METHYL 2-AMINO-5-BROMO-3-IODOBENZOATE
- Product Name
- METHYL 2-AMINO-5-BROMO-3-IODOBENZOATE
- CAS No.
- 289039-83-4
- Chemical Name
- METHYL 2-AMINO-5-BROMO-3-IODOBENZOATE
- Synonyms
- Methyl 2-amino-3-iodo-5-bromobenzoate;METHYL 2-AMINO-5-BROMO-3-IODOBENZOATE;Methyl 2-amino-5-bromo-3-iodobenzoate - [M71779];2-Amino-5-bromo-3-iodo-benzoic acid methyl ester;Benzoic acid, 2-amino-5-bromo-3-iodo-, methyl ester
- CBNumber
- CB1461987
- Molecular Formula
- C8H7BrINO2
- Formula Weight
- 355.96
- MOL File
- 289039-83-4.mol
METHYL 2-AMINO-5-BROMO-3-IODOBENZOATE Property
- storage temp.
- 2-8°C, protect from light
- Appearance
- Off-white to light brown Solid
- InChI
- InChI=1S/C8H7BrINO2/c1-13-8(12)5-2-4(9)3-6(10)7(5)11/h2-3H,11H2,1H3
- InChIKey
- NYKVKANRUGAWAL-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=CC(Br)=CC(I)=C1N
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 096031
- Product name
- Methyl 2-amino-5-bromo-3-iodobenzoate
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $265
- Updated
- 2021/12/16
- Product number
- 2895AB
- Product name
- Methyl2-amino-5-bromo-3-iodobenzoate
- Packaging
- 1g
- Price
- $417
- Updated
- 2021/12/16
- Product number
- HCH0369139
- Product name
- METHYL-2-AMINO-5-BROMO-3-IODOBENZOATE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $501.81
- Updated
- 2021/12/16
- Product number
- 096031
- Product name
- Methyl 2-amino-5-bromo-3-iodobenzoate
- Purity
- 95+%
- Packaging
- 1g
- Price
- $588
- Updated
- 2021/12/16
- Product number
- 2895AB
- Product name
- Methyl2-amino-5-bromo-3-iodobenzoate
- Packaging
- 5g
- Price
- $1513
- Updated
- 2021/12/16
METHYL 2-AMINO-5-BROMO-3-IODOBENZOATE Chemical Properties,Usage,Production
Synthesis
52727-57-8
289039-83-4
General procedure for the synthesis of methyl 2-amino-5-bromo-3-iodobenzoate from methyl 5-bromoaminobenzoate: 371 mg of methyl 2-amino-5-bromobenzoate (2 mmol) was dissolved in 2 mL of concentrated acetic acid, and 495 mg of N-iodosuccinimide (2.2 mmol) was added and the reaction was carried out for 17 hours at room temperature. After completion of the reaction, the mixture was poured into a mixture of 5 mL of saturated sodium bicarbonate solution and ice and extracted twice with ethyl acetate (EtOAc). The organic phases were combined, washed with saturated brine, dried over anhydrous magnesium sulfate, filtered and concentrated under reduced pressure to give 585 mg of methyl 2-amino-5-bromo-3-iodobenzoate (82% yield) as a light brown solid. Mass spectrometry (EI) showed a molecular ion peak m/z 354.9 (M+).
References
[1] Patent: US2006/30613, 2006, A1. Location in patent: Page/Page column 21-22
[2] Patent: WO2016/87975, 2016, A1. Location in patent: Page/Page column 26
METHYL 2-AMINO-5-BROMO-3-IODOBENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
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