1,10-PHENANTHROLINE-2,9-DICARBOXYLIC ACID
- Product Name
- 1,10-PHENANTHROLINE-2,9-DICARBOXYLIC ACID
- CAS No.
- 57709-61-2
- Chemical Name
- 1,10-PHENANTHROLINE-2,9-DICARBOXYLIC ACID
- Synonyms
- DK7507;2,9-dicarboxylic acid;2,9-dicarboxy-1,10-phenanthroline;1,10-PHENTHROLINE-2,9-DICARBOXYLIC ACID;2,9-Dicarboxylicacid-1,10-phenanthroline;1,10-PHENANTHROLINE-2,9-DICARBOXYLIC ACID;1,10-Phenanthroline-2,9-dicarboxylic acid hydrate;1,10-PHENANTHROLINE-2,9-DICARBOXYLIC ACID HYDRATE, 98%;1,10-PHENANTHROLINE-2,9-DICARBOXYLIC ACID ISO 9001：2015 REACH
- CBNumber
- CB1457456
- Molecular Formula
- C14H8N2O4
- Formula Weight
- 268.22
- MOL File
- 57709-61-2.mol
1,10-PHENANTHROLINE-2,9-DICARBOXYLIC ACID Property
- Melting point:
- 239 °C(Solv: methanol (67-56-1))
- Boiling point:
- 563.1±45.0 °C(Predicted)
- Density
- 1.585±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C
- pka
- 0.61±0.30(Predicted)
- Appearance
- Off-white to light yellow Solid
- InChI
- InChI=1S/C14H8N2O4/c17-13(18)9-5-3-7-1-2-8-4-6-10(14(19)20)16-12(8)11(7)15-9/h1-6H,(H,17,18)(H,19,20)
- InChIKey
- FXSVCROWUPWXBP-UHFFFAOYSA-N
- SMILES
- N1C2C(=CC=C3C=2N=C(C(O)=O)C=C3)C=CC=1C(O)=O
- CAS DataBase Reference
- 57709-61-2
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- CHM0005552
- Product name
- 1,10-PHENANTHROLINE-2,9-DICARBOXYLIC ACID HYDRATE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $504.03
- Updated
- 2021/12/16
- Product number
- 8605CQ
- Product name
- 1,10-Phenanthroline-2,9-dicarboxylicAcid
- Packaging
- 1g
- Price
- $278
- Updated
- 2021/12/16
- Product number
- CS-W004587
- Product name
- 1,10-Phenanthroline-2,9-dicarboxylicacid
- Purity
- ≥97.0%
- Packaging
- 1g
- Price
- $112
- Updated
- 2021/12/16
- Product number
- 57709612
- Product name
- 1,10-Phenanthroline-2,9-dicarboxylicacid
- Packaging
- 1g
- Price
- $157.5
- Updated
- 2021/12/16
- Product number
- AS442736
- Product name
- 1,10-Phenanthroline-2,9-dicarboxylicacid
- Purity
- 95%
- Packaging
- 1g
- Price
- $160
- Updated
- 2021/12/16
1,10-PHENANTHROLINE-2,9-DICARBOXYLIC ACID Chemical Properties,Usage,Production
Uses
1,10-Phenanthroline-2,9-dicarboxylic acid hydrate is used to produce 1,10-phenanthroline-2,9-dicarbonyl chloride.
Synthesis
78831-41-1
57709-61-2
General procedure for the synthesis of 2,9-dicarboxy-1,10-phenanthroline from 2,9-bis(trichloromethyl)-1,10-phenanthroline: 2,9-bis(trichloromethyl)-1,10-phenanthroline (540 mg, 1.3 mmol, 1.0 eq.) was dissolved in a concentrated aqueous sulfuric acid solution (95-98%, 17 mL), and the reaction was stirred for 7 hr at 85 °C. Upon completion of the reaction, the brown reaction solution was cooled to room temperature and slowly poured onto crushed ice. After the ice was completely melted, the resulting white suspension was filtered under vacuum, washed thoroughly with water and dried in air to obtain the pure 2,9-dicarboxy-1,10-phenanthroline (360 mg, quantitative yield). The product characterization data were as follows: 1H NMR (300 MHz, DMSO-d6): δ= 8.22 (s, 2H), 8.42 (d, 3J = 8.4 Hz, 2H), 8.74 (d, 3J = 8.4 Hz, 2H); melting point 215-216 °C (decomposition).
References
[1] Synlett, 2018, vol. 29, # 10, p. 1362 - 1366
[2] Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1996, # 1, p. 75 - 82
[3] Journal of Heterocyclic Chemistry, 1981, vol. 18, p. 599 - 602
1,10-PHENANTHROLINE-2,9-DICARBOXYLIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1,10-PHENANTHROLINE-2,9-DICARBOXYLIC ACID manufacturers
- Product
- 1,10-phenanthroline-2,9-dicarboxylic acid 57709-61-2
- Price
- US $13.00-133.00/g
- Min. Order
- 1g
- Purity
- 0.98
- Supply Ability
- 10kg
- Release date
- 2025-09-23
- Product
- 1,10-PHENANTHROLINE-2,9-DICARBOXYLIC ACID 57709-61-2
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2024-12-03
- Product
- 1,10-PHENANTHROLINE-2,9-DICARBOXYLIC ACID 57709-61-2
- Price
- US $9.80/KG
- Min. Order
- 1g
- Purity
- ≥99%
- Supply Ability
- 100kg
- Release date
- 2020-01-08