2-CHLOROPHENYLZINC IODIDE
- Product Name
- 2-CHLOROPHENYLZINC IODIDE
- CAS No.
- 148651-35-8
- Chemical Name
- 2-CHLOROPHENYLZINC IODIDE
- Synonyms
- 2-CHLOROPHENYLZINC IODIDE;2-chlorophenylzinc iodide solution;2-Chlorophenylzinc iodide solution 0.5 in THF;2-Chlorophenylzinc iodide solution 0.5M in THF;2-Chlorophenylzinc iodide 0.5 M in Tetrahydrofuran;2-CHLOROPHENYLZINC IODIDE, 0.5M SOLUTION IN TETRAHYDROFURAN;2-Chlorophenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles;2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
- CBNumber
- CB1436675
- Molecular Formula
- C6H4ClIZn
- Formula Weight
- 303.84
- MOL File
- 148651-35-8.mol
2-CHLOROPHENYLZINC IODIDE Property
- Density
- 0.973 g/mL at 25 °C
- Flash point:
- 1 °F
- storage temp.
- 2-8°C
- Sensitive
- Air & Light Sensitive
- Exposure limits
- ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) - CAS DataBase Reference
- 148651-35-8
Safety
- Hazard Codes
- F,Xn
- Risk Statements
- 11-19-22-36/37/38-40-36/37
- Safety Statements
- 16-26-33-36-36/37
- RIDADR
- UN 2056 3/PG 2
- WGK Germany
- 1
- HazardClass
- 4.3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H261In contact with water releases flammable gas
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
H319Causes serious eye irritation
H333May be harmful if inhaled
H335May cause respiratory irritation
H351Suspected of causing cancer
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 499803
- Product name
- 2-Chlorophenylzinc iodide solution
- Purity
- 0.5M in THF
- Packaging
- 50ml
- Price
- $273
- Updated
- 2023/06/20
- Product number
- H58383
- Product name
- 2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
- Packaging
- 50ml
- Price
- $216
- Updated
- 2021/12/16
- Product number
- 2135
- Product name
- 2-Chlorophenylzinciodide
- Packaging
- 100mL
- Price
- $755
- Updated
- 2021/12/16
- Product number
- ING0005751
- Product name
- 2-CHLOROPHENYLZINC IODIDE
- Purity
- 95.00%
- Packaging
- 50ML
- Price
- $2760.45
- Updated
- 2021/12/16
- Product number
- ING0005751
- Product name
- 2-CHLOROPHENYLZINC IODIDE
- Purity
- 95.00%
- Packaging
- 100ML
- Price
- $3106.95
- Updated
- 2021/12/16
2-CHLOROPHENYLZINC IODIDE Chemical Properties,Usage,Production
Uses
2-Chlorophenylzinc iodide is an organozinc compound, which can be used as a reactant in Negishi cross-coupling reaction to construct carbon-carbon bonds by reacting with organic halides using nickel or palladium catalysts.
It can also be utilized as a reactant to prepare:
- Arylmethanes via rhodium-catalyzed cross-coupling reaction with methyl halides.
- (2-chlorobenzyl)trimethylsilane by Rh-catalyzed cross-coupling reaction with (iodomethyl)trimethylsilane.
- Dichloro biphenyl by palladium catalyzed oxidative homocoupling reaction using N-chlorosuccinimide (NCS) or O2 as the oxidant.