ChemicalBook > CAS DataBase List > methyl (3beta,19alpha,20alpha)-16,17-didehydro-10,11-dimethoxy-19-methyloxayohimban-16-carboxylate

methyl (3beta,19alpha,20alpha)-16,17-didehydro-10,11-dimethoxy-19-methyloxayohimban-16-carboxylate

Product Name
methyl (3beta,19alpha,20alpha)-16,17-didehydro-10,11-dimethoxy-19-methyloxayohimban-16-carboxylate
CAS No.
131-02-2
Chemical Name
methyl (3beta,19alpha,20alpha)-16,17-didehydro-10,11-dimethoxy-19-methyloxayohimban-16-carboxylate
Synonyms
Reserpilin;Reserpiline;Elliptamine;Einecs 205-005-3;Methyl (3?,19?,20?)-16,17-didehydro-10,11-dimethoxy-19-methyloxayohimban-16-carboxylate;Methyl 16,17-didehydro-10,11-dimethoxy-19alpha-methyl-18-oxa-3beta,20alpha-yohimban-16-carboxylat;(3β,20α)-16,17-Didehydro-19α-methyl-10,11-dimethoxy-18-oxayohimban-16-carboxylic acid methyl ester;(3β,20α)-16,17-Didehydro-10,11-dimethoxy-19α-methyl-18-oxayohimban-16-carboxylic acid methyl ester;Oxayohimban-16-carboxylic acid, 16,17-didehydro-10,11-dimethoxy-19-methyl-, methyl ester, (3-beta,19-alpha,20-alpha)-;4H-Indolo[2,3-a]pyrano[3,4-g]quinolizine-1-carboxylic acid, 4a,5,7,8,13,13b,14,14a-octahydro-10,11-dimethoxy-4-methyl-, methyl ester, (4S,4aS,13bR,14aS)-
CBNumber
CB1916199
Molecular Formula
C23H28N2O5
Formula Weight
412.48
MOL File
131-02-2.mol
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methyl (3beta,19alpha,20alpha)-16,17-didehydro-10,11-dimethoxy-19-methyloxayohimban-16-carboxylate Property

alpha 
D20 -38° (ethanol); -14° (c = 1.5 in pyridine); -12° (c = 1.7 in chloroform)
Boiling point:
180-185 °C(Press: 0.01 Torr)
Density 
1.31±0.1 g/cm3(Predicted)
storage temp. 
Store at -20°C
pka
17.95±0.60(Predicted)
form 
A solid
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Safety

RIDADR 
1544
HazardClass 
6.1(b)
PackingGroup 
III
Toxicity
guinea pig,LDLo,intravenous,19mg/kg (19mg/kg),Arzneimittel-Forschung. Drug Research. Vol. 23, Pg. 600, 1973.
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
M451310
Product name
Methyl(3beta,19alpha,20alpha)-16,17-didehydro-10,11-dimethoxy-19-methyloxayohimban-16-carboxylate
Packaging
1mg
Price
$45
Updated
2021/12/16
TRC
Product number
M451310
Product name
Methyl(3beta,19alpha,20alpha)-16,17-didehydro-10,11-dimethoxy-19-methyloxayohimban-16-carboxylate
Packaging
2mg
Price
$60
Updated
2021/12/16
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methyl (3beta,19alpha,20alpha)-16,17-didehydro-10,11-dimethoxy-19-methyloxayohimban-16-carboxylate Chemical Properties,Usage,Production

Description

An amorphous alkaloid present in Rauwolfia canescens and R. serpentina, the alkaloid forms several crystalline salts and derivatives including the hydrochloride, m.p. 205-7°C; [α]24D - 40° (c 0.44, EtOH); the tartrate, m.p. 190- 2°C; [α]20D - 50° (c 1.0, H20); the oxalate, m.p. 252°C; [α]20D - 4° (c 0.2, aqueous EtOH); the picrate, m.p. 173°C and the di-p-toluyl-L-tartrate, m.p. 194- 5° C (dec.).

Definition

ChEBI: Reserpiline is a yohimban alkaloid.

References

Klohs et al., Chem. & Ind., 1264 (1954)
Stoll, Hoffmann, Brunner., Helv. Chim. Acta, 38,270 (1955)
Shamma, Richey., J. Amer. Chem. Soc., 85,2507 (1963)

methyl (3beta,19alpha,20alpha)-16,17-didehydro-10,11-dimethoxy-19-methyloxayohimban-16-carboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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methyl (3beta,19alpha,20alpha)-16,17-didehydro-10,11-dimethoxy-19-methyloxayohimban-16-carboxylate Suppliers

China 5 United States 4 Global 9
BOC Sciences
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131-02-2, methyl (3beta,19alpha,20alpha)-16,17-didehydro-10,11-dimethoxy-19-methyloxayohimban-16-carboxylate Related Search:


  • Reserpiline
  • (3β,20α)-16,17-Didehydro-10,11-dimethoxy-19α-methyl-18-oxayohimban-16-carboxylic acid methyl ester
  • (3β,20α)-16,17-Didehydro-19α-methyl-10,11-dimethoxy-18-oxayohimban-16-carboxylic acid methyl ester
  • Einecs 205-005-3
  • Elliptamine
  • Methyl 16,17-didehydro-10,11-dimethoxy-19alpha-methyl-18-oxa-3beta,20alpha-yohimban-16-carboxylat
  • Oxayohimban-16-carboxylic acid, 16,17-didehydro-10,11-dimethoxy-19-methyl-, methyl ester, (3-beta,19-alpha,20-alpha)-
  • Reserpilin
  • 4H-Indolo[2,3-a]pyrano[3,4-g]quinolizine-1-carboxylic acid, 4a,5,7,8,13,13b,14,14a-octahydro-10,11-dimethoxy-4-methyl-, methyl ester, (4S,4aS,13bR,14aS)-
  • Methyl (3?,19?,20?)-16,17-didehydro-10,11-dimethoxy-19-methyloxayohimban-16-carboxylate
  • 131-02-2