024/03/01
TCI Chemical
Product number
A0001
Product name
Abietic Acid
Purity
>80.0%(GC)
Packaging
500g
Price
$363
Updated
2024/03/01
Alfa Aesar
Product number
042582
Product name
Abietic acid, 90+%
Packaging
250mg
Price
$100
Updated
2024/03/01
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ABIETIC ACID Chemical Properties,Usage,Production

Description

Abietic acid is probably a major allergen of colophony, by way of oxidation products. Its detection in a material indicates that allergenic components of colophony are present.

Chemical Properties

yellow resinous powder, crystals or chunks

Uses

Abietic Acid is the primary component of resin acid found commonly in rosin. Abietic Acid exhibited potent testosterone 5α-reductase inhibitory activity in vitro.

Uses

manufacture of esters (ester gums), e.g., methyl ester, vinyl and glyceryl esters for use in lacquers and varnishes; manufacture of "metal resinates", soaps, plastics, and paper sizes; assists growth of lactic and butyric acid bacteria; component in tall oil used as deodorizing agent in cooling fluids; major component of rosin used in the production of varnishes, printing inks, paper, soldering fluxes, greases, cutting fluids, glue tackifiers, adhesives, surface coatings, polish, shoes, insulations, waxes, cosmetics (mascara, rouge, eye shadow), topical medicaments, violin bow rosin, day, athletic grip aid, pine oil deansers; component in dental impression materials and periodontal packings

Uses

Abietic acid is used to make ester gums in lacquers, varnishes and soaps. It is also used in metal resonates and plastics. Further, it is utilized in musical instruments to make them less slippery. It acts as a precursor to natural product synthesis. In addition to this, it is used to depackage integrated circuits from their epoxy coatings.

Definition

ChEBI: An abietane diterpenoid that is abieta-7,13-diene substituted by a carboxy group at position 18.

General Description

Yellowish resinous powder.

Reactivity Profile

ABIETIC ACID reacts exothermically with bases, both organic (for example, the amines) and inorganic. Can react with active metals to form gaseous hydrogen and a metal salt. Such reactions are slow if the solid acid remains dry. Can react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slow for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions.

Health Hazard

ACUTE/CHRONIC HAZARDS: Slight fire hazard, slight explosive hazard as dust. Low toxicity.

Fire Hazard

Combustible.

Contact allergens

Abietic acid is probably the major allergen of colophony, along with dehydroabietic acid, by way of oxidation products. Its detection in a material indicates that allergenic components of colophony are present

Safety Profile

Poison by intravenous route.Combustible. Slight explosion hazard as dust. Whenheated to decomposition it emits acrid smoke andirritating fumes.

Purification Methods

Filter, dry it in a vacuum (over KOH or CaSO4) and store it in an O2-free atmosphere. It can also be purified via the anhydride, tritylabietate and the potassium, piperidine and brucine salts. max : nm(log ): 2343(4.3), 241(4.4), 2505(4.2), 235(4.34) and 240(4.36) in Et. [Harris & Sanderson Org Synth Coll Vol IV 1 1963, J Am Chem Soc 35 3736 1949, Lambard & Frey Bull Soc Chim Fr 1194 1948, Buchbauer et al. Monatsh Chem 116 1345 1985.] [Beilstein 9 IV 2175.]

ABIETIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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ABIETIC ACID Suppliers

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View Lastest Price from ABIETIC ACID manufacturers

Shanghai Standard Technology Co., Ltd.
Product
Abietic Acid 514-10-3
Price
US $0.00/mg
Min. Order
20mg
Purity
≥98%(HPLC)
Supply Ability
100 g
Release date
2020-08-21
Zhuozhou Wenxi import and Export Co., Ltd
Product
ABIETIC ACID 514-10-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
ABIETIC ACID 514-10-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09

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