ChemicalBook > CAS DataBase List > (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE

(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE

Product Name
(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE
CAS No.
364732-88-7
Chemical Name
(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE
Synonyms
(R)-Phanephos, 98%, ee 98%;(Rp)-(-)-4,12-Bis(diphenylphosphino)[2.2]paracyclophane;(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane,99%e.e.;(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%;(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%,99%ee;Phosphine, 1,1'-(tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diyl)bis[1,1-diphenyl-, stereoisomer
CBNumber
CB1972821
Molecular Formula
C40H34P2
Formula Weight
576.65
MOL File
364732-88-7.mol
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(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE Property

Melting point:
222-225°C
alpha 
-62.6° (c 3.11, CH2Cl2)
storage temp. 
Inert atmosphere,Room Temperature
form 
solid
color 
white
optical activity
[α]/D -34±4°, c = 1 in chloroform
CAS DataBase Reference
364732-88-7
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Safety

Hazard Codes 
Xi
Risk Statements 
37
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
682144
Product name
(R)-(–)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane
Purity
96%
Packaging
100mg
Price
$120
Updated
2024/03/01
Sigma-Aldrich
Product number
682144
Product name
(R)-(–)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane
Purity
96%
Packaging
500mg
Price
$547
Updated
2024/03/01
Alfa Aesar
Product number
H25812
Product name
(R)-Phanephos, 98%, ee 98%
Packaging
250mg
Price
$139.18
Updated
2021/12/16
Strem Chemicals
Product number
15-0425
Product name
(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (R)-PHANEPHOS
Packaging
100mg
Price
$102
Updated
2024/03/01
Strem Chemicals
Product number
15-0425
Product name
(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (R)-PHANEPHOS
Packaging
500mg
Price
$412
Updated
2024/03/01
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(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE Chemical Properties,Usage,Production

Uses

Efficient ligand for asymmetric hydrogentation of dehydroamino acids, methyl esters and keytones.

(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE Suppliers

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View Lastest Price from (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE manufacturers

Career Henan Chemical Co
Product
(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE, 96% 364732-88-7
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-08-08

364732-88-7, (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANERelated Search:


  • (R)-Phanephos, 98%, ee 98%
  • (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane,99%e.e.
  • (R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%
  • (Rp)-(-)-4,12-Bis(diphenylphosphino)[2.2]paracyclophane
  • Phosphine, 1,1'-(tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diyl)bis[1,1-diphenyl-, stereoisomer
  • (R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%,99%ee
  • 364732-88-7
  • Chiral Phosphine
  • PHANEPhos Series