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MAGNOLINE

Product Name
MAGNOLINE
CAS No.
6859-66-1
Chemical Name
MAGNOLINE
Synonyms
MAGNOLINE;(1R)-1,2,3,4-Tetrahydro-1-[[4-[2-hydroxy-5-[[(1S)-1,2,3,4-tetrahydro-7-hydroxy-6-methoxy-2-methylisoquinolin-1-yl]methyl]phenoxy]phenyl]methyl]-6-methoxy-2-methylisoquinolin-7-ol;7-Isoquinolinol, 1,2,3,4-tetrahydro-1-[[4-[2-hydroxy-5-[[(1S)-1,2,3,4-tetrahydro-7-hydroxy-6-methoxy-2-methyl-1-isoquinolinyl]methyl]phenoxy]phenyl]methyl]-6-methoxy-2-methyl-, (1R)-
CBNumber
CB1480557
Molecular Formula
C36H40N2O6
Formula Weight
596.71
MOL File
6859-66-1.mol
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MAGNOLINE Property

Melting point:
178-179°
alpha 
D -9.6° (pyridine)
Boiling point:
738.3±60.0 °C(Predicted)
Density 
1.254±0.06 g/cm3(Predicted)
pka
9.31±0.45(Predicted)
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
API0008045
Product name
MAGNOLINE
Purity
95.00%
Packaging
5MG
Price
$267.3
Updated
2021/12/16
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MAGNOLINE Chemical Properties,Usage,Production

Description

A closely-related bisbenzylisoquinoline base found also in Magnolia fuscata, the alkaloid occurs mainly in the leaves and is obtained in the pure form as a microcrystalline powder from EtOH or C6H6. It may be separated from magnolamine by virtue of its insolubility in hot C6H6. It is only sparingly soluble in most organic solvents but dissolves readily in aqueous alkalies. The alkaloid is laevorotatory with [α]D - 9.6° (pyridine). It furnishes vitreous salts with mineral acids but yields a crystalline picrate as a yellow microcrystalline powder from EtOH, m.p. 160-2°C (dec.) and a picrolonate, m.p. 190°C (dec.). Treatment with CH2N2 gives the trimethyl ether, m.p. 1 09-1 10°C, oxidized by KMn04 in Me2CO to 2-methoxy-5:4'-dicarboxydiphenyl ether and a lactam, l-keto-6:7- dimethoxy-2-methyltetrahydroisoquinoline. On the basis of these results, the alkaloid may be represented by the above structure which makes it a close relative of dauricine (q.v.). The Ullmann reaction has been used by Kametani and his colleagues to synthesize the alkaloid.

Definition

ChEBI: Berbamunine is a benzyltetrahydroisoquinoline, a bisbenzylisoquinoline alkaloid and an isoquinolinol. It is a conjugate base of a berbamuninium(2+).

References

Pyman., J. Chern. Soc., 95, 1272 (1909) Proskurnina, Orekhov., Bull. Soc. Chirn., 5, 1357 (1958) Proskurnina, Orekhov., J. Gen. Chern. USSR., 10, 707 (1940) Synthesis: Kametani, !ida, Sakurai., Chern. Pharrn. Bull. (Tokyo), 16, 1623 (1968)

MAGNOLINE Preparation Products And Raw materials

Raw materials

Preparation Products

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6859-66-1, MAGNOLINERelated Search:


  • MAGNOLINE
  • (1R)-1,2,3,4-Tetrahydro-1-[[4-[2-hydroxy-5-[[(1S)-1,2,3,4-tetrahydro-7-hydroxy-6-methoxy-2-methylisoquinolin-1-yl]methyl]phenoxy]phenyl]methyl]-6-methoxy-2-methylisoquinolin-7-ol
  • 7-Isoquinolinol, 1,2,3,4-tetrahydro-1-[[4-[2-hydroxy-5-[[(1S)-1,2,3,4-tetrahydro-7-hydroxy-6-methoxy-2-methyl-1-isoquinolinyl]methyl]phenoxy]phenyl]methyl]-6-methoxy-2-methyl-, (1R)-
  • 6859-66-1