TETRAACETYLRIBOFURANOSE
- Product Name
- TETRAACETYLRIBOFURANOSE
- CAS No.
- 28708-32-9
- Chemical Name
- TETRAACETYLRIBOFURANOSE
- Synonyms
- (3R,4R,5R)-5-(AcetoxyMethyl)tetrahydrofuran-2,3,4-triyl triacetate;TETRAACETYLRIBOFURAN;Ribavirin Impurity 10;Tetraacetyribofuranose;tetraacetylrlbofuranose;TETRAACETYLRIBOFURANOSE;TETRACAETATE PENTOFURANOSE;TETRACAETATE PENTOFURAROSE;beta-D-Ribosoetetraacetate;D-Ribofuranose tetraacetate
- CBNumber
- CB2159081
- Molecular Formula
- C13H18O9
- Formula Weight
- 318.28
- MOL File
- 28708-32-9.mol
TETRAACETYLRIBOFURANOSE Property
- Melting point:
- 82 °C(Solv: chloroform (67-66-3))
- Boiling point:
- 385.6±42.0 °C(Predicted)
- Density
- 1.29±0.1 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- White to off-white Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- Z4546
- Product name
- D-Ribofuranose,1,2,3,5-tetraacetate
- Packaging
- 100g
- Price
- $67
- Updated
- 2021/12/16
- Product number
- CRB0003943
- Product name
- TETRAACETYL-D-RIBOSE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $504.99
- Updated
- 2021/12/16
- Product number
- A164211
- Product name
- (3R,4R,5R)-5-(Acetoxymethyl)tetrahydrofuran-2,3,4-triyltriacetate
- Purity
- 98%
- Packaging
- 500g
- Price
- $101
- Updated
- 2021/12/16
- Product number
- CD70001502
- Product name
- (3R,4R,5R)-5-(Acetoxymethyl)tetrahydrofuran-2,3,4-triyltriacetate
- Purity
- 98%
- Packaging
- 500g
- Price
- $129
- Updated
- 2021/12/16
- Product number
- A164211
- Product name
- (3R,4R,5R)-5-(Acetoxymethyl)tetrahydrofuran-2,3,4-triyltriacetate
- Purity
- 98%
- Packaging
- 1kg
- Price
- $173
- Updated
- 2021/12/16
TETRAACETYLRIBOFURANOSE Chemical Properties,Usage,Production
Uses
Tetra-O-acetyl-D-ribofuranose is a useful product for proteomic research.
Synthesis
532-20-7
108-24-7
28708-32-9
The general procedure for the synthesis of (3R,4R,5R)-5-(acetyloxymethyl)tetrahydrofuran-2,3,4-triyl triacetate from the compound (CAS:532-20-7) and ethanoic anhydride was carried out as follows: peroxoacetylation of natural carbohydrates was carried out according to the literature procedure under the catalysis of pyridine with appropriate modifications. A mixture of carbohydrate (1.0 mmol), ethanoic anhydride (1.9 mL; 20 mmol) and pyridine (3 mL) was stirred and reacted at 25°C for 24 hours. After completion of the reaction, the reaction mixture was diluted with 5 mL of dichloromethane, and the organic phase was washed sequentially with 1 mol/L hydrochloric acid (3 × 5 mL), saturated sodium bicarbonate solution (3 × 5 mL), and brine (5 mL). The organic layer was dried with anhydrous sodium sulfate and subsequently concentrated under reduced pressure to afford the fully-O-acetylated carbohydrate derivative. The structures of the resulting fully acetylated carbohydrates were in agreement with those reported in the literature through physical properties and spectroscopic data.
References
[1] Tetrahedron Letters, 2008, vol. 49, # 29-30, p. 4491 - 4493
[2] European Journal of Medicinal Chemistry, 2010, vol. 45, # 7, p. 2713 - 2718
[3] Asian Journal of Chemistry, 2014, vol. 26, # 14, p. 4367 - 4369
[4] Journal of the Brazilian Chemical Society, 2015, vol. 26, # 4, p. 755 - 764
[5] Organic and Biomolecular Chemistry, 2004, vol. 2, # 17, p. 2538 - 2546
TETRAACETYLRIBOFURANOSE Preparation Products And Raw materials
Raw materials
Preparation Products
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