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PICROLONIC ACID

Product Name
PICROLONIC ACID
CAS No.
550-74-3
Chemical Name
PICROLONIC ACID
Synonyms
NSC 5049;PICROLIC ACID;PicrolonicAci;PICROLONIC ACID;Picrolonic acid, AR;Picrolonic acid,93%;Picrolonic acid, 98+%;LABOTEST-BB LT00233107;4-nitro-3-methyl-p-nitrophenyl-5-pyrazolone;3-methyl-4-nitro-1-p-nitrophenyl-5-pyrazolone
CBNumber
CB1405992
Molecular Formula
C10H8N4O5
Formula Weight
264.19
MOL File
550-74-3.mol
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PICROLONIC ACID Property

Melting point:
119 °C
Boiling point:
548.8±50.0 °C(Predicted)
Density 
1.65±0.1 g/cm3(Predicted)
storage temp. 
Sealed in dry,2-8°C
solubility 
0.27 % in water at room temperature, readily soluble in alcohol.
form 
Yellow crystalline material. Melting point 116-120°C (with decomposition).
pka
2.44±0.40(Predicted)
Water Solubility 
Slightly soluble in water. Soluble in alcohol.
Merck 
14,7412
BRN 
623723
CAS DataBase Reference
550-74-3(CAS DataBase Reference)
EPA Substance Registry System
Picrolonic acid (550-74-3)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
68-36/37/38-22-36/38-7
Safety Statements 
37/39-26-36
RIDADR 
3224
RTECS 
UQ9510000
TSCA 
Yes
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H341Suspected of causing genetic defects

Precautionary statements

P201Obtain special instructions before use.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
PRB0000029
Product name
PICROLONIC ACID
Purity
95.00%
Packaging
5MG
Price
$501.95
Updated
2021/12/16
AHH
Product number
MT-21465
Product name
Picrolonicacid
Purity
98%
Packaging
100g
Price
$698
Updated
2021/12/16
Chemenu
Product number
CM188661
Product name
3-Methyl-4-nitro-1-(4-nitrophenyl)-1H-pyrazol-5(4H)-one
Purity
95%
Packaging
100g
Price
$487
Updated
2021/12/16
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PICROLONIC ACID Chemical Properties,Usage,Production

Chemical Properties

beige to ochre-yellow powder

Uses

With calcium(II), lead(II) and thorium(IV) the reagent gives complexes which are practically insoluble in water. The high molecular weight crystalline complexes can be used to advantage for the accurate determination of minute amounts of various metals.
The reagent has also proved suitable for the spectrophotometric determination of calcium. Calcium picrolonate is transformed by bromine water in alkaline medium to a red, water-soluble complex. The absorption of this compound is constant for about two days and it also follows the Beer-Lambert Law.

Uses

Reagent for the isolation of amines as crystalline π-complexes.Picrolonic acid is an analytical reagent used for the estimation of calcium, magnesium, lead, strontium and thorium. It is also used for the analysis of alkaloids, tryptophan and phenylalanine.

Uses

As reagent for alkaloids, tryptophan, phenylalanine, and for the detection and estimation of calcium.

Purification Methods

Crystallise picrolic acid from water or EtOH (solubility is 0.123% at 15o and 1.203% at 100o in H2O; and 1.107% at 0o and 11.68% at 81o in EtOH). It forms Ca, Cu Hg, Mg, Na, Sr, Pb and many other metal complexes [Maquestian et al Bull Soc Chim Belg 82 233 1973, Isaki et al. Chem Ber 74 1420 1941]. [Beilstein 24 H 51, 24 I 218, 24 II 25, 22 III/IV 105.]

PICROLONIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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PICROLONIC ACID Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
Junsei Chemical Co., Ltd.
Tel
--
Fax
--
Email
shiyaku@junsei.co.jp
Country
Japan
ProdList
3096
Advantage
46
Wako Pure Chemical Industries, Ltd.
Tel
--
Fax
--
Email
labchem-tec@wako-chem.co.jp
Country
Japan
ProdList
6819
Advantage
80
Kanto Chemical Co., Inc.
Tel
--
Fax
--
Email
reag-info@gms.kanto.co.jp
Country
Japan
ProdList
6756
Advantage
74
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View Lastest Price from PICROLONIC ACID manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
PICROLONIC ACID 550-74-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-28
Hebei Yanxi Chemical Co., Ltd.
Product
PICROLONIC ACID 550-74-3
Price
US $70.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-09-08
Hebei Mojin Biotechnology Co., Ltd
Product
PICROLONIC ACID 550-74-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-10-17

550-74-3, PICROLONIC ACIDRelated Search:


  • PICROLONIC ACID
  • 2,4-dihydro-5-methyl-4-nitro-2-(4-nitrophenyl)-3h-pyrazol-3-on
  • 2-Pyrazolin-5-one, 3-methyl-4-nitro-1-(p-nitrophenyl)-
  • 3H-Pyrazol-3-one, 1,4-dihydro-5-methyl-4-nitro-2-(4-nitrophenyl)-
  • 3-methyl-4-nitro-1-(p-nitrophenyl)-2-pyrazolin-5-on
  • 3-Methyl-4-nitro-1-(p-nitrophenyl)-2-pyrazolin-5-one
  • 5-Methyl-4-nitro-2-(4-nitrophenyl)-2,4-dihydro-3H-pyrazol-3-one
  • PICROLIC ACID
  • Picrolonic acid, 98+%
  • 3-methyl-4-nitro-1-(4-nitrophenyl)-2-pyrazolin-5-one
  • 3-methyl-4-nitro-1-p-nitrophenyl-5-pyrazolone
  • Picrolonic acid, AR
  • 2-(4-Nitrophenyl)-4-nitro-5-methyl-2,4-dihydro-3H-pyrazole-3-one
  • 2,4-Dihydro-5-methyl-4-nitro-2-(4-nitrophenyl)-3H-pyrazol-3-one
  • 5-Methyl-4-nitro-2-(p-nitrophenyl)-2,4-dihydro-3H-pyrazole-3-one
  • 4-nitro-3-methyl-p-nitrophenyl-5-pyrazolone
  • Picrolonic acid,93%
  • 3-Methyl-4-nitro-1-(4-nitrophenyl)-1H-pyrazol-5(4H)-one
  • NSC 5049
  • 4-NITRO-3-METHYL-1-(P-NITROPHENYL)PYRAZOL-5-ONE
  • LABOTEST-BB LT00233107
  • 3H-Pyrazol-3-one, 2,4-dihydro-5-methyl-4-nitro-2-(4-nitrophenyl)-
  • PicrolonicAci
  • 550-74-3