perphthalic acid
- Product Name
- perphthalic acid
- CAS No.
- 2311-91-3
- Chemical Name
- perphthalic acid
- Synonyms
- perphthalic acid;monoperphthalic acid;Monoperoxyphthalic acid;2-Carboperoxybenzoic acid;Benzenecarboperoxoic acid, 2-carboxy-;2-Carboxy-1-benzeneperoxycarboxylic acid
- CBNumber
- CB1937576
- Molecular Formula
- C8H6O5
- Formula Weight
- 182.13
- MOL File
- 2311-91-3.mol
perphthalic acid Property
- Melting point:
- 111 °C (decomp)(Solv: ligroine (8032-32-4); ethyl ether (60-29-7)(3:1))
- Boiling point:
- 407.3±47.0 °C(Predicted)
- Density
- 1.507±0.06 g/cm3(Predicted)
- pka
- 3.32±0.36(Predicted)
- EPA Substance Registry System
- Benzenecarboperoxoic acid, 2-carboxy- (2311-91-3)
N-Bromosuccinimide Price
- Product number
- M566850
- Product name
- MonoperoxyphthalicAcid
- Packaging
- 1g
- Price
- $1260
- Updated
- 2021/12/16
- Product number
- CHM0078217
- Product name
- 2-CARBOPEROXYBENZOIC ACID
- Purity
- 95.00%
- Packaging
- 10G
- Price
- $1334.03
- Updated
- 2021/12/16
- Product number
- 60513
- Product name
- MonoperoxyphthalicAcid
- Packaging
- 100mg
- Price
- $2200
- Updated
- 2021/12/16
- Product number
- CHM0078217
- Product name
- 2-CARBOPEROXYBENZOIC ACID
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $909.56
- Updated
- 2021/12/16
- Product number
- SC-69883
- Product name
- 2-CARBONOPEROXOYLBENZOICACID
- Purity
- 95
- Packaging
- 5g
- Price
- $1250
- Updated
- 2021/12/16
perphthalic acid Chemical Properties,Usage,Production
Uses
Monoperoxyphthalic Acid is used as a reagent in the synthesis of 4-Hydroxyretinoic Acid (H953300); a novel substrate for human liver microsomal UDP-glucuronosyltransferase(s) and recombinant UGT2B7.
Application
Mild peroxycarboxylic acids for effecting epoxidation of π-bonds, Baeyer-Villiger reactions, and the oxidation of diverse heteroatoms including nitrogen, sulfur, and selenium.
Preparation
Monoperoxyphthalic acid is prepared as required by the addition of phthalic anhydride to 30% aqueous Hydrogen Peroxide, in the presence of Sodium Hydroxide or Sodium Carbonate. Magnesium monoperoxyphthalate is prepared by the addition of phthalic anhydride and Magnesium Oxide to aqueous hydrogen peroxide.
Drying: magnesium monoperoxyphthalate should be dried over calcium chloride in a desiccator.
Synthesis Reference(s)
The Journal of Organic Chemistry, 24, p. 1354, 1959 DOI: 10.1021/jo01091a612
storage
Magnesium monoperoxyphthalate may be stored at room temperature. All work should be carried in an efficient fume hood behind a polycarbonate safety screen.
perphthalic acid Preparation Products And Raw materials
Raw materials
Preparation Products
perphthalic acid Suppliers
- Tel
- --
- Fax
- --
- chemicals@usbio.net
- Country
- United States
- ProdList
- 6214
- Advantage
- 80