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2-bromo-1H-pyrrolo[2,3-b]pyridine

Product Name
2-bromo-1H-pyrrolo[2,3-b]pyridine
CAS No.
1083181-25-2
Chemical Name
2-bromo-1H-pyrrolo[2,3-b]pyridine
Synonyms
2-Bromo-7-azaindole;2-bromo-1H-pyrrolo[2,3-b]pyridine;1H-Pyrrolo[2,3-b]pyridine, 2-broMo-
CBNumber
CB21515769
Molecular Formula
C7H5BrN2
Formula Weight
197.03
MOL File
1083181-25-2.mol
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2-bromo-1H-pyrrolo[2,3-b]pyridine Property

Density 
1.770±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
12.22±0.40(Predicted)
Appearance
Off-white to yellow Solid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
B111500
Product name
2-Bromo-1H-pyrrolo[2,3-b]pyridine
Packaging
50mg
Price
$65
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0036132
Product name
2-BROMO-1H-PYRROLO[2,3-B]PYRIDINE
Purity
95.00%
Packaging
5G
Price
$909.56
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0036132
Product name
2-BROMO-1H-PYRROLO[2,3-B]PYRIDINE
Purity
95.00%
Packaging
10G
Price
$1334.03
Updated
2021/12/16
AK Scientific
Product number
1677AA
Product name
2-Bromo-1H-pyrrolo[2,3-b]pyridine
Packaging
5g
Price
$1493
Updated
2021/12/16
Ambeed
Product number
A164782
Product name
2-Bromo-1H-pyrrolo[2,3-b]pyridine
Purity
95%
Packaging
100mg
Price
$72
Updated
2021/12/16
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2-bromo-1H-pyrrolo[2,3-b]pyridine Chemical Properties,Usage,Production

Synthesis

1198416-32-8

1083181-25-2

2-Bromo-1-toluenesulfonyl-1H-pyrrolo[2,3-b]pyridine (30 g, 0.085 mol) was used as a raw material, which was mixed with methanol (850 mL) and aqueous potassium hydroxide solution (5 mol/L, 100 mL). The reaction mixture was heated under reflux conditions overnight. Upon completion of the reaction, most of the solvent was evaporated under reduced pressure. The residue was partitioned between ethyl acetate (EtOAc) and water. The organic layer was separated, dried over anhydrous sodium sulfate (Na2SO4) and subsequently concentrated to afford 2-bromo-1H-pyrrolo[2,3-b]pyridine (24 g, 80% yield), which could be used in subsequent steps without further purification. The 1H NMR (400 MHz, DMSO-d6) data of the product were as follows: δ 6.550 (s, 1H); 7.039 (dd, J = 5.2 Hz, 3.2 Hz, 1H); 7.857 (dd, J = 1.6 Hz, 3.2 Hz, 1H); 8.155 (q, J = 1.6 Hz, 1H); 12.418 (br, 1H).

References

[1] Patent: US2009/318455, 2009, A1. Location in patent: Page/Page column 98-99

2-bromo-1H-pyrrolo[2,3-b]pyridine Preparation Products And Raw materials

Raw materials

Preparation Products

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2-bromo-1H-pyrrolo[2,3-b]pyridine Suppliers

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1083181-25-2, 2-bromo-1H-pyrrolo[2,3-b]pyridineRelated Search:


  • 2-bromo-1H-pyrrolo[2,3-b]pyridine
  • 1H-Pyrrolo[2,3-b]pyridine, 2-broMo-
  • 2-Bromo-7-azaindole
  • 1083181-25-2