ETHYL 3-CHLOROBENZOYLFORMATE
- Product Name
- ETHYL 3-CHLOROBENZOYLFORMATE
- CAS No.
- 62123-73-3
- Chemical Name
- ETHYL 3-CHLOROBENZOYLFORMATE
- Synonyms
- ETHYL 3-CHLOROBENZOYLFORMATE;Ethyl 2-(3-chlorophenyl)-2-oxoacetate;(3-Chlorophenyl)oxoacetic acid ethyl ester;(3-CHLOROPHENYL)GLYOXYLIC ACID ETHYL ESTER;3-Chloro-oxo-benzeneacetic acid ethyl ester;Benzeneacetic acid,3-chloro-a-oxo-, ethyl ester;Benzeneacetic acid, 3-chloro-α-oxo-, ethyl ester
- CBNumber
- CB1419685
- Molecular Formula
- C10H9ClO3
- Formula Weight
- 212.63
- MOL File
- 62123-73-3.mol
ETHYL 3-CHLOROBENZOYLFORMATE Property
- Boiling point:
- 88°C 0,1mm
- Density
- 1.2270 g/cm3
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- pale yellow liquid
- CAS DataBase Reference
- 62123-73-3(CAS DataBase Reference)
Safety
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 023000
- Product name
- Ethyl3-chlorobenzoylformate
- Purity
- 96%
- Packaging
- 250mg
- Price
- $125
- Updated
- 2021/12/16
- Product number
- 023000
- Product name
- Ethyl3-chlorobenzoylformate
- Purity
- 96%
- Packaging
- 1g
- Price
- $250
- Updated
- 2021/12/16
- Product number
- 086335
- Product name
- Ethyl 3-chlorobenzoylformate
- Purity
- 97%
- Packaging
- 1g
- Price
- $252
- Updated
- 2021/12/16
- Product number
- KE0100
- Product name
- (3-Chlorophenyl)oxoaceticacidethylester
- Packaging
- 1g
- Price
- $364
- Updated
- 2021/12/16
- Product number
- 086335
- Product name
- Ethyl 3-chlorobenzoylformate
- Purity
- 97%
- Packaging
- 2g
- Price
- $401
- Updated
- 2021/12/16
ETHYL 3-CHLOROBENZOYLFORMATE Chemical Properties,Usage,Production
Synthesis
64-17-5
21667-62-9
62123-73-3
GENERAL METHODS: 3-Chlorobenzoylacetonitrile (1.0 mmol) and PIDA (2.2 mmol) were dissolved in ethanol (8 mL), and the reaction was stirred under reflux conditions for 0.5 hours. The reaction process was monitored by thin layer chromatography (TLC). After completion of the reaction, the reaction mixture was concentrated under reduced pressure. The residue was purified by silica gel column chromatography (eluent ratio 20:1 petroleum ether/ethyl acetate) to afford the target product ethyl 3-chlorobenzoylformate. Note: The solvent used in this synthesis step is methanol (MeOH).
References
[1] Tetrahedron Letters, 2015, vol. 56, # 24, p. 3793 - 3795
ETHYL 3-CHLOROBENZOYLFORMATE Preparation Products And Raw materials
Raw materials
Preparation Products
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