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METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE

Product Name
METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE
CAS No.
101184-08-1
Chemical Name
METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE
Synonyms
DK7442;Methyl 4-(1H<;RARECHEM AL BF 0793;Methyl 4-(1H-imidazol-1-yl);Methyl 4-imidazol-1-ylbenzoate;METHYL 4-(1 H-IMIDAZOL-1-YL)BENZOATE;4-(Imidazol-1-yl)benzoicacidmethylester;Methyl 4-(1H-imidazol-1-yl)benzoate 99%;Methyl 4-(1H-iMidazol-1-yl)benzoate,99%;Methyl 4-(imidazol-1-yl)benzoate, GC 99%
CBNumber
CB2206837
Molecular Formula
C11H10N2O2
Formula Weight
202.21
MOL File
101184-08-1.mol
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METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE Property

Melting point:
124-127 °C (lit.)
Boiling point:
354.7±25.0 °C(Predicted)
Density 
1.18±0.1 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
5.06±0.10(Predicted)
Appearance
White to off-white Solid
InChI
InChI=1S/C11H10N2O2/c1-15-11(14)9-2-4-10(5-3-9)13-7-6-12-8-13/h2-8H,1H3
InChIKey
KUBBZTZQWIGHFH-UHFFFAOYSA-N
SMILES
C(OC)(=O)C1=CC=C(N2C=NC=C2)C=C1
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
2933299090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
476811
Product name
Methyl 4-(1H-imidazol-1-yl)benzoate
Purity
99%
Packaging
1g
Price
$16.3
Updated
2023/06/20
TRC
Product number
M220913
Product name
Methyl 4-(1H-imidazol-1-yl)benzoate
Packaging
500mg
Price
$310
Updated
2021/12/16
Matrix Scientific
Product number
042900
Product name
Methyl 4-(1H-imidazol-1-yl)benzenecarboxylate
Purity
>95%
Packaging
500mg
Price
$21
Updated
2021/12/16
Matrix Scientific
Product number
042900
Product name
Methyl 4-(1H-imidazol-1-yl)benzenecarboxylate
Purity
>95%
Packaging
1g
Price
$32
Updated
2021/12/16
Apolloscientific
Product number
OR32165
Product name
Methyl 4-(1H-imidazol-1-yl)benzoate
Packaging
1g
Price
$56
Updated
2021/12/16
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METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE Chemical Properties,Usage,Production

General Description

Methyl 4-(1H-imidazol-1-yl)benzoate is a imidazole derivative. It is a heterocyclic building block used in chemical synthesis.

Synthesis

288-32-4

403-33-8

101184-08-1

General procedure for the synthesis of methyl 4-(1H-imidazol-1-yl)benzoate from imidazole and methyl 4-fluorobenzoate: imidazole (132 g, 1.9 mol), methyl 4-fluorobenzoate (170 ml, 1.3 mol) and potassium carbonate (357 g, 2.6 mol) were dissolved in DMSO (200 ml) to form a reaction mixture. The reaction mixture was stirred at 120°C for 3 hours. After completion of the reaction, it was cooled to room temperature and the mixture was poured into cold water. The solid product precipitated was collected by filtration and washed with cold water. The yield of the final product was 59%.

References

[1] Patent: KR101502187, 2015, B1. Location in patent: Paragraph 0384; 0385
[2] Journal of Medicinal Chemistry, 1990, vol. 33, # 4, p. 1091 - 1097
[3] Patent: US4804662, 1989, A

METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE Suppliers

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View Lastest Price from METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE manufacturers

Career Henan Chemical Co
Product
Methyl 4-(1H-imidazol-1-yl)benzoate 101184-08-1
Price
US $1.00/KG
Min. Order
1KG
Purity
97%
Supply Ability
200KG
Release date
2018-08-15

101184-08-1, METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATERelated Search:

METHYL4-BROMOFURAN-2-CARBOXYLATE 4-(1H-Indol-6-yl)Morpholine [4-(1H-Imidazol-1-yl)phenyl]methanol 4-(1H-PYRROL-1-YL)BENZYLAMINE Methyl 4-(1H-pyrazol-1-yl)benzoate 4-(1H-PYRROL-1-YL)BENZOIC ACID 4-(1H-PYRROL-1-YL)BENZALDEHYDE 4-(IMIDAZOL-1-YL)-BENZOIC ACID ETHYL ESTER methyl 2-chloro-4-(1H-imidazol-1-yl)benzenecarboxylate METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE METHYL 3-METHOXY-4-(4-METHYL-1-IMIDAZOLYL)BENZOATE 3-AMINO-4-IMIDAZOL-1-YL-BENZOIC ACID ETHYL ESTER 4-IMIDAZOL-1-YL-3-NITRO-BENZOIC ACID ETHYL ESTER AKOS BBS-00000333 METHYL 4-(1H-IMIDAZOL-2-YL)BENZENECARBOXYLATE METHYL 4-(2-METHYL-1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE AKOS BBS-00000335 ETHYL 4-(2-METHYLIMIDAZO[4,5-C]PYRIDIN-1-YL)BENZOATE

  • Methyl 4-(1H-iMidazol-1-yl)benzoate,99%
  • Methyl 4-(1H-imidazol-1-yl)benzoate 99%
  • Methyl 4-(1H-imidazol-1-yl)
  • METHYL 4-(1H-IMIDAZOL-1-YL)BENZENECARBOXYLATE
  • METHYL 4-(1 H-IMIDAZOL-1-YL)BENZOATE
  • RARECHEM AL BF 0793
  • 4-(Imidazol-1-yl)benzoicacidmethylester
  • Methyl 4-(imidazol-1-yl)benzoate, GC 99%
  • Methyl 4-imidazol-1-ylbenzoate
  • Benzoic acid, 4-(1H-imidazol-1-yl)-, methyl ester
  • 1-(4-Methoxycarbonylphenyl)-1H-imidazole
  • DK7442
  • Methyl 4-(1<I>H<
  • Methyl 4-(1<i>H</i>-imidazol-1-yl)benzoate
  • 101184-08-1
  • Building Blocks
  • Heterocyclic Building Blocks
  • Imidazoles
  • Heterocyclic Compounds
  • Building Blocks
  • Heterocyclic Building Blocks
  • Imidazoles