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(+)-Bis[(R)-1-phenylethyl]amine

Product Name
(+)-Bis[(R)-1-phenylethyl]amine
CAS No.
23294-41-9
Chemical Name
(+)-Bis[(R)-1-phenylethyl]amine
Synonyms
(R,R)-Bis-(1-phenylethyl)amin;(R)-bis((R)-1-phenylethyl)aMine;(+)-Bis[(R)-1-phenylethyl]amine;(+)-bis[(r)-α-methylbenzyl]amine;(+)-Bis[(R)-1-phenylethyl]amine 99%;(+)-BIS (R)-1-PHENYLETHYL!AMINE HYDRO-;[R-(R*,R*)]-(+)-Bis(α-methylbenzyl)amine;(+)-Bis[(R)-1-phenylethyl]amine, ChiPros;(+)-Bis[(R)-1-phenylethyl]amine, 99% (99+% EE/GLC);(+)-Bis[(R)-1-phenylethyl]amine, ChiPros 99%, ee 98+%
CBNumber
CB1502475
Molecular Formula
C16H19N
Formula Weight
225.34
MOL File
23294-41-9.mol
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(+)-Bis[(R)-1-phenylethyl]amine Property

Melting point:
~260 °C
Boiling point:
86 °C0.05 mm Hg(lit.)
alpha 
199 º (NEAT)
Density 
0.985 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.5523(lit.)
Flash point:
>230 °F
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
pka
8.79±0.29(Predicted)
optical activity
[α]20/D +199.0°, neat
Water Solubility 
Insoluble in water.
BRN 
3590931
CAS DataBase Reference
23294-41-9
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37
WGK Germany 
3
F 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
452823
Product name
(+)-Bis[(R)-1-phenylethyl]amine
Purity
99%
Packaging
1g
Price
$73.4
Updated
2024/03/01
Sigma-Aldrich
Product number
452823
Product name
(+)-Bis[(R)-1-phenylethyl]amine
Purity
99%
Packaging
10g
Price
$461
Updated
2024/03/01
Alfa Aesar
Product number
H27424
Product name
(+)-Bis[(R)-1-phenylethyl]amine, ChiPros?, 99%, ee 98+%
Packaging
1g
Price
$45.65
Updated
2024/03/01
Alfa Aesar
Product number
H27424
Product name
(+)-Bis[(R)-1-phenylethyl]amine, ChiPros?, 99%, ee 98+%
Packaging
5g
Price
$140
Updated
2024/03/01
Alfa Aesar
Product number
H27424
Product name
(+)-Bis[(R)-1-phenylethyl]amine, ChiPros?, 99%, ee 98+%
Packaging
25g
Price
$533
Updated
2024/03/01
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(+)-Bis[(R)-1-phenylethyl]amine Chemical Properties,Usage,Production

Uses

(+)-Bis[(R)-1-phenylethyl]amine play a very extensive role of making chirally optically active drugs and compounds. Also as intermediates.

Uses

(+)-Bis[(R)-1-phenylethyl]amine can be used:

  • In the synthesis of?β-amino acids.
  • In the preparation of chiral C(19)-C(26) and C(27)-C(32) moieties of scytophycin C.
  • To induce enantioselectivity in the deprotonation of prochiral ketones.
  • As a starting material for the synthesis of chiral phenolate ligands through Mannich condensation reaction.
  • In the synthesis of chiral phosphoramidite ligands.
  • To prepare chiral cyclic isoimidium salts, which are further used to synthesize chiral lactones through Diels-Alder reaction.

(+)-Bis[(R)-1-phenylethyl]amine Preparation Products And Raw materials

Raw materials

p-Toluenesulfonic acid Acetonitrile Toluene Sodium borohydride (R)-(+)-1-Phenylethylamine Acetophenone Tetrahydrofuran Ethyl acetate Dichloromethane HEAVY DISTILLATE

Preparation Products

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(+)-Bis[(R)-1-phenylethyl]amine Suppliers

China 59 Germany 2 India 1 Switzerland 1 United Kingdom 1 United States 12 Global 76

23294-41-9, (+)-Bis[(R)-1-phenylethyl]amineRelated Search:

Triethanolamine Triallylamine 2-(2-Aminoethylamino)ethanol Diethyltoluenediamine Bis(2-ethylhexyl)amine N,N-Diisopropylethylamine Triethylenediamine Diethylaminoethanol Triethylenetetramine Dibenzylamine (-)-Bis[(S)-1-phenylethyl]amine (+)-Bis[(R)-1-phenylethyl]amine

  • (+)-Bis[(R)-1-phenylethyl]amine, ChiPros
  • [R-(R*,R*)]-(+)-Bis(α-methylbenzyl)amine
  • (+)-Bis[(R)-1-phenylethyl]amine
  • (+)-Bis[(R)-1-phenylethyl]aMine, ChiPros|r, 99%, ee 98+%
  • (R)-bis((R)-1-phenylethyl)aMine
  • (+)-Bis[(R)-1-phenylethyl]amine 99%
  • (+)-BIS (R)-1-PHENYLETHYL!AMINE HYDRO-
  • (+)-Bis[(R)-1-phenylethyl]amine, 99% (99+% EE/GLC)
  • (R,R)-Bis-(1-phenylethyl)amin
  • (+)-bis[(r)-α-methylbenzyl]amine
  • (+)-Bis[(R)-1-phenylethyl]amine, ChiPros 99%, ee 98+%
  • (+)-Bis[(R)-α-methylbenzyl]amine, [R-(R*,R*)]-(+)-Bis(α-methylbenzyl)amine
  • (+)-BIS[(R)-1-PHENYLETHYL]AMINE, OR (R)-BIS((R)-1-PHENYLETHYL)AMINE
  • Benzenemethanamine, α-methyl-N-[(1R)-1-phenylethyl]-, (αR)-
  • (+)-BIS[(R)-1-PHENYLETHYL]AMINE, OR (R)-BIS((R)-1-PHENYLETHYL)AMINE
  • 23294-41-9