Di-tert-amyl peroxide Property

Melting point:

-55°C

Boiling point:

146 °C(lit.)

Density 

0.818 g/mL at 25 °C(lit.)

vapor pressure 

14.7hPa at 25℃

refractive index 

n20/D 1.409(lit.)

Flash point:

77 °F

Water Solubility 

13.83mg/L at 20℃

InChI

InChI=1S/C10H22O2/c1-7-9(3,4)11-12-10(5,6)8-2/h7-8H2,1-6H3

InChIKey

JJRDRFZYKKFYMO-UHFFFAOYSA-N

SMILES

O(C(C)(C)CC)OC(C)(C)CC

LogP

4.7 at 25℃

NIST Chemistry Reference

(CH3)2C(C2H5)OOC(CH3)2C2H5(10508-09-5)

EPA Substance Registry System

Peroxide, bis(1,1-dimethylpropyl) (10508-09-5)

Safety

Hazard Codes 

O,Xn

Risk Statements 

8-22-38-7

Safety Statements 

7-16-17-36/37/39-47-14

RIDADR 

UN 3107 5.2

WGK Germany 

2

RTECS 

SD8300000

HazardClass 

5.2

PackingGroup 

II

HS Code 

29096000

Toxicity

mouse,LD50,oral,1450mg/kg (1450mg/kg),"Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 263, 1986.

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H242Heating may cause a fire

H315Causes skin irritation

H341Suspected of causing genetic defects

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P220Keep/Store away from clothing/…/combustible materials.

P234Keep only in original container.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P281Use personal protective equipment as required.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P411Store at temperatures not exceeding … oC/…oF.

P420Store away from other materials.

P501Dispose of contents/container to..…

Di-tert-amyl peroxide Chemical Properties,Usage,Production

Description

Di-tert-amyl peroxide (DTAP) is a slightly yellowish, mobile liquid. This liquid dialkyl peroxide is used as an initiator (radical source) in the polymerisation of monomers, like e.g. ethylene, styrene, and (meth)acrylates.

Chemical Properties

Colorless to light yellow liquid

Uses

Di-tert-amyl peroxide is commonly used as a radical initiator to induce polymerisation (free radical polymerisation process) for the manufacture of plastic (polypropylene visbreaking, acrylicresins, LDPE/EVA), and as cross-linking agent for the production of resins (resin hardener).