Methyl 3-amino-4-bromobenzoate
- Product Name
- Methyl 3-amino-4-bromobenzoate
- CAS No.
- 46064-79-3
- Chemical Name
- Methyl 3-amino-4-bromobenzoate
- Synonyms
- Methyl 3-amino-4-bromobenzoate;3-Amino-4-bromo-benzoic acid me;Methyl 3-Amino-4-bromobenzoate 98%;Benzoicacid, 3-aMino-4-broMo-, Methyl ester;benzoic acid,3-amino-4-bromo-,methyl ester,methyl3-amino-4-bromobenzoate,Methyl 3-Amino-4-bromobenzoate,2-bromo-5-methoxycarbonylaniline,3-
- CBNumber
- CB21463170
- Molecular Formula
- C8H8BrNO2
- Formula Weight
- 230.06
- MOL File
- 46064-79-3.mol
Methyl 3-amino-4-bromobenzoate Property
- Melting point:
- 118-120°C
- Boiling point:
- 337.0±22.0 °C(Predicted)
- Density
- 1.578±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- pka
- 1.39±0.10(Predicted)
- Appearance
- Off-white to yellow Solid
Safety
- HazardClass
- IRRITANT
- HS Code
- 29163990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M328650
- Product name
- Methyl3-amino-4-bromobenzoate
- Packaging
- 500mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- J50910
- Product name
- Methyl3-Amino-4-bromobenzoate
- Packaging
- 1g
- Price
- $10
- Updated
- 2021/12/16
- Product number
- 057605
- Product name
- Methyl 3-amino-4-bromobenzoate
- Purity
- 95%
- Packaging
- 5g
- Price
- $24
- Updated
- 2021/12/16
- Product number
- 4658-9-03
- Product name
- Methyl 3-amino-4-bromobenzoate
- Purity
- 97.0%
- Packaging
- 250mg
- Price
- $50
- Updated
- 2021/12/16
- Product number
- 057605
- Product name
- Methyl 3-amino-4-bromobenzoate
- Purity
- 95%
- Packaging
- 25g
- Price
- $78
- Updated
- 2021/12/16
Methyl 3-amino-4-bromobenzoate Chemical Properties,Usage,Production
Synthesis
67-56-1
2840-29-1
46064-79-3
General method: 3-Amino-4-bromobenzoic acid (1 eq.) was dissolved in methanol and cooled to 0°C. The mixture was then heated to 0°C and refluxed for 24 hours. Thionyl chloride (2.5 eq.) was added slowly and the reaction mixture was heated to reflux for 24 hours after completion of the addition. After completion of the reaction, the solvent was removed by evaporation and the residue was neutralized with saturated aqueous NaHCO3 solution. Subsequently, the mixture was extracted with ethyl acetate, the organic layers were combined and dried with anhydrous magnesium sulfate. Finally, the target product, methyl 3-amino-4-bromobenzoate, was purified by column chromatography (hexane/ethyl acetate as eluent).
References
[1] European Journal of Medicinal Chemistry, 2014, vol. 76, p. 343 - 351
[2] Journal of Medicinal Chemistry, 2016, vol. 59, # 6, p. 2423 - 2435
Methyl 3-amino-4-bromobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
Methyl 3-amino-4-bromobenzoate Suppliers
- Tel
- 18210857532; 18210857532
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 5108538618
- Fax
- 86 510 85386988-8017
- suger.wang@chemfuture.com
- Country
- China
- ProdList
- 832
- Advantage
- 65
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44801
- Advantage
- 61
- Tel
- 86-027-67849912
- Fax
- 86-027-87531808
- sales@chemwish.com
- Country
- China
- ProdList
- 35896
- Advantage
- 56
- Tel
- +86 (0) 571 85 58 67 18
- Fax
- 0086-571-85864795
- Country
- China
- ProdList
- 18207
- Advantage
- 66
- Tel
- +86-21-54098501
- Fax
- +86-21-54096319
- sales@sinch.com.cn
- Country
- China
- ProdList
- 11598
- Advantage
- 64
- Tel
- 0573-85285100 18627885956
- Fax
- 0573-85285100
- isenchem@163.com
- Country
- China
- ProdList
- 9310
- Advantage
- 66
- Tel
- 021-50795510 4000665055
- Fax
- 021-50795055
- sales@accelachem.com
- Country
- China
- ProdList
- 11035
- Advantage
- 64
- Tel
- 021-31038972,31038973 17321035817
- Fax
- +86-21-51385350
- sales@harvest-chem.com
- Country
- China
- ProdList
- 2816
- Advantage
- 64
- Tel
- 021-54306202 13764082696
- info@hanhongsci.com
- Country
- China
- ProdList
- 42934
- Advantage
- 64
View Lastest Price from Methyl 3-amino-4-bromobenzoate manufacturers
- Product
- Benzoicacid, 3-aMino-4-broMo-, Methyl ester 46064-79-3
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
- Product
- Methyl 3-amino-4-bromobenzoate 46064-79-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-11