SILVER PERCHLORATE
Description References- Product Name
- SILVER PERCHLORATE
- CAS No.
- 7783-93-9
- Chemical Name
- SILVER PERCHLORATE
- Synonyms
- SILVER PERCHLORATE;SILVER (I) PERCHLORATE;SILVER PERCHLORATE 99.9%;Perchloricacid,silver(1+)salt;Silver(I)perchlorate,anhydrous;perchloricacid,silver(1++)salt;Hyperchloric acid silver(I) salt;SILVER PERCHLORATE, ANHYDROUS, 97%;Silverperchlorate,anhydrous,min.97%;SILVER PERCHLORATE, ANHYDROUS REAGENT
- CBNumber
- CB2180173
- Molecular Formula
- AgClO4
- Formula Weight
- 207.32
- MOL File
- 7783-93-9.mol
SILVER PERCHLORATE Property
- Melting point:
- 486°C
- Density
- 2.8 g/mL at 25 °C(lit.)
- solubility
- benzene: slightly soluble(lit.)
- form
- Crystals
- color
- White
- Specific Gravity
- 2.806
- Water Solubility
- Soluble in water and many organic solvents (benzene, toluene, pyridine)Soluble in water, benzene and toluene.
- Sensitive
- Hygroscopic
- Merck
- 14,8523
- Exposure limits
- ACGIH: TWA 0.01 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.01 mg/m3 - Stability:
- hygroscopic
- InChIKey
- YDHABVNRCBNRNZ-UHFFFAOYSA-M
- CAS DataBase Reference
- 7783-93-9(CAS DataBase Reference)
- EPA Substance Registry System
- Perchloric acid, silver(1+) salt (7783-93-9)
Safety
- Hazard Codes
- O,C
- Risk Statements
- 8-34
- Safety Statements
- 17-26-27-36/37/39
- RIDADR
- UN 1481 5.1/PG 2
- WGK Germany
- 3
- F
- 3-8-10
- TSCA
- Yes
- HazardClass
- 5.1
- PackingGroup
- II
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H272May intensify fire; oxidizer
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220Keep/Store away from clothing/…/combustible materials.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 674583
- Product name
- Silver perchlorate
- Purity
- anhydrous, 97%
- Packaging
- 5g
- Price
- $70.8
- Updated
- 2024/03/01
- Product number
- 674583
- Product name
- Silver perchlorate
- Purity
- anhydrous, 97%
- Packaging
- 25g
- Price
- $249
- Updated
- 2024/03/01
- Product number
- 042209
- Product name
- Silver perchlorate, anhydrous
- Packaging
- 5g
- Price
- $61.2
- Updated
- 2024/03/01
- Product number
- 042209
- Product name
- Silver perchlorate, anhydrous
- Packaging
- 25g
- Price
- $223
- Updated
- 2024/03/01
- Product number
- 93-4722
- Product name
- Silver perchlorate, anhydrous, min. 97%
- Packaging
- 5g
- Price
- $63
- Updated
- 2024/03/01
SILVER PERCHLORATE Chemical Properties,Usage,Production
Description
Silver perchlorate (chemical formula: AgClO4) is a silver salt of perchloric acid as both a useful source of the Ag+ ion and a catalyst in the organic chemistry. It should be noted that due to the high instability and explosiveness of the anion perchlorate contained in it, it is limited for usage in industry. It is a kind of strong oxidizer and can be used to promoting the oxidation reaction in the organic synthesis. It can also be used as a catalyst for which it can be used to replace a halide with perchlorates to form intermediate in synthesis. It can be manufactured through the heating reaction of the mixture of perchloric acid with silver nitrate, the reaction between barium perchlorate and silver sulfate, or the reaction of perchloric acid with silver oxide.
References
https://en.wikipedia.org/wiki/Silver_perchlorate
http://www.softschools.com/formulas/chemistry/silver_perchlorate_formula/393/
Chemical Properties
The silver perchlorate salt, is deliquescent and forms a light-sensitive monohydrate that can be dehydrated at 43 °C and is soluble in a variety of organic solvents. Explosions of silver perchlorate have been reported.
Chemical Properties
Colorless crystals. Soluble in water; reacts with explosive violence with many organic sol- vents; explodes on grinding.
Uses
In the explosives industry.
Uses
Silver perchlorate is used as a catalyst in organic chemistry. It is an effective reagent for replacing halides ligands with perchlorate. It is also used in the manufacturing of explosives.
Purification Methods
Reflux it with *benzene (6mL/g) in a flask fitted with a Dean and Stark trap until all the water is removed azeotropically (ca 4hours). The solution is cooled and diluted with dry pentane (4mL/g of AgClO4). The precipitated AgClO4 is filtered off and dried in a desiccator over P2O5 at 1mm for 24hours [Radell et al. J Am Chem Soc 83 3958 1961]. It has also been recrystallised from perchloric acid. [Caution due to its EXPLOSIVE nature in the presence of organic matter.] Store it in the dark.
SILVER PERCHLORATE Preparation Products And Raw materials
Raw materials
Preparation Products
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