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Diethyl(methylsulfonylmethyl)phosphonate

Product Name
Diethyl(methylsulfonylmethyl)phosphonate
CAS No.
40137-11-9
Chemical Name
Diethyl(methylsulfonylmethyl)phosphonate
Synonyms
Diethyl(methylsulfonylmethyl)phosphonate;Diethyl?P-[(methylsulfonyl)methyl]phosphonate;1-[ethoxy(methylsulfonylmethyl)phosphoryl]oxyethane;Phosphonic acid, [(methylsulfonyl)methyl]-, diethyl ester;Phosphonic acid, P-[(methylsulfonyl)methyl]-, diethyl ester
CBNumber
CB21856482
Molecular Formula
C6H15O5PS
Formula Weight
230.22
MOL File
40137-11-9.mol
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Diethyl(methylsulfonylmethyl)phosphonate Property

Melting point:
93-95°C
Boiling point:
373.6±25.0 °C(Predicted)
Density 
1.241±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
sol acetone, CH2Cl2, DME, THF.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

ChemScene
Product number
CS-0046853
Product name
Diethyl((methylsulfonyl)methyl)phosphonate
Packaging
1g
Price
$103
Updated
2021/12/16
ChemScene
Product number
CS-0046853
Product name
Diethyl((methylsulfonyl)methyl)phosphonate
Packaging
5g
Price
$309
Updated
2021/12/16
Matrix Scientific
Product number
120825
Product name
Diethylmethylsulfonylmethylphosphonate
Purity
97%
Packaging
5g
Price
$550
Updated
2021/12/16
Matrix Scientific
Product number
120825
Product name
Diethylmethylsulfonylmethylphosphonate
Purity
97%
Packaging
25g
Price
$2160
Updated
2021/12/16
Crysdot
Product number
CD62000384
Product name
Diethyl((methylsulfonyl)methyl)phosphonate
Purity
95+%
Packaging
10g
Price
$902
Updated
2021/12/16
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Diethyl(methylsulfonylmethyl)phosphonate Chemical Properties,Usage,Production

Uses

Diethyl Methylsulfonylmethylphosphonate is used for the preparation of synthetically versatile vinyl sulfones from aldehydes and ketones.

Preparation

Preparative Methods: conveniently prepared by oxidation of Diethyl Methylthiomethylphosphonate (eq 1). Both inorganic oxidants (e.g. Potassium Permanganate in water or Hydrogen Peroxide/Selenium(IV) Oxide) and organic oxidants (e.g. Peracetic Acid in ether or m-Chloroperbenzoic Acid in CH2Cl2 ) have been used to accomplish this transformation.

storage

Diethyl methylsulfonylmethylphosphonate is reasonably stable for storage. Reactions involving this reagent are best conducted under anhydrous conditions, under nitrogen, in a well ventilated fume hood.

Diethyl(methylsulfonylmethyl)phosphonate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Diethyl(methylsulfonylmethyl)phosphonate manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Diethyl(methylsulfonylmethyl)phosphonate 40137-11-9
Price
US $1.00-100.00/KG
Min. Order
1KG
Purity
95%
Supply Ability
300KG
Release date
2024-08-19

40137-11-9, Diethyl(methylsulfonylmethyl)phosphonateRelated Search:


  • Diethyl(methylsulfonylmethyl)phosphonate
  • Phosphonic acid, P-[(methylsulfonyl)methyl]-, diethyl ester
  • Phosphonic acid, [(methylsulfonyl)methyl]-, diethyl ester
  • 1-[ethoxy(methylsulfonylmethyl)phosphoryl]oxyethane
  • Diethyl?P-[(methylsulfonyl)methyl]phosphonate
  • 40137-11-9
  • C6H15O5PS