ChemicalBook > CAS DataBase List > DI-TERT-BUTYLPIPERAZINE-1,4-DICARBOXYLATE

DI-TERT-BUTYLPIPERAZINE-1,4-DICARBOXYLATE

Product Name
DI-TERT-BUTYLPIPERAZINE-1,4-DICARBOXYLATE
CAS No.
76535-75-6
Chemical Name
DI-TERT-BUTYLPIPERAZINE-1,4-DICARBOXYLATE
Synonyms
1,4-Bis(Boc)piperazine;DI-TERT-BUTYLPIPERAZINE-1;1,4-Bis(tert-butoxycarbonyl)piperazine;1,4-Bis (t-butyloxycarbonyl) piperazine;DI-TERT-BUTYLPIPERAZINE-1,4-DICARBOXYLATE;1,4-Di-tert-butyl piperazine-1,4-dicarboxylate;1,4-piperazinedicarboxylic acid, bis(1,1-dimethylethyl) ester;1,4-Piperazinedicarboxylic acid, 1,4-bis(1,1-dimethylethyl) ester
CBNumber
CB21229864
Molecular Formula
C14H26N2O4
Formula Weight
286.37
MOL File
76535-75-6.mol
More
Less

DI-TERT-BUTYLPIPERAZINE-1,4-DICARBOXYLATE Property

Boiling point:
353.3±17.0 °C(Predicted)
Density 
1.089±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
0.03±0.70(Predicted)
Appearance
White to off-white Solid
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Usbiological
Product number
411288
Product name
1,4-Di-tert-butyl piperazine-1,4-dicarboxylate
Packaging
100mg
Price
$305
Updated
2021/12/16
AK Scientific
Product number
B999
Product name
1,4-Di-tert-butylpiperazine-1,4-dicarboxylate
Packaging
1g
Price
$20
Updated
2021/12/16
Oakwood
Product number
212849
Product name
Di-tert-butylpiperazine-1,4-dicarboxylate
Purity
95%
Packaging
1g
Price
$28
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD43643
Product name
1,4-Di-tert-butyl piperazine-1,4-dicarboxylate
Packaging
5G
Price
$91.6
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD43643
Product name
1,4-Di-tert-butyl piperazine-1,4-dicarboxylate
Packaging
10g
Price
$146.6
Updated
2021/12/16
More
Less

DI-TERT-BUTYLPIPERAZINE-1,4-DICARBOXYLATE Chemical Properties,Usage,Production

Synthesis

110-85-0

24424-99-5

76535-75-6

General procedure for the synthesis of 1,4-bis(tert-butoxycarbonyl)piperazine from piperazine and di-tert-butyl dicarbonate: In a 10 mL round bottom flask, EtOH (5 mL), di-tert-butyl dicarbonate (1-2 mmol), nano-Fe3O4 catalyst (3 mol%, 0.007 g) and piperazine (1 mmol) were added. The reaction mixture was stirred at room temperature until complete (refer to Table 3 for reaction times). After completion of the reaction, the nano-Fe3O4 catalyst was separated using external magnet adsorption. The separated solution was dried and the solvent was concentrated, and the resulting crude product was recrystallized with hexane or ethyl acetate (5 mL) to give pure 1,4-bis(tert-butoxycarbonyl)piperazine. The recovered Fe3O4 nanocatalyst was washed with EtOH and dried, and could be reused. The catalyst was recycled six times without significant changes in the reaction yield and time.

References

[1] Tetrahedron Letters, 2009, vol. 50, # 46, p. 6244 - 6246
[2] Synthetic Communications, 2012, vol. 42, # 1, p. 25 - 32
[3] Tetrahedron Letters, 2007, vol. 48, # 47, p. 8318 - 8322
[4] Comptes Rendus Chimie, 2013, vol. 16, # 11, p. 962 - 966
[5] Chinese Journal of Catalysis, 2013, vol. 34, # 9, p. 1730 - 1733

DI-TERT-BUTYLPIPERAZINE-1,4-DICARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

DI-TERT-BUTYLPIPERAZINE-1,4-DICARBOXYLATE Suppliers

China 49 India 2 Russia 1 United Kingdom 1 United States 6 Global 59
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
Email
sales@chemreagents.com
Country
United States
ProdList
10186
Advantage
62
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14101
Advantage
59
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
18209
Advantage
56
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-6206333 13167063860
Fax
021-50323701
Email
anhua.mao@aladdin-e.com
Country
China
ProdList
25003
Advantage
65
AllyChem Co., Ltd.
Tel
0411-62313318 13942603642
Fax
0411-87549748
Email
info@allychem.com
Country
China
ProdList
1028
Advantage
65
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
Shanghai Xingui Biotechnology Co., Ltd.
Tel
15121041756
Email
xingui2022@126.com
Country
China
ProdList
9979
Advantage
58
Changsha Luxing Bio-Chem Technology Co., Ltd.
Tel
0731-88827538 15873153880
Fax
0731-88827238
Email
luxingbc@126.com
Country
China
ProdList
2001
Advantage
65
Cool Pharm, Ltd
Tel
021-60455363 18019463053
Fax
50966098
Email
sales@coolpharm.com
Country
China
ProdList
12346
Advantage
58

76535-75-6, DI-TERT-BUTYLPIPERAZINE-1,4-DICARBOXYLATERelated Search:


  • DI-TERT-BUTYLPIPERAZINE-1,4-DICARBOXYLATE
  • 1,4-Di-tert-butyl piperazine-1,4-dicarboxylate
  • 1,4-Bis(tert-butoxycarbonyl)piperazine
  • 1,4-Bis(Boc)piperazine
  • 1,4-Piperazinedicarboxylic acid, 1,4-bis(1,1-dimethylethyl) ester
  • DI-TERT-BUTYLPIPERAZINE-1
  • 1,4-Bis (t-butyloxycarbonyl) piperazine
  • 1,4-piperazinedicarboxylic acid, bis(1,1-dimethylethyl) ester
  • 76535-75-6