2,2'-BITHIOPHENE

ChemicalBook > CAS DataBase List > 2,2'-BITHIOPHENE

Product Name: 2,2'-BITHIOPHENE
CAS No.: 492-97-7
Chemical Name: 2,2'-BITHIOPHENE
Synonyms: Dithienyl;2T;2TH;S1020;2,2-DITHIENYL;2,2’-dlthienyl;2,2'-BITHIENYL;2,2'-DITHIENYL;2,2'-Bithienyl;2,2'-Bithiophen
CBNumber: CB1388493
Molecular Formula: C8H6S2
Formula Weight: 166.26
MOL File: 492-97-7.mol

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2,2'-BITHIOPHENE Property

Melting point:: 32-33 °C (lit.)
Boiling point:: 260 °C (lit.)
Density: 1.2455 (rough estimate)
refractive index: 1.6210 (estimate)
Flash point:: >230 °F
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
form: powder to lump to clear liquid
color: White or Colorless to Light yellow to Green
Water Solubility: Insoluble in water.
Sensitive: Light Sensitive
BRN: 3039
InChIKey: OHZAHWOAMVVGEL-UHFFFAOYSA-N
LogP: 3.750
CAS DataBase Reference: 492-97-7(CAS DataBase Reference)
EPA Substance Registry System: 2,2'-Bithiophene (492-97-7)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 20/21/22-36/37/38
Safety Statements: 22-24/25-36-26
WGK Germany: 3
F: 10-23
TSCA: T
HazardClass: IRRITANT
HS Code: 29309090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 241636
Product name: 2,2′-Bithiophene
Purity: 99%
Packaging: 10g
Price: $172
Updated: 2024/03/01

TCI Chemical

Product number: B1276
Product name: 2,2'-Bithiophene
Purity: >98.0%(GC)
Packaging: 1g
Price: $23
Updated: 2024/03/01

TCI Chemical

Product number: B1276
Product name: 2,2'-Bithiophene
Purity: >98.0%(GC)
Packaging: 25g
Price: $100
Updated: 2024/03/01

Alfa Aesar

Product number: A12335
Product name: 2,2'-Bithiophene, 98%
Packaging: 1g
Price: $30.65
Updated: 2024/03/01

Alfa Aesar

Product number: A12335
Product name: 2,2'-Bithiophene, 98%
Packaging: 5g
Price: $91.2
Updated: 2024/03/01

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2,2'-BITHIOPHENE Chemical Properties,Usage,Production

Description

2,2'-bithiophene is an intermediate widely used for the synthesis of small molecules or polymer semiconductors in application of organic electronics.?It has proven that?2,2'-bithiophene exists as a mixture of the cis-like and the trans-like planar structures. 5,5'-positions of?2,2'-bithiophene are easily accessible for bromination and stannylation to give 5,5'-dibromo-2,2'-bithiophene or 5,5'-trimethylstannyl-2,2'-bithiophene, which can be used for direct arylation reactions.

Chemical Properties

white to light yellow crystal powder

Uses

2,2’Bithiophene is a reactant in the preparation of thienophenyl compounds.

Uses

2,2'-Bithiophene is used as a precursor in the preparation of 5,5'-bis(trimethylstannyl)-2,2'-bithiophene , which is used for the synthesis of small molecules and polymer semiconductors for organic field-effect transistor (OFETs), organic light-emitting diode (OLED), Plastic Light Emitting Diode (PLED) and Organic Photovoltaic (OPV) applications. It is associated with aryl iodides and involved in rhodium catalyzed arylation of heteroarenes.

Uses

2,2′-Bithiophene can be polymerized to form poly(2,2′-Bithiophene) which can be electrodeposited on indium tin oxide (ITO) substrates for the fabrication of electrochromic devices. It can also be used in the formation of electrode material for the development of supercapacitors.

Definition

ChEBI: A thiophene derivative that consists of two thiophene rings connected by a 2,2'-linkage.

Synthesis Reference(s)

The Journal of Organic Chemistry, 51, p. 2627, 1986 DOI: 10.1021/jo00364a002
Synthetic Communications, 19, p. 307, 1989 DOI: 10.1080/00397918908050983

General Description

2,2′-Bithiophene is an electron transporting material with the π-electrons present in the system that facilitate charge mobility.

2,2'-BITHIOPHENE Preparation Products And Raw materials

Raw materials

Preparation Products

2,2'-BITHIOPHENE-5-CARBOXALDEHYDE 2,2'-BITHIOPHENE-5-BORONIC ACID

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View Lastest Price from 2,2'-BITHIOPHENE manufacturers

Henan Fengda Chemical Co., Ltd

Product: 2,2'-Bithiophene 492-97-7
Price: US $200.00-1.00/KG
Min. Order: 1KG
Purity: 99%, 99.5% Sublimated
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-30

Hebei Duling International Trade Co. LTD

Product: 2,2'-BITHIOPHENE 492-97-7
Price: US $26.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 1000kg
Release date: 2023-01-06

Shanghai UCHEM Inc.

Product: 2,2'-Bithiophene 492-97-7
Price: US $10.00-182.00/g
Min. Order: 25g
Purity: 0.98
Supply Ability: 25kg
Release date: 2023-10-20

492-97-7, 2,2'-BITHIOPHENERelated Search:

5,5'-Dibromo-2,2'-bithiophene 2,2'-BITHIOPHENE 2,2'-BITHIOPHENE-5-METHYLAMINE 5,5''-dibromo-[2,2':5',2"]terthiohene 2,2':5',2''-TERTHIOPHENE-5-CARBOXALDEHYDE Vat Red 1, Solubilized 5-ACETYL-2,2'-BITHIENYL 2,2'-BITHIOPHENE-5-CARBOXALDEHYDE 2,2':5',2''-TERTHIOPHENE 6-CHLORO-N-M-TOLYLPYRIDAZIN-3-AMINE 2,2'-BITHIOPHENE-5-BORONIC ACID Thiophene 5,5'-DIACETYL-2,2'-BITHIENYL 2,2''-BITHIOPHENE-5,5''-DICARBOXYLIC ACID 3,3'-Dibromo-2,2'-bithiophene 2,2'-BITHIOPHENE-5-CARBOTHIOAMIDE 4,4'-DIBROMO-2,2'-BITHIOPHENE 2,2'-BITHIOPHENE-5-CARBOXYLIC ACID

2,2'-Bithiophene,98%

2TH

2,2'-Bithiophen

2,2μ-Bithienyl, 2,2μ-Dithienyl

2-(2'-Thieno)thiophene

2,2'-Bithiophene,97%

2,2zzhlxy-Bithiophene

2,2’-dlthienyl

2,2'-Dithiophene

Dithienyl

2-(Thiophen-2yl) thiophene

2,2′-Bithiophene, >=99%

2,2'-BITHIOPHENE

2,2'-BITHIENYL

[2,2']BITHIOPHENYL

2,2'-DITHIENYL

2,2-DITHIENYL

2-(2-Thienyl)thiophen

2,2'-Bithiophene &gt

2,2'-BITHIOPHENE ISO 9001：2015 REACH

S1020

2,2'-Bithiophene (6CI, 7CI, 8CI, 9CI, ACI)

2,2'-Bisthiophene

2,2'-Bithiophene

2,2'-Bisthiophene

2,2'-Bithienyl

492-97-7

492-97-9

C4H3S2

C8H6S2

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