BENZYL CIS-4-AMINOCYCLOHEXYLCARBAMATE
- Product Name
- BENZYL CIS-4-AMINOCYCLOHEXYLCARBAMATE
- CAS No.
- 149423-70-1
- Chemical Name
- BENZYL CIS-4-AMINOCYCLOHEXYLCARBAMATE
- Synonyms
- Benzyl (cis-4-aminocyclohexyl);cis-N-Cbz-1,4-cyclohexanediaMine;N-Cbz-cis-1,4-cyclohexanediamine;CIS-1-N-CBZ-1,4-CYCLOHEXYLDIAMINE;1-N-CBZ-CIS-1,4-CYCLOHEXYLDIAMINE;Trans-1N-Cbz-cyclohexane-1,4-diaMine;BENZYL CIS-4-AMINOCYCLOHEXYLCARBAMATE;benzyl (1s,4s)-4-aminocyclohexylcarbamate;cis-4-(Benzyloxycarbonylamino)cyclohexylamine;cis-4-(BenzyloxycarbonylaMino)cyclohexylaMine, 97%
- CBNumber
- CB1691616
- Molecular Formula
- C14H20N2O2
- Formula Weight
- 248.32
- MOL File
- 149423-70-1.mol
BENZYL CIS-4-AMINOCYCLOHEXYLCARBAMATE Property
- Boiling point:
- 409.5±44.0 °C(Predicted)
- Density
- 1.13±0.1 g/cm3(Predicted)
- pka
- 12.23±0.40(Predicted)
Safety
- HS Code
- 2924297099
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
N-Bromosuccinimide Price
- Product number
- B233800
- Product name
- Benzylcis-4-aminocyclohexylcarbamate
- Packaging
- 250mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- FB56992
- Product name
- Benzyl (cis-4-aminocyclohexyl)carbamate
- Packaging
- 50mg
- Price
- $63
- Updated
- 2021/12/16
- Product number
- FB56992
- Product name
- Benzyl (cis-4-aminocyclohexyl)carbamate
- Packaging
- 100mg
- Price
- $101
- Updated
- 2021/12/16
- Product number
- FB56992
- Product name
- Benzyl (cis-4-aminocyclohexyl)carbamate
- Packaging
- 250mg
- Price
- $125
- Updated
- 2021/12/16
- Product number
- 089463
- Product name
- Benzyl cis-4-aminocyclohexylcarbamate
- Packaging
- 1g
- Price
- $198
- Updated
- 2021/12/16
BENZYL CIS-4-AMINOCYCLOHEXYLCARBAMATE Chemical Properties,Usage,Production
Synthesis
509143-03-7
149423-70-1
Step B: Synthesis of cis-(4-amino-cyclohexyl)-carbamic acid benzyl ester. To a solution of cis-(4-tert-butoxycarbonylamino-cyclohexyl)-carbamic acid benzyl ester (6.2 g, 0.018 mol) in dichloromethane (40 mL) was added trifluoroacetic acid (2.7 mL, 0.36 mol). The reaction mixture was stirred at room temperature for 4 hours. Upon completion of the reaction, the excess solvent was removed by rotary evaporation and the resulting oil was dissolved in dichloromethane (30 mL). The organic layer was extracted with dilute aqueous sodium hydroxide/aqueous sodium bicarbonate solution (30 mL). The aqueous layer was back-extracted twice with dichloromethane, and the organic layers were combined, dried over anhydrous magnesium sulfate, and concentrated to give cis-(4-amino-cyclohexyl)-carbamic acid benzyl ester (4.3 g, 97%) as a colorless oil. The product was used directly in the next reaction without further purification.ESI MS m/z 249.2 [M + H]+.
References
[1] Patent: EP1464335, 2004, A2. Location in patent: Page/Page column 293
BENZYL CIS-4-AMINOCYCLOHEXYLCARBAMATE Preparation Products And Raw materials
Raw materials
Preparation Products
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