1-(2-nitrophenyl)ethanol
- Product Name
- 1-(2-nitrophenyl)ethanol
- CAS No.
- 3205-25-2
- Chemical Name
- 1-(2-nitrophenyl)ethanol
- Synonyms
- NSC 47195;1-(2-Nitrophenyl);1-(2-Nitrophenyl)ethan-1-ol;alpha-(2-Nitrophenyl)ethanol;rac-1-(2-Nitrophenyl)ethanol;2-Nitro-α-methylbenzyl Alcohol;α-Methyl-2-nitrobenzyl Alcohol;1-(2-Nitrophenyl)ethyl Alcohol;2-methyl-2-nitroBenzenemethanol;α-Methyl-2-nitro-benzeneMethanol
- CBNumber
- CB21311657
- Molecular Formula
- C8H9NO3
- Formula Weight
- 167.16
- MOL File
- 3205-25-2.mol
1-(2-nitrophenyl)ethanol Property
- Melting point:
- 40-41℃
- Boiling point:
- 106-107°C 1mmHg.
- Density
- 1.2300 g/cm3 (20 ºC)
- refractive index
- 1.5572 (589.3 nm 20℃)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Dichloromethane, Ether, Ethyl Acetate, Methanol
- form
- Solid
- pka
- 13.84±0.20(Predicted)
- color
- Pale Yellow
- InChI
- InChI=1S/C8H9NO3/c1-6(10)7-4-2-3-5-8(7)9(11)12/h2-6,10H,1H3
- InChIKey
- DSDBYQDNNWCLHL-UHFFFAOYSA-N
- SMILES
- C(C1C=CC=CC=1N(=O)=O)(O)C
- CAS DataBase Reference
- 3205-25-2
Safety
- HS Code
- 2906290090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- N1132
- Product name
- 1-(2-Nitrophenyl)ethanol
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $96
- Updated
- 2025/07/31
- Product number
- N1132
- Product name
- 1-(2-Nitrophenyl)ethanol
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $383
- Updated
- 2025/07/31
- Product number
- N503410
- Product name
- rac-1-(2-Nitrophenyl)ethanol
- Packaging
- 1g
- Price
- $145
- Updated
- 2021/12/16
- Product number
- 39721
- Product name
- 1-(2-Nitrophenyl)ethanol,≥98%(GC)
- Purity
- ≥98%(GC)
- Packaging
- 1G
- Price
- $103.67
- Updated
- 2021/12/16
- Product number
- J54967
- Product name
- 1-(2-Nitrophenyl)ethanol
- Packaging
- 1g
- Price
- $49
- Updated
- 2021/12/16
1-(2-nitrophenyl)ethanol Chemical Properties,Usage,Production
Chemical Properties
Yellow Oil
Uses
(R,S)-1-(2-Nitrophenyl)ethanol (cas# 3205-25-2) is a compound useful in organic synthesis.
Synthesis
577-59-3
80379-10-8
General procedure for the synthesis of (S)-1-(2-nitrophenyl)ethan-1-ol from o-nitroacetophenone: Synthesis of (RS)-1-(2-nitrophenyl)ethan-1-ol: Sodium borohydride (0.69 g, 18.16 mmol) was added in small portions to a mixed solution of 2-nitroacetophenone (1.0 g, 6.06 mmol) dissolved in methanol (9 mL) and 1,4-dioxane (6 mL) (cf. Dong et al., 2005). The reaction mixture was stirred at room temperature for 30 min and then concentrated under vacuum. The residue was diluted with ethyl acetate (50 mL) and washed sequentially with water (10 mL) and brine (10 mL). The organic phase was dried over anhydrous sodium sulfate and concentrated in vacuum to give racemic (RS)-1-(2-nitrophenyl)ethanol (1.02 g, 100% yield). 1H NMR (400 MHz, CDCl3) data: δ 7.90 (m, 1H, Ph-H), 7.84 (m, 1H, Ph-H), 7.66 (m, 1H, Ph-H), 7.44 (m, 1H, Ph-H), 5.42 (m, 1H, Ph-CH), 2.33 (d, 1H, J = 3.5 Hz, OH), 1.58 (d, 3H, J = 5.1 Hz, CH3).
References
[1] Patent: US9200319, 2015, B2. Location in patent: Page/Page column 57
[2] Journal of Organometallic Chemistry, 2016, vol. 808, p. 68 - 77
[3] Chemistry - A European Journal, 2012, vol. 18, # 31, p. 9628 - 9637
[4] Applied Organometallic Chemistry, 2018, vol. 32, # 3,
[5] Organic Letters, 2018, vol. 20, # 11, p. 3403 - 3407
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Raw materials
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View Lastest Price from 1-(2-nitrophenyl)ethanol manufacturers
- Product
- 1-(2-Nitrophenyl)ethanol 3205-25-2
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20T
- Release date
- 2024-07-11
- Product
- 1-(2-nitrophenyl)ethanol 3205-25-2
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 95%
- Supply Ability
- 500kg
- Release date
- 2018-08-19