(1-ETHOXYCYCLOPROPOXY)TRIMETHYLSILANE

Product Name: (1-ETHOXYCYCLOPROPOXY)TRIMETHYLSILANE
CAS No.: 27374-25-0
Chemical Name: (1-ETHOXYCYCLOPROPOXY)TRIMETHYLSILANE
Synonyms: [(1-ETHOXYCYCLOPROPYL)OXY]TRIMETHYLSILANE;1-Ethoxy-1-(trimethylsiloxy)cyclopropane;DK713;(1-EthoxycycL;opropoxy)trimethyL;(1-ETHOXYCYCLOPROPOXY)TRIMETHYLSILANE;1-ETHOXY-1-TRIMETHYLSILOXYL CYCLOPROPANE;Trimethyl[(1-ethoxycyclopropyl)oxy]silane;(1-ETHOXYCYCLOPROPOXY)TRIMETHYLSILANE 99%;(1-Ethoxycyclopropoxy)trimethylsilane,99%
CBNumber: CB1440863
Molecular Formula: C8H18O2Si
Formula Weight: 174.31
MOL File: 27374-25-0.mol

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(1-ETHOXYCYCLOPROPOXY)TRIMETHYLSILANE Property

Boiling point:: 50-53 °C/22 mmHg (lit.)
Density: 0.867 g/mL at 25 °C (lit.)
refractive index: n20/D 1.407(lit.)
Flash point:: 79 °F
storage temp.: Inert atmosphere,2-8°C
solubility: insol H2O.
form: Liquid
color: Clear colorless
Specific Gravity: 0.867
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
BRN: 1924720
InChIKey: BZMMRNKDONDVIB-UHFFFAOYSA-N
CAS DataBase Reference: 27374-25-0

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Safety

Hazard Codes: Xi
Risk Statements: 10-36/37/38
Safety Statements: 26-36-37/39-16
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
F: 10-21
HazardClass: 3.2
PackingGroup: III
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 332739
Product name: (1-Ethoxycyclopropoxy)trimethylsilane
Purity: 98%
Packaging: 5g
Price: $113
Updated: 2024/03/01

Sigma-Aldrich

Product number: 332739
Product name: (1-Ethoxycyclopropoxy)trimethylsilane
Purity: 98%
Packaging: 25g
Price: $299
Updated: 2023/06/20

TRC

Product number: E700055
Product name: (1-Ethoxycyclopropoxy)trimethylsilane
Packaging: 25g
Price: $375
Updated: 2021/12/16

Matrix Scientific

Product number: 188507
Product name: (1-Ethoxycyclopropoxy)trimethylsilane
Packaging: 50g
Price: $462
Updated: 2021/12/16

Matrix Scientific

Product number: 188507
Product name: (1-Ethoxycyclopropoxy)trimethylsilane
Packaging: 100g
Price: $720
Updated: 2021/12/16

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(1-ETHOXYCYCLOPROPOXY)TRIMETHYLSILANE Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Physical properties

bp 50–53 °C/22 mmHg.

Uses

(1-Ethoxycyclopropoxy)trimethylsilane was used in the preparation of N-(1′-alkoxy)cyclopropyl-2-haloanilines.

Uses

The 1-Ethoxy-1-(trimethylsilyloxy)cyclopropane can be used as preparation of 3-metallopropionates; metal homoenolate precursor; γ-hydroxy esters; cyclopentenones; 3-aminopropionates; cyclopropylamine formation; 1-aminocyclopropanecarboxylic acids and 1-aminocyclopropanephosphonic acids; β- and γ-amino acids.
The 1-Ethoxy-1-(trimethylsilyloxy)cyclopropane is widely used in various reactions. Cyclization of optically pure β-halo esters gives cyclopropanone acetals enantiomerically pure at C-2 and a 1:1 diastereomeric mixture at C-1.
Use of Cyclopropanone Hemiacetals. Heating cyclopropanone hemiacetal at 100°Cin an aqueous buffer provides the cyclopropanone hydrate. It also serves as a source of homoenolate radical species with a catalytic amount of AgNO3.

Preparation

For the synthesis of the parent and the 2-monoalkyl-substituted compounds, reduction of ethyl 3- chloropropionate with sodium–potassium alloy in the presence of chlorotrimethylsilane in ether. A recent modification using ultrasound irradiation is much more convenient and more widely applicable. Other substituted derivatives are prepared by cyclopropanation of alkyl silyl ketene acetals with the Furukawa reagent (diiodomethane/diethylzinc).

(1-ETHOXYCYCLOPROPOXY)TRIMETHYLSILANE Preparation Products And Raw materials

Raw materials

Preparation Products

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(1-ETHOXYCYCLOPROPOXY)TRIMETHYLSILANE Suppliers

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View Lastest Price from (1-ETHOXYCYCLOPROPOXY)TRIMETHYLSILANE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: (1-Ethoxycyclopropoxy)trimethylsilane 27374-25-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

Zhuozhou Wenxi import and Export Co., Ltd

Product: (1-Ethoxycyclopropoxy)trimethylsilane 27374-25-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-09

Zhuozhou Wenxi import and Export Co., Ltd

Product: (1-ETHOXYCYCLOPROPOXY)TRIMETHYLSILANE 27374-25-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

27374-25-0, (1-ETHOXYCYCLOPROPOXY)TRIMETHYLSILANERelated Search:

Silicon carbide Cyclopropane TRIMETHYLSILANE (1-ETHOXYCYCLOPROPOXY)TRIMETHYLSILANE ISOPROPOXYTRIMETHYLSILANE

1-Ethoxy-1-(trimethylsiloxy)cyclopropane

1-Ethoxy-1-(trimethylsilyloxy)cyclopropane

2- 1-Ethoxy-1-trimethylsiloxylcyclopropane

(1-ETHOXYCYCLOPROPOXY)TRIMETHYLSILANE 99%

(1-ETHOXYCYCLOPROPOXY)TRIMETHYLSILANE

[(1-ETHOXYCYCLOPROPYL)OXY]TRIMETHYLSILANE

1-ETHOXY-1-TRIMETHYLSILOXYL CYCLOPROPANE

CYCLOPROPANONE ETHYL TRIMETHYLSILYL ACETAL

1-(Trimethylsilyloxy)-1-ethoxycyclopropane

1-Ethyloxy-1-(trimethylsilyloxy)cyclopropane

Trimethyl[(1-ethoxycyclopropyl)oxy]silane

(1-Ethoxycyclopropoxy)trimethylsilane,99%

(1-Ethoxycyclopropoxy)trimethylsilaneCyclopropanone ethyl trimethylsilyl acetal

(1-Ethoxycyclopropoxy)trimethylsilane ,98.5%

SILANE, [(1-ETHOXYCYCLOPROPYL)OXY]TRIMETHYL-

(1-Ethoxycyclopropoxy)triMethylsilane, 99% 25GR

(1-Ethoxycyclopropoxy)triMethylsilane, 99% 5GR

opropoxy)trimethyL

(1-EthoxycycL

Cyclopropane, 1-ethoxy-1-[(trimethylsilyl)oxy]-

(1-ethoxycyclopropyl)oxy-trimethylsilane(27374-25-0)

DK713

27374-25-0

C2H5OC3H4OSICH33

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