ChemicalBook > CAS DataBase List > 4-CARBOXYCINNAMIC ACID

4-CARBOXYCINNAMIC ACID

Product Name
4-CARBOXYCINNAMIC ACID
CAS No.
19675-63-9
Chemical Name
4-CARBOXYCINNAMIC ACID
Synonyms
RARECHEM BK HW 0113;P-CARBOXYCINNAMIC ACID;4-CARBOXYCINNAMIC ACID;p-Carboxycinnamic acid,97%;4-Carboxybenzeneacrylic acid;4-Carboxy-trans-cinnamic acid;4-(2-CARBOXYVINYL)BENZOIC ACID;3-(4-Carboxyphenyl)acrylic acid;4-(2-Carboxyethenyl)benzoic acid;4-CARBOXYCINNAMIC ACID USP/EP/BP
CBNumber
CB1433694
Molecular Formula
C10H8O4
Formula Weight
192.17
MOL File
19675-63-9.mol
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4-CARBOXYCINNAMIC ACID Property

Melting point:
>300°C
Boiling point:
248.14°C (rough estimate)
Density 
1.0825 (rough estimate)
refractive index 
1.4440 (estimate)
storage temp. 
Sealed in dry,Room Temperature
pka
4.12±0.10(Predicted)
form 
powder
color 
cream
BRN 
2614866
CAS DataBase Reference
19675-63-9(CAS DataBase Reference)
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
HS Code 
2916399090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
C183313
Product name
4-(2-Carboxyvinyl)benzoicAcid
Packaging
1g
Price
$70
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC71077
Product name
4-Carboxycinnamic acid
Packaging
5G
Price
$80
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC71077
Product name
4-Carboxycinnamic acid
Packaging
2g
Price
$50
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC71077
Product name
4-Carboxycinnamic acid
Packaging
10g
Price
$128
Updated
2021/12/16
AK Scientific
Product number
0136AB
Product name
4-(2-Carboxyvinyl)benzoicacid
Packaging
5g
Price
$158
Updated
2021/12/16
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4-CARBOXYCINNAMIC ACID Chemical Properties,Usage,Production

Chemical Properties

cream fine powder

Uses

4-(2-Carboxyvinyl)benzoic Acid is used in preparation of Polycarboxylic Acid water reducer with good dispersion and slump resistance.

Synthesis

619-58-9

79-10-7

19675-63-9

In a typical reaction, 4-iodobenzoic acid (9 mmol), acrylic acid (15 mmol), tributylamine (30 mmol), and DMF (10 mL) were added to a round-bottomed flask containing 1.47 mol/L of AOFs-Ni(0) catalyst. The reaction was carried out in a temperature-controlled oil bath. After completion of the reaction, the mixture was cooled to room temperature. The AOFs-Ni(0) catalyst was separated from the mixture by filtration and washed sequentially with hot ethanol for next use. The filtrate was extracted with ethyl acetate (30 mL) and washed with distilled water (3 × 15 mL). Subsequently, the solvent was removed by rotary evaporation to give the crude product. The crude product was purified by column chromatography using mixed solvents (petroleum ether/ethyl acetate = 3/1) on H 60-silica powder. The purified 4-(2-carboxyvinyl)benzoic acid was characterized by melting point determination, 1H NMR, HRMS and GC-MS.

References

[1] RSC Advances, 2016, vol. 6, # 20, p. 16115 - 16121
[2] Applied Organometallic Chemistry, 2012, vol. 26, # 1, p. 16 - 20
[3] Journal of Chemical Research, 2016, vol. 40, # 3, p. 164 - 166

4-CARBOXYCINNAMIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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4-CARBOXYCINNAMIC ACID Suppliers

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Alfa Aesar
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View Lastest Price from 4-CARBOXYCINNAMIC ACID manufacturers

Career Henan Chemical Co
Product
4-CARBOXYCINNAMIC ACID 19675-63-9
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2020-02-05

19675-63-9, 4-CARBOXYCINNAMIC ACIDRelated Search:

4-(1-PYRROLIDINO)BENZALDEHYDE methyl 4-(2-cyanopropan-2-yl)benzoate Styrene 2-Carboxycinnamic acid, predominantly trans, 97%,2-CARBOXYCINNAMIC ACID 99%,O-CARBOXYCINNAMIC ACID,2-CARBOXYCINNAMIC ACID 4-CARBOXYCINNAMIC ACID 3-CARBOXYCINNAMIC ACID M-CARBOXYCINNAMIC ACID BIS-HYDROXAMIDE carboxycinnamic acid bishydroxamide RARECHEM AL BK 0920 RARECHEM AL BM 1481 4-[(1E)-3-ETHOXY-3-OXOPROP-1-EN-1-YL]BENZOIC ACID RARECHEM AL BK 1481 RARECHEM AL BR 0110 RARECHEM AL BM 0110 (2E)-2-cyano-3-[4-(methoxycarbonyl)phenyl]acrylic acid RARECHEM AL BM 0109 RARECHEM AL BM 0920 (E)-3-[4-(METHOXYCARBONYL)PHENYL]-2-PROPENOIC ACID

  • 3-(4-CARBOXYPHENYL)PROPENOIC ACID
  • 4-(2-CARBOXYVINYL)BENZOIC ACID
  • 4-CARBOXYCINNAMIC ACID
  • P-CARBOXYCINNAMIC ACID
  • RARECHEM BK HW 0113
  • 4-Carboxycinnamic acid, predominantly trans, 98%
  • 4-Carboxy-trans-cinnamic acid
  • 3-(4-Carboxyphenyl)acrylic acid
  • 4-(2-Carboxyethenyl)benzoic acid
  • 4-Carboxybenzeneacrylic acid
  • p-Carboxycinnamic acid,97%
  • 4-(2-Carboxyvinyl)benzoic acid 95+%
  • 4-[(E)-2-carboxylatoethenyl]benzoate
  • Benzoic acid, 4-(2-carboxyethenyl)-
  • 4-[(E)-2-Carboxyvinyl]benzoic acid
  • 4-CARBOXYCINNAMIC ACID USP/EP/BP
  • 4-(2-carboxyeth-1-en-1-yl)benzoic acid
  • 19675-63-9
  • Aromatic Cinnamic Acids, Esters and Derivatives