ChemicalBook > CAS DataBase List > BOC-3-AMINO-4-METHYLBENZOIC ACID

BOC-3-AMINO-4-METHYLBENZOIC ACID

Product Name: BOC-3-AMINO-4-METHYLBENZOIC ACID
CAS No.: 231958-04-6
Chemical Name: BOC-3-AMINO-4-METHYLBENZOIC ACID
Synonyms: BOC-(3)ATL(4)-OH;BOC-(3)ABZ(4-ME)-OH;BOC-3-AMINO-4-METHYLBENZOIC ACID;3-(Boc-amino)-4-methylbenzoic acid;N-T-BUTOXYCARBONYL-3-AMINO-4-TOLUIC ACID;3--4-Methylbenzoicacid 231958-04-6;N-T-BUTOXYCARBONYL-3-AMINO-4-METHYL-BENZOIC ACID;3-[(t-Butoxycarbonyl)amino]-4-methylbenzoic acid;3-[(tert-butyloxycarbonyl)aMino]-4-Methylbenzoic acid;3-[[(1,1-Dimethylethoxy)carbonyl]amino]-4-methylbenzoic acid
CBNumber: CB1421172
Molecular Formula: C13H17NO4
Formula Weight: 251.28
MOL File: Mol file

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BOC-3-AMINO-4-METHYLBENZOIC ACID Property

Boiling point:: 354.3±35.0 °C(Predicted)
Density: 1.212±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: 4.32±0.10(Predicted)
Appearance: White to off-white Solid

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Safety

HazardClass: IRRITANT

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

ChemScene

Product number: CS-W021750
Product name: 3-((tert-Butoxycarbonyl)amino)-4-methylbenzoicacid
Purity: >98.0%
Packaging: 1g
Price: $82
Updated: 2021/12/16

AK Scientific

Product number: 1519AB
Product name: 3-((tert-Butoxycarbonyl)amino)-4-methylbenzoicacid
Packaging: 100mg
Price: $95
Updated: 2021/12/16

Matrix Scientific

Product number: 041687
Product name: Boc-3-amino-4-methylbenzoic acid
Purity: 95%
Packaging: 1g
Price: $126
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: AAA0004016
Product name: BOC-3-AMINO-4-METHYLBENZOIC ACID
Purity: 95.00%
Packaging: 5MG
Price: $188.1
Updated: 2021/12/16

ChemScene

Product number: CS-W021750
Product name: 3-((tert-Butoxycarbonyl)amino)-4-methylbenzoicacid
Purity: >98.0%
Packaging: 5g
Price: $286
Updated: 2021/12/16

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BOC-3-AMINO-4-METHYLBENZOIC ACID Chemical Properties,Usage,Production

Synthesis

24424-99-5

2458-12-0

231958-04-6

To a mixed solution of 3-amino-4-methylbenzoic acid (2.0 g, 13.2 mmol) in water (25 mL) and 1 N sodium hydroxide (25 mL) was added di-tert-butyl dicarbonate (4.3 g, 19.8 mmol). The reaction mixture was stirred at room temperature for 18 hours. After completion of the reaction, the mixture was extracted by partitioning with ethyl acetate and 5% aqueous citric acid. The organic layer was separated, washed sequentially with water and saturated saline, and then dried with anhydrous magnesium sulfate. The desiccant was removed by filtration and the filtrate was concentrated under reduced pressure to give 3-((tert-butoxycarbonyl)amino)-4-methylbenzoic acid as a pink solid (3.3 g, quantitative yield).

References

[1] Patent: US2012/142708, 2012, A1. Location in patent: Page/Page column 23
[2] Patent: WO2005/42537, 2005, A1. Location in patent: Page/Page column 46; 47
[3] Bioorganic and Medicinal Chemistry Letters, 2014, vol. 24, # 16, p. 3700 - 3705
[4] European Journal of Organic Chemistry, 2001, # 2, p. 311 - 322
[5] Journal of Medicinal Chemistry, 2008, vol. 51, # 1, p. 4 - 16

BOC-3-AMINO-4-METHYLBENZOIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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BOC-3-AMINO-4-METHYLBENZOIC ACID Suppliers

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View Lastest Price from BOC-3-AMINO-4-METHYLBENZOIC ACID manufacturers

Career Henan Chemical Co

Product: BOC-3-AMINO-4-METHYLBENZOIC ACID 231958-04-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 200kg
Release date: 2018-12-24

231958-04-6, BOC-3-AMINO-4-METHYLBENZOIC ACIDRelated Search:

BOC-3-AMINO-4-METHYLBENZOIC ACID

BOC-(3)ATL(4)-OH

BOC-(3)ABZ(4-ME)-OH

3-[(tert-butyloxycarbonyl)aMino]-4-Methylbenzoic acid

3--4-Methylbenzoicacid 231958-04-6

3-[[(1,1-Dimethylethoxy)carbonyl]amino]-4-methylbenzoic acid

N-T-BUTOXYCARBONYL-3-AMINO-4-METHYL-BENZOIC ACID

N-T-BUTOXYCARBONYL-3-AMINO-4-TOLUIC ACID

3-(Boc-amino)-4-methylbenzoic acid

4-methyl-3-[(2-methylpropan-2-yl)oxycarbonylamino]benzoic acid

Benzoic acid, 3-[[(1,1-dimethylethoxy)carbonyl]amino]-4-methyl-

3-[(t-Butoxycarbonyl)amino]-4-methylbenzoic acid

231958-04-6