ChemicalBook > CAS DataBase List > alpha-Hexylcinnamaldehyde

alpha-Hexylcinnamaldehyde

Product Name
alpha-Hexylcinnamaldehyde
CAS No.
101-86-0
Chemical Name
alpha-Hexylcinnamaldehyde
Synonyms
HCA;HEXYL CINNAMIC ALDEHYDE;HEXYL CINNAMAL;JASMONAL H;HEXYLCINNAMALDEHYDE;FEMA 2569;2-Benzylideneoctanal;α-Hexylcinnamaldehyde;n-Hexyl cinnamaldehyde;2-(phenylmethylene)-Octanal
CBNumber
CB2154127
Molecular Formula
C15H20O
Formula Weight
216.32
MOL File
101-86-0.mol
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alpha-Hexylcinnamaldehyde Property

Boiling point:
174-176 °C/15 mmHg (lit.)
Density 
0.95 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.55(lit.)
FEMA 
2569 | ALPHA-HEXYLCINNAMALDEHYDE
Flash point:
200 °F
storage temp. 
-20°C
solubility 
water: soluble0.005g/L at 25°C
form 
Oil
color 
Clear Yellow
Odor
at 100.00 %. fresh floral green jasmin herbal waxy
Odor Type
floral
JECFA Number
686
Stability:
Hygroscopic
LogP
5.33
CAS DataBase Reference
101-86-0(CAS DataBase Reference)
NIST Chemistry Reference
Octanal, 2-(phenylmethylene)-(101-86-0)
EPA Substance Registry System
.alpha.-Hexylcinnamaldehyde (101-86-0)
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Safety

Hazard Codes 
C,Xi
Risk Statements 
36/37/38-34-43-52/53
Safety Statements 
26-36/37/39-45-36-36/37-61
RIDADR 
UN 3265 8/PG 3
WGK Germany 
2
RTECS 
GD6560000
HS Code 
29122990
Toxicity
The acute oral LD50 value in rats was reported as 3.1 g/kg (2.45-3.75 g/kg) (Moreno, 1971). The acute dermal LD50 value in rabbits was reported as > 3 g/kg (Moreno, 1971).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
09178
Product name
α-Hexylcinnamaldehyde
Purity
analytical standard
Packaging
1ml
Price
$71
Updated
2024/03/01
Sigma-Aldrich
Product number
291285
Product name
α-Hexylcinnamaldehyde
Purity
technical grade, 85%
Packaging
250ml
Price
$116
Updated
2023/06/20
Sigma-Aldrich
Product number
W256900
Product name
α-Hexylcinnamaldehyde
Purity
≥95%, stabilized, FG
Packaging
1kg
Price
$76.5
Updated
2023/01/07
Sigma-Aldrich
Product number
W256900
Product name
α-Hexylcinnamaldehyde
Purity
≥95%, stabilized, FG
Packaging
5kg
Price
$222
Updated
2023/01/07
Sigma-Aldrich
Product number
W256900
Product name
α-Hexylcinnamaldehyde
Purity
≥95%, stabilized, FG
Packaging
10Kg
Price
$318
Updated
2023/01/07
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alpha-Hexylcinnamaldehyde Chemical Properties,Usage,Production

Description

α-Hexylcinnamaldehyde has a jasmine-like odor, particularly on dilution. May be synthesized by condensation of octylaldehyde with benzaldehyde.

Chemical Properties

alpha-Hexylcinnamaldehyde is a yellow liquid with a mild, slightly fatty, floral, somewhat herbal odor, and a distinct jasmine note. Similarly to the ??-amyl homolog, ??-hexylcinnamaldehydemust be protected against oxidation by the addition of stabilizers. It is prepared in a manner similar to that of ??-amylcinnamaldehyde by alkaline condensation of excess benzaldehyde with octanal (instead of heptanal). ??-Hexylcinnamaldehyde is widely used in flower compositions (e.g., jasmine and gardenia) and, because of its stability to alkali, in soap perfumes.

Chemical Properties

Pale-yellow liquid; jasminelike odor, particularly on dilution. Soluble in most fixed oils and in mineral oil; insoluble in glycerol and in propylene glycol.

Chemical Properties

Hexyl cinnamaldehyde has a jasmine-like odor, particularly on dilution.

Occurrence

Reported found in cooked, scented rice.

Uses

hexyl cinnamal is also known as hexyl cinnamic aldehyde. It is a fragrance that provides a floral, jasmine-like scent.

Uses

α-Hexylcinnamaldehyde is characterized by a typical floral scent, which makes them suitable to be used as fragrances in personal care (perfumes, creams, shampoos, etc.) and household products. It has been also used as flavouring additive in food and pharmaceutical industry.

Definition

ChEBI: A member of the class of cinnamaldehydes carrying a hexyl substituent at the alpha-position.

Preparation

By condensation of octylaldehyde with benzaldehyde

Taste threshold values

Taste characteristics at 5 ppm: sweet, waxy, floral, green, citrus and fruity nuances

General Description

Solubilization of α-hexylcinnamaldehyde by the ionic surfactants, sodium dodecyl sulfate and dodecyltrimethylammonium chloride and a non-ionic surfactant such as dodecyl polyoxyethylene ethers has been investigated.

Hazard

Combustible.

Contact allergens

Hexyl cinnamic aldehyde is a fragrance allergen. Its presence has to be mentioned by name in cosmetics within the EU.

Solubility in organics

Insoluble in Propylene glycol and Glycerin. Soluble in alcohol, miscible with oils.

alpha-Hexylcinnamaldehyde Preparation Products And Raw materials

Raw materials

Octanal alpha-Amylcinnamaldehyde Benzaldehyde Desulfurization

Preparation Products

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alpha-Hexylcinnamaldehyde Suppliers

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View Lastest Price from alpha-Hexylcinnamaldehyde manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
alpha-Hexylcinnamaldehyde 101-86-0
Price
US $0.00/KG
Min. Order
25KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-08
Hebei Zhuanglai Chemical Trading Co Ltd
Product
Alpha-Hexylcinnamaldehyde 101-86-0
Price
US $150.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
500kg
Release date
2024-11-20
Hebei Weibang Biotechnology Co., Ltd
Product
alpha-Hexylcinnamaldehyde 101-86-0
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10 mt
Release date
2024-11-18

101-86-0, alpha-HexylcinnamaldehydeRelated Search:

Tricyclohexyl phosphine α-Lipoic Acid α-Methylcinnamaldehyde Cinnamaldehyde Diethylstilbestrol Dicyclohexylamine 3-（trifluoromethyl) Cinnamaldehyde 4-(Dimethylamino)cinnamaldehyde Salicylic acid Glycerol Dicyclohexylcarbodiimide 3-(4-METHYLBENZYLIDENE)CAMPHOR  Phenanthrene alpha-Hexylcinnamaldehyde Cassia Aurantium P.E Catechins 8% HPLC TOSLAB 864097 2-(E)-BENZYLIDENE-6-(TRIFLUOROACETYL)CYCLOHEXANONE TOSLAB 860368

  • (2Z)-2-Hexyl-3-phenyl-2-propenal
  • .alpha.-hexylcinnamaldehyde(positivecontrolchemical)
  • 2-(phenylmethylene)-octana
  • 2-(phenylmethylene)-Octanal
  • 2-(Phenylmethylene)octanal,a-Hexyl-phenylacrolein
  • FEMA 2569
  • HCA
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  • HEXYLCINNAMALDEHYDE
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  • A-N-HEXYL-B-PHENYLACROLEIN
  • ALPHA-HEXYLCINNAMIC ALDEHYDE
  • ALPHA-HEXYLCINNAMALDEHYDE
  • ALPHA-N-HEXYLCINNAMALDEHYDE
  • A-HEXYLCINNAMALDEHYDE
  • A-HEXYLCINNAMIC ALDEHYDE
  • 2-[1-PHENYL-METH-(E)-YLIDENE]-OCTANAL
  • 9,10-dihydro-9-oxa-10-phosphenanthrene-10-oxide
  • Alpha-Hexylcinnamadehyde
  • 2-Hexyl-3-phenyl-2-propenal
  • 2-hexylcinnamaldehyde
  • a-Hexylcinnamalbehyde
  • alpha-hexyl-cinnamaldehyd
  • alpha-hexylcinnamylaldehyde
  • alpha-n-Hexyl-beta-phenylacrolein
  • Cinnamaldehyde, alpha-hexyl-
  • -Hexyl-3-phenyl-propenal
  • n-Hexyl cinnamaldehyde
  • Octanal,2-(phenylmethylene)-
  • ALPHA-HEXYLCINNAMALDEHYDE 95+% FCC
  • ALPHA-HEXYLCINNAMALDEHYDE, TECH., 85%
  • α-n-Hexyl-β-phenylacrolein
  • Alpha-Hexyl
  • HEXYLCINNAMALDEHYDE(SG)
  • alpha-Hexylcinnamaldehyde technical grade, 85%
  • HEXYL CINNAMAL
  • α-Hexylcinnamaldehyde, 95%, stabilized with 0.075 - 0.3% BHT
  • (2Z)-2-(phenylmethylene)octanal
  • a-Hexylcinnamaldehyd
  • alpha-Hexylcinnamaldehyde solution
  • alpha-Hexylzimtaldehyd
  • HEXYLZIMTALDEHYD, ALPHA
  • lpha-hexylcinnamyl aldehyde
  • jasminolene
  • α-n-hexylcinnamal
  • HEXYLCINNAMALDEHYDE WITH GC
  • HEXYL CINNAMIC ALDEHYDE, NATURAL
  • 2-Hexylcinnamic aldehyde
  • α-Hexylbenzenepropenal
  • (2E)-2-Benzylideneoctanal
  • 2-[(E)-Benzylidene]octanal
  • α-hexyl-pphenylacrolein
  • 2-(Phenylmethylidene)octanal
  • 2-Hexyl-3-phenylacrylaldehyde 2-Hexyl-3-phenyl-2-propenal
  • 2-Benzylideneoctanal
  • (Z)-2-benzylideneoctanal
  • α-Hexylcinnamaldehyd
  • α-Hexylcinnamaldehyde&gt