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Cyanoferrocene

Product Name
Cyanoferrocene
CAS No.
1273-84-3
Chemical Name
Cyanoferrocene
Synonyms
Cyanoferrocene;Ferrocene, cyano-;Ferrocenylnitrile;Ferrocenyl cyanide;Cyclopentadienecarbonitrile, cyclopentadienyliron deriv.
CBNumber
CB21457014
Molecular Formula
C6H4N.C5H5.Fe
Formula Weight
211.044
MOL File
1273-84-3.mol
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Cyanoferrocene Property

Melting point:
107-108℃
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
OGM0003544
Product name
CYANOFERROCENE
Purity
95.00%
Packaging
5MG
Price
$498.71
Updated
2021/12/16
Arctom
Product number
AS517933
Product name
Cyanoferrocene
Purity
98%
Packaging
250mg
Price
$17
Updated
2021/12/16
Arctom
Product number
AS517933
Product name
Cyanoferrocene
Purity
98%
Packaging
1g
Price
$42
Updated
2021/12/16
Arctom
Product number
AS517933
Product name
Cyanoferrocene
Purity
98%
Packaging
5g
Price
$163
Updated
2021/12/16
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Cyanoferrocene Chemical Properties,Usage,Production

Description

Cyanoferrocene, [Fe(C5H5)(C6H4N)], forms sheets through hydrogen bonding. The N atom in the molecule accepts hydrogen bonds from C-H bonds in two other molecules, resulting in each molecule being hydrogen-bonded to four others. cyanoferrocene has occupied an important position since it can be converted to a structurally diverse set of ferrocenyl compounds that are attractive synthetic targets due to their chemical and biological properties.

Preparation

The synthesis of cyanoferrocene involved treating 3.1g (0.01 mol) of iodoferrocene and 3.6g (0.04 mol) of copper(I) cyanide with 20 ml of pyridine, using the same procedure used for preparing chloroferrocene. The resulting crude product was purified by chromatography on Florisil, yielding 1.75 g of cyanoferrocene with a yield of 83%. The melting point of cyanoferrocene was 106-107°C (lit. 107-108°C). A by-product of unidentified yellow crystals was also obtained, weighing 0.15g with a melting point of 157-158°C.

References

The Reaction of Haloferrocenes with Copper(Ⅰ) Salts
DOI: 10.1246/bcsj.42.1976
Cyanoferrocene: a Two-Dimensional Network Generated by Short C-H...N Hydrogen Bonds
DOI: 10.1107/S0108270196006233
Efficient one-pot synthesis of cyanoferrocene from ferrocenecarboxaldehyde using NH2OH · HCl/KI/ZnO/CH3CN system
DOI: 10.1016/j.jorganchem.2007.02.002

Cyanoferrocene Preparation Products And Raw materials

Raw materials

Preparation Products

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Cyanoferrocene Suppliers

Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
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View Lastest Price from Cyanoferrocene manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Cyanoferrocene 1273-84-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
10000KG
Release date
2024-08-15

1273-84-3, CyanoferroceneRelated Search:


  • Cyclopentadienecarbonitrile, cyclopentadienyliron deriv.
  • Ferrocenyl cyanide
  • Ferrocenylnitrile
  • Ferrocene, cyano-
  • Cyanoferrocene
  • 1273-84-3
  • C11H9FeN