FERRIC ACETATE

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Product Name: FERRIC ACETATE
CAS No.: 10450-55-2
Chemical Name: FERRIC ACETATE
Synonyms: Basic ferric acetate;IRON (III) ACETATE;NSC 112208;FERRIC ACETATE;Iron hydroxyacetate;FERRIC ACETATE BASIC;Hydroxydiacetyl iron;Bis(acetato)hydroxyiron;Hydroxybis(acetato)iron;Iron hydroxide diacetate
CBNumber: CB2164120
Molecular Formula: C4H7FeO5
Formula Weight: 190.94
MOL File: 10450-55-2.mol

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FERRIC ACETATE Property

solubility: insoluble in H2O; soluble in ethanol, acid solutions
form: brown-red amorphous powder
color: brown-red amorphous powder
Water Solubility: insoluble H2O; soluble EtOH, acid [CRC10]
CAS DataBase Reference: 10450-55-2

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Hazard and Precautionary Statements (GHS)

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FERRIC ACETATE Chemical Properties,Usage,Production

Description

Ferric acetate is the coordination compound more commonly known as "basic iron acetate". With the formula [Fe₃O(OAc)₆(H₂O)₃]OAc (OAc is CH₃CO₂^-), it is a salt, composed of the cation [Fe₃(μ³-O)(OAc)₆(H₂O)₃]⁺ and an acetate anion . The formation of the red-brown complex has long been used as a test for ferric ions.

Chemical Properties

Red powder. Soluble in alcohol and acids; insoluble in water. Combustible.

Physical properties

Basic iron acetate forms on treating aqueous solutions of iron (III) sources with acetate salts.
Early work showed that it is trinuclear.The Fe centres are equivalent, each being octahedral, being bound to six oxygen ligands, including a triply bridging oxide at the center of the equilateral triangle.The compound was an early example of a molecular compound of iron that features an oxide ligand. Ignoring its 24 hydrogen centres, the cation has D_3h symmetry.

Uses

In the textile industry as a mordant in dyeing and printing, and for the weighting of silk and felt; as wood preservative; in leather dyes.

Uses

Materials prepared by heating iron, acetic acid, and air, loosely described as basic iron acetates, are used as dyes and mordants.

Reactions

The terminal aqua ligands on the trimetallic frame work can be substituted with other ligands, such as pyridine and dimethyl formamide . Many different salts are known by exchanging the anion, e.g. [Fe3(μ³-O)(OAc)₆(H₂O)₃]Cl. Reduction of the cation affords the neutral mixed-valence derivative that contains one ferrous and two ferric centers. Mixed metal species are known such as [Fe₂CoO(OAc)₆(H₂O)₃].

FERRIC ACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

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10450-55-2, FERRIC ACETATERelated Search:

Ferric ammonium oxalate FERRIC ACETATE CHOLINE CITRATE POTASSIUM TRIOXALATOFERRATE(III) IRON (III) OXALATE FERRIC OLEATE Ammonium ferric citrate Iron(III) 2-ethylhexanoate FERRIC OCTOATE FERRIC STEARATE IRON(III) ACRYLATE FERRIC CITRATE FERRIC TARTRATE FERRIC BENZOATE Ferrous acetate IRON III METHACRYLATE FERRIC SODIUM OXALATE (ETHYLENEDINITRILO)TETRAACETIC ACID FERRIC SODIUM SALT DIHYDRATE

FERRIC ACETATE

FERRIC ACETATE BASIC

IRON (III) ACETATE

IRON (III) ACETATE, BASIC

iron di(acetate) hydroxide

Diacetic acid hydroxyiron(III) salt

Hydroxyiron(III)diacetate

Basic ferric acetate

Bis(acetato)hydroxyiron

Bis(acetato-O)hydroxyiron

Hydroxybis(acetato)iron

Iron hydroxide diacetate

Iron hydroxyacetate

NSC 112208

acetic acid,iron,hydrate

Hydroxydiacetyl iron，hydrate

Hydroxydiacetyl iron

Iron, bis(acetato-kO)hydroxy-

10450-55-2

C6H9FeO6

CH3COO3Fe

C4H7FeO5