ChemicalBook > CAS DataBase List > 5,5-Dibromo-2,2-dimethyl-1,3-dioxane-4,6-dione
5,5-Dibromo-2,2-dimethyl-1,3-dioxane-4,6-dione
- Product Name
- 5,5-Dibromo-2,2-dimethyl-1,3-dioxane-4,6-dione
- CAS No.
- 66131-14-4
- Chemical Name
- 5,5-Dibromo-2,2-dimethyl-1,3-dioxane-4,6-dione
- Synonyms
- 5,5-dibromo-2,2-dimethyl-1,3-Dioxane-4,6-dione;Dibromomeldrum'sAcid;5,5-Dibromomeldrum's Acid;5,5-Dibromomoldrum's acid;5,5-DIBROMOMELDRUM'S ACID; >98%;2,2-dimethyl-5,5-dibromo-1,3-dioxane-4,6-dione;1,3-Dioxane-4,6-dione, 5,5-dibromo-2,2-dimethyl-;5,5-Dibromomeldrum's Acid (=5,5-Dibromo-2,2-dimethyl-4,6-dioxy-1,3-dioxane);5,5-Dibromomeldrum'sAcid(=5,5-Dibromo-2,2-dimethyl-4,6-dioxy-1,3-dioxane)>5,5-DIBROMOMELDRUM''S ACID (=5,5-DIBROMO-2,2-DIMETHYL-4,6-DIOXO-1,3-DIOXANE) 98+%
- CBNumber
- CB1501887
- Molecular Formula
- C6H6Br2O4
- Formula Weight
- 301.92
- MOL File
- 66131-14-4.mol
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5,5-Dibromo-2,2-dimethyl-1,3-dioxane-4,6-dione Property
- Melting point:
- 75°C
- Boiling point:
- 382.3±42.0 °C(Predicted)
- Density
- 2.052±0.06 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- solubility
- almost transparency in Methanol
- form
- powder to crystal
- color
- White to Almost white
- InChIKey
- HPBNIRVIOCWRDC-UHFFFAOYSA-N
- CAS DataBase Reference
- 66131-14-4
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Safety
- Risk Statements
- 36/37/38-36/37/39-26
- Safety Statements
- 26-36/37/39-36/37/38
- HS Code
- 29322090
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
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N-Bromosuccinimide Price
TCI Chemical
- Product number
- D1710
- Product name
- 5,5-Dibromomeldrum's Acid (=5,5-Dibromo-2,2-dimethyl-4,6-dioxy-1,3-dioxane)
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $155
- Updated
- 2024/03/01
TCI Chemical
- Product number
- D1710
- Product name
- 5,5-Dibromomeldrum's Acid (=5,5-Dibromo-2,2-dimethyl-4,6-dioxy-1,3-dioxane)
- Purity
- >98.0%(T)
- Packaging
- 25g
- Price
- $532
- Updated
- 2024/03/01
TRC
- Product number
- D426393
- Product name
- 5,5-Dibromomeldrum''sacid
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FD60648
- Product name
- 5,5-Dibromomeldrum's Acid
- Packaging
- 5G
- Price
- $85
- Updated
- 2021/12/16
AK Scientific
- Product number
- 4841BB
- Product name
- 5,5-Dibromo-2,2-dimethyl-1,3-dioxane-4,6-dione
- Packaging
- 5g
- Price
- $141
- Updated
- 2021/12/16
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5,5-Dibromo-2,2-dimethyl-1,3-dioxane-4,6-dione Chemical Properties,Usage,Production
Reactions
Selective α-bromination of aldehydes and α′-bromination of α,β-unsaturated ketones; reductive coupling to an ethylenetetracarboxylate.
Synthesis
The preparative method of 5,5-Dibromo-2,2-dimethyl-1,3-dioxane-4,6-dione: by bromination of Meldrum's acid (2,2-Dimethyl-1,3-dioxane-4,6-dione) (commercially available) with Bromine in the presence of Potassium Hydroxide or Sodium Hydroxide eq 1).
References
1. Bloch, R. S 1978, 140.
2. Davidson, D.; Bernhard, S. A. JACS 1948, 70, 3426.
3. Synder, H. R.; Kruse, C. W. JACS 1958, 80, 1942.
4. Novikov, V. L.; Shestak, O. P.; Kamernitskii, A. V.; Elyakov, G. B. Izv. Akad. Nauk SSSR, Ser. Khim. 1982, 476 (CA 1982, 96, 180 832).
5,5-Dibromo-2,2-dimethyl-1,3-dioxane-4,6-dione Preparation Products And Raw materials
Raw materials
Preparation Products
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5,5-Dibromo-2,2-dimethyl-1,3-dioxane-4,6-dione Suppliers
- Tel
- 800-4238616
- Fax
- +1-888-520-1075 / +1-503-283-1987
- sales@tciamerica.com
- Country
- Americas
- ProdList
- 23653
- Advantage
- 75
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View Lastest Price from 5,5-Dibromo-2,2-dimethyl-1,3-dioxane-4,6-dione manufacturers
Career Henan Chemical Co
- Product
- 5,5-DIBROMOMELDRUM'S ACID 66131-14-4
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 100KG
- Release date
- 2018-12-21