4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE

Product Name: 4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE
CAS No.: 13274-43-6
Chemical Name: 4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE
Synonyms: N-Methyl-1,2,4-triazoline-3,5-dione;4-Methyl-1,2,4-triazolinedione;N-Methyl-1,2,4-triazolinedione;4-methyl-1,2,4-triazole-3,5-dione;N-Methyl-1,3,4-triazoline-2,5-dione;4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE;4-METHYL-1,2,4 TRIAUZOLINE 3,5-DIONE;3H-1,2,4-Triazole-3,5(4H)-dione, 4-Methyl-
CBNumber: CB1416301
Molecular Formula: C3H3N3O2
Formula Weight: 113.07
MOL File: 13274-43-6.mol

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4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE Property

Melting point:: 107-109 °C(lit.)
Boiling point:: 137.5±23.0 °C(Predicted)
Density: 1.71±0.1 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
solubility: DMSO (Slightly), Chloroform (Sparingly), Ethyl Acetate (Slightly), Methanol
form: Solid
pka: -3.61±0.20(Predicted)
color: Pink to Dark Pink
Stability:: Hygroscopic, Temperature Sensitive, Unstable in Solution

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Safety

WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M330850
Product name: N-Methyl-1,2,4-triazolinedione
Packaging: 1g
Price: $1390
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0164903
Product name: 4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE
Purity: 95.00%
Packaging: 500MG
Price: $750.75
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0164903
Product name: 4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE
Purity: 95.00%
Packaging: 5G
Price: $2136.75
Updated: 2021/12/16

AHH

Product number: MT-19018
Product name: 4-Methyl-1,2,4-triazoline-3,5-dione
Purity: 95%
Packaging: 5g
Price: $555
Updated: 2021/12/16

Crysdot

Product number: CD11293856
Product name: 4-Methyl-3H-1,2,4-triazole-3,5(4H)-dione
Purity: 95+%
Packaging: 1g
Price: $706
Updated: 2021/12/16

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4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE Chemical Properties,Usage,Production

Uses

4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE is a dienophile used in the partial elucidation of Trichogramma putative sex pheromone at trace levels.

Synthesis Reference(s)

The Journal of Organic Chemistry, 31, p. 3444, 1966 DOI: 10.1021/jo01348a532
Synthetic Communications, 17, p. 409, 1987 DOI: 10.1080/00397918708063918

Purification Methods

MTAD is obtained as pink needles by sublimation at 40-50o/0.1mm (see 4-phenyl-1,2,4-triazoline-3,5-dione, PTAD below). [Cookson et al. Org Synth 51 121 1971, Cheng et al. J Org Chem 49 2910 1984, Beilstein 26 III/IV 538.]

4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE Suppliers

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13274-43-6, 4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONERelated Search:

4-PHENYL-1,2,4-TRIAZOLINE-3,5-DIONE 4-(2-CHLORO-PHENYL)-[1,2,4]TRIAZOLE-3,5-DIONE 4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE 4-(4-BROMO-PHENYL)-[1,2,4]TRIAZOLE-3,5-DIONE 4-(4-METHOXY-PHENYL)-[1,2,4]TRIAZOLE-3,5-DIONE 4-(4-FLUORO-PHENYL)-[1,2,4]TRIAZOLE-3,5-DIONE 4-CYCLOHEXYL-[1,2,4]TRIAZOLE-3,5-DIONE 4-P-TOLYL-[1,2,4]TRIAZOLE-3,5-DIONE DMEQ-TAD 4-(4-CHLORO-PHENYL)-[1,2,4]TRIAZOLE-3,5-DIONE

4-METHYL-1,2,4-TRIAZOLINE-3,5-DIONE

4-METHYL-1,2,4 TRIAUZOLINE 3,5-DIONE

N-Methyl-1,2,4-triazolinedione

4-Methyl-1,2,4-triazolinedione

N-Methyl-1,2,4-triazoline-3,5-dione

N-Methyl-1,3,4-triazoline-2,5-dione

3H-1,2,4-Triazole-3,5(4H)-dione, 4-Methyl-

4-methyl-1,2,4-triazole-3,5-dione

13274-43-6

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