ChemicalBook > CAS DataBase List > N,N-Dimethylcyclohexylamine

N,N-Dimethylcyclohexylamine

Product Name
N,N-Dimethylcyclohexylamine
CAS No.
98-94-2
Chemical Name
N,N-Dimethylcyclohexylamine
Synonyms
DMCHA;Dimethylcyclohexylamine;PC8;N,N-Dimethylcyclohexanamine;Polycat 8;DIMETHYLAMINOCYCLOHEXANE;N,N-Dimethylaminocyclohexane;Cyclohexanamine,N,N-dimethyl-;KL3;NiaxC8
CBNumber
CB1854754
Molecular Formula
C8H17N
Formula Weight
127.23
MOL File
98-94-2.mol
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N,N-Dimethylcyclohexylamine Property

Melting point:
-60 °C
Boiling point:
158-159 °C (lit.)
Density 
0.849 g/mL at 25 °C (lit.)
vapor pressure 
3.6 mm Hg ( 20 °C)
refractive index 
n20/D 1.454(lit.)
Flash point:
108 °F
storage temp. 
Store below +30°C.
solubility 
10 g/L (20°C)
form 
Liquid
pka
pK1:10.72(+1) (25°C)
color 
Clear
PH
12 (5g/l, H2O, 20℃)
explosive limit
3.6-19%(V)
Water Solubility 
10 g/L (20 ºC)
FreezingPoint 
<-77℃
Sensitive 
Air Sensitive
BRN 
1919922
Dielectric constant
2.8599999999999999
InChIKey
SVYKKECYCPFKGB-UHFFFAOYSA-N
LogP
2.31 at 25℃
CAS DataBase Reference
98-94-2(CAS DataBase Reference)
NIST Chemistry Reference
Cyclohexanamine, N,N-dimethyl-(98-94-2)
EPA Substance Registry System
N,N-Dimethylcyclohexylamine (98-94-2)
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Safety

Hazard Codes 
C,N,T
Risk Statements 
10-20/21/22-34-50/53-23/24-22
Safety Statements 
26-28-36/37/39-45-61-28A-16
RIDADR 
UN 2264 8/PG 2
WGK Germany 
1
RTECS 
GX1198000
Autoignition Temperature
419 °F
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29213010
Hazardous Substances Data
98-94-2(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 272 mg/kg LD50 dermal Rat > 400 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

H311Toxic in contact with skin

H314Causes severe skin burns and eye damage

H330Fatal if inhaled

H400Very toxic to aquatic life

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
290629
Product name
N,N-Dimethylcyclohexylamine
Purity
99%
Packaging
25ml
Price
$24.7
Updated
2024/03/01
Sigma-Aldrich
Product number
290629
Product name
N,N-Dimethylcyclohexylamine
Purity
99%
Packaging
1l
Price
$105
Updated
2024/03/01
TCI Chemical
Product number
D0705
Product name
N,N-Dimethylcyclohexylamine
Purity
>98.0%(GC)(T)
Packaging
25mL
Price
$22
Updated
2024/03/01
TCI Chemical
Product number
D0705
Product name
N,N-Dimethylcyclohexylamine
Purity
>98.0%(GC)(T)
Packaging
500mL
Price
$47
Updated
2024/03/01
Alfa Aesar
Product number
L14521
Product name
N,N-Dimethylcyclohexylamine, 98+%
Packaging
25ml
Price
$25.65
Updated
2024/03/01
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N,N-Dimethylcyclohexylamine Chemical Properties,Usage,Production

Chemical Properties

CLEAR LIQUID

Uses

Dimethylcyclohexylamine is used in polyurethane plastics and textiles and as a chemical intermediate.

Uses

N,N-Dimethylcyclohexylamine has been used:

  • as switchable hydrophilicity solvent (SHS) for the extraction of lipids from freeze-dried samples of Botryococcus braunii microalgae for biofuel production
  • as catalyst in three-component organocatalyzed Strecker reaction on water

Application

The curing temperature of baking finishes comprising polyurethane-forming substances can be reduced by 50 – 80 ℃ by adding weakly acidic derivatives of N,N-Dimethylcyclohexylamine. Like pyridine, dimethylcyclohexylamine catalyzes certain reactions and is slightly more efficient than pyridine in the preparation of acid chlorides with thionyl chloride. It can be used as corrosion inhibitor and as an antioxidant in fuel oils.

Definition

ChEBI: A tertiary amine consisting of cyclohexane having a dimethylamino substituent.

Production Methods

N,N-Dimethylcyclohexylamine is manufactured either by the reaction of methyl chloride or formaldehyde and hydrogen with cyclohexylamine (HSDB 1989).

Synthesis Reference(s)

Journal of the American Chemical Society, 93, p. 2897, 1971 DOI: 10.1021/ja00741a013
Organic Syntheses, Coll. Vol. 6, p. 499, 1988

General Description

Colorless liquid with a musky ammonia odor. Less dense than water.

Air & Water Reactions

Highly flammable. Water soluble.

Reactivity Profile

N,N-Dimethylcyclohexylamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Health Hazard

Inhalation of high concentration of vapor will will produce irritation of the respiratory tract and lungs. Inhalation of large quantities of vapor may be fatal.

Health Hazard

Industrial hygiene studies in polyurethane manufacturing plants have identified levels of 0.007-0.81 p.p.m. N-N-dimethylcyclohexylamine in air; however, these levels were not regarded as hazardous (Reisdorf and Haggerty 1982). There are no current exposure standards for N-N-dimethylcyclohexylamine and no documentation of human toxicological effects.

Fire Hazard

Behavior in Fire: Dangerous when exposed to heat or flame. Can react vigorously with oxidizing materials.

Industrial uses

This amine is used as a catalyst in the production of polyurethane foams. It is also used as an intermediate for rubber accelerators and dyes and in the treatment of textiles.

Safety Profile

Poison by ingestion. Moderately toxic by inhalation. Whenheated to decomposition it emits toxic fumes of NOx

Metabolism

There is no record of any metabolic studies with MTV-dime thy ley clohexylamine. However, one can predict that it would be oxidized to the N-oxide by either a cytochrome P-450 system (Damani 1982) or the flavin-containing monooxygenase (Ziegler 1988). Mixed function oxidase enzymes would be expected to produce demethylation (Lindeke and Cho 1982). Many studies describe the metabolism of the parent compound cyclohexylamine (Henderson 1990).

N,N-Dimethylcyclohexylamine Preparation Products And Raw materials

Raw materials

Preparation Products

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N,N-Dimethylcyclohexylamine Suppliers

Shanghai YouPeng Chemical Co. Ltd.
Tel
021-69005955 13701776567
Fax
021-69005775
Email
youpengchem@163.com
Country
China
ProdList
4293
Advantage
56
Tonglan New Energy Technology Development (Shandong) Group Co., Ltd
Tel
13026585814
Email
13026585814@163.com
Country
China
ProdList
104
Advantage
58
Tianjin Zhongxin Chemtech Co., Ltd.
Tel
022-66880623
Fax
86(0)22-66880086
Email
sales@tjzxchem.com
Country
China
ProdList
613
Advantage
60
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Chang Zhou Chemistar Chemistry Technology Co.,Ltd
Tel
+86 (519) 8689-6136
Fax
+86 (519) 8205-9235
Email
kr@krchemistar.com
Country
China
ProdList
181
Advantage
55
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
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View Lastest Price from N,N-Dimethylcyclohexylamine manufacturers

Jinan Finer Chemical Co., Ltd
Product
N,N-Dimethylcyclohexylamine 98-94-2
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
99%
Supply Ability
5000mt/year
Release date
2021-07-27
Hebei Weibang Biotechnology Co., Ltd
Product
N,N-Dimethylcyclohexylamine 98-94-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2023-02-03
Hebei Mojin Biotechnology Co., Ltd
Product
N,N-Dimethylcyclohexylamine 98-94-2
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-28

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