ChemicalBook > CAS DataBase List > 1-BROMO-1-PROPENE

1-BROMO-1-PROPENE

Product Name
1-BROMO-1-PROPENE
CAS No.
590-14-7
Chemical Name
1-BROMO-1-PROPENE
Synonyms
1-Bromopropene;(1E)-1-Bromo-1-propene;1-Bromo-1-propene, cis/trans mixture;1-bromo-propen;1-Brom-1-propen;1-bromo-1-propen;PROPENYL BROMIDE;1-bromopropylene;1-Propenylbromid;1-BROMO-1-PROPENE
CBNumber
CB1742369
Molecular Formula
C3H5Br
Formula Weight
120.98
MOL File
590-14-7.mol
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1-BROMO-1-PROPENE Property

Melting point:
−116 °C(lit.)
Boiling point:
64-65 °C(lit.)
Density 
1.420 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.454
Flash point:
5 °F
storage temp. 
2-8°C
form 
clear liquid
color 
Colorless to Light yellow to Light orange
BRN 
1719096
CAS DataBase Reference
590-14-7
EPA Substance Registry System
1-Propene, 1-bromo- (590-14-7)
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Safety

Hazard Codes 
F,Xi
Risk Statements 
11-36/37/38
Safety Statements 
26-36
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
RTECS 
UC7080000
F 
8
HazardClass 
3.1
PackingGroup 
II
HS Code 
29033919
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
B78203
Product name
1-Bromo-1-propene (cis and trans)
Purity
98%
Packaging
100g
Price
$587
Updated
2024/03/01
TCI Chemical
Product number
B1038
Product name
1-Bromo-1-propene (cis- and trans- mixture)
Purity
>97.0%(GC)
Packaging
5g
Price
$79
Updated
2024/03/01
TCI Chemical
Product number
B1038
Product name
1-Bromo-1-propene (cis- and trans- mixture)
Purity
>97.0%(GC)
Packaging
25g
Price
$237
Updated
2024/03/01
TRC
Product number
P769100
Product name
1-PropenylBromide(mixtureofisomers)
Packaging
10g
Price
$75
Updated
2021/12/16
AK Scientific
Product number
4765AL
Product name
1-Bromo-1-propene
Packaging
5g
Price
$126
Updated
2021/12/16
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1-BROMO-1-PROPENE Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS TO LIGHT YELLOW LIQUID

Uses

1-Propenyl bromide is a useful building block, especially when a 3 carbon addition is required, such as its use in the synthesis of the pharmaceutical spilanthol.

Uses

1-Bromo-1-propene upon n-BuLi treatment generates the propynyllithium anion, in situ, which later undergoes nucleophilic addition reactions. Some of its other applications are:

  • Synthesis of organic reagents such as methyl but-2-ynoate and 1-iodopropyne.
  • Preparation o f intermediates in the total synthesis of (+)-aphanamol I and skyllamycins A-C.
  • Synthesis of allylated pyrazoles, aryl alkynyl sulfides and allenamides.

Synthesis Reference(s)

The Journal of Organic Chemistry, 56, p. 4066, 1991 DOI: 10.1021/jo00012a053

1-BROMO-1-PROPENE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-BROMO-1-PROPENE Suppliers

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View Lastest Price from 1-BROMO-1-PROPENE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
1-Bromo-1-propene (cis and trans) 98% 590-14-7
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

590-14-7, 1-BROMO-1-PROPENERelated Search:

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  • 1-BROMO-1-PROPENE, 98%, MIXTURE OF ISOME RS
  • 1-Bromo-1-Propene,MixtureOfIsomers98%
  • 1-Bromo-1-propene, mixture of isomers, stabilized, 95%
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  • 1-Bromo-1-propene (cis- and trans- mixture)
  • 1-Bromo-1-propene, 95%, mixture of isomers, stabilized
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  • 1-Bromo-1-propene (cis and trans),1-Propenyl bromide
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