CHLOROMETHYL PHENYL SULFOXIDE

Product Name: CHLOROMETHYL PHENYL SULFOXIDE
CAS No.: 7205-94-9
Chemical Name: CHLOROMETHYL PHENYL SULFOXIDE
Synonyms: Einecs 230-580-2;CHLOROMETHYL PHENYL SULFOXIDE;Phenyl (chloromethyl) sulfoxide;[(Chloromethyl)sulfinyl]benzene;[(chloromethyl)sulphinyl]benzene;Benzene, ((chloromethyl)sulfinyl)-;Chloromethyl phenyl sulfoxide >=97.0%
CBNumber: CB2111210
Molecular Formula: C7H7ClOS
Formula Weight: 174.65
MOL File: 7205-94-9.mol

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CHLOROMETHYL PHENYL SULFOXIDE Property

Melting point:: 33-35 °C
Boiling point:: 109-111 °C/0.01 mmHg
Density: 1.35±0.1 g/cm3(Predicted)
Flash point:: 100 °C
storage temp.: -20°C
solubility: sol CHCl3 and THF.
form: solid
BRN: 1617664
EPA Substance Registry System: Benzene, [(chloromethyl)sulfinyl]- (7205-94-9)

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Safety

Safety Statements: 22-24/25
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

AK Scientific

Product number: 5388CA
Product name: Chloromethyl phenyl sulfoxide
Packaging: 1g
Price: $534
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0067366
Product name: CHLOROMETHYL PHENYL SULFOXIDE
Purity: 95.00%
Packaging: 1G
Price: $711.76
Updated: 2021/12/16

Crysdot

Product number: CD12039766
Product name: ((Chloromethyl)sulfinyl)benzene
Purity: 95+%
Packaging: 1g
Price: $300
Updated: 2021/12/16

Alichem

Product number: 7205949
Product name: ((Chloromethyl)sulfinyl)benzene
Packaging: 1g
Price: $400
Updated: 2021/12/16

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CHLOROMETHYL PHENYL SULFOXIDE Chemical Properties,Usage,Production

Uses

Chloromethyl phenyl sulfoxide has been used in the preparation of:

1-chloroalkyl sulfoxides
starting material for the synthesis alkyl sulfoxides and thiol ester acyl anion equivalent

Preparation

Chlorination of methylphenyl sulfoxide with sulfonyl chloride in dichloromethane or N-chlorosuccinimide in chloroform gives Chloromethyl phenyl sulfoxide in good yields. A one-step process starting from phenyl sulfide involves chlorination with sulfonyl chloride in dichloromethane followed by oxidation with the same reagent in the presence of wet silica gel. Another method uses silver(I) nitrate and sulfonyl chloride in acetonitrile.

Synthesis Reference(s)

Journal of the American Chemical Society, 90, p. 4496, 1968 DOI: 10.1021/ja01018a078
Synthesis, p. 831, 1986
Tetrahedron Letters, 17, p. 613, 1976

General Description

Chloromethyl phenyl sulfoxide has synthetic potential and exhibits unusual stereochemical specificity. Stereospecific hydroxyalkylation of chloromethyl phenyl sulfoxide has been investigated.

CHLOROMETHYL PHENYL SULFOXIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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CHLOROMETHYL PHENYL SULFOXIDE Suppliers

China 21 Switzerland 1 United Kingdom 1 United States 2 Global 25

Shanghai Hanhong Scientific Co.,Ltd.

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Sigma-Aldrich

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Suzhou Victorypharm Co.,Ltd.

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7205-94-9, CHLOROMETHYL PHENYL SULFOXIDERelated Search:

Phenyl sulfoxide CHLOROMETHYL PHENYL SULFONE SPECS AK-823/41252283 4-[2-CHLORO-2-(PHENYLSULFONYL)ETHYL]-1,4-OXAZINAN-4-IUM CHLORIDE 1-CHLORO-2-PHENYLVINYL 4-METHYLPHENYL SULFONE [(1-CHLORO-4-PHENYLBUTA-1,3-DIENYL)SULFINYL]BENZENE CHLOROMETHYL PHENYL SULFOXIDE 1-chloro-4-[(chloromethyl)sulphonyl]benzene Sulfoxide, pentachlorophenyl trichloromethyl 3,5-BIS(TRIFLUOROMETHYL)PHENYL CHLOROMETHYL SULFONE 1,2-DICHLOROVINYL4-METHYLPHENYLSULFONE P-TOLUENESULFONYLMETHYL CHLORIDE 1-[(CHLOROMETHYL)SULFONYL]NAPHTHALENE

CHLOROMETHYL PHENYL SULFOXIDE

[(chloromethyl)sulphinyl]benzene

[(Chloromethyl)sulfinyl]benzene

Phenyl (chloromethyl) sulfoxide

Benzene, ((chloromethyl)sulfinyl)-

Einecs 230-580-2

Chloromethyl phenyl sulfoxide >=97.0%

7205-94-9

C6H5SOCH2Cl

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