ChemicalBook > CAS DataBase List > Bode Catalyst 2
Bode Catalyst 2
- Product Name
- Bode Catalyst 2
- CAS No.
- 903571-02-8
- Chemical Name
- Bode Catalyst 2
- Synonyms
- Bode Catalyst 2;GUECWMLEUCWYOS-WKOQGQMTSA-M;(+)-(5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-triMethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo;(+)-(5aR,10bS)-5a,10b-Dihydro-2-mesityl-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride;(5aR,10bS)-2-Mesityl-2,5a,6,10b-tetrahydro-4H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazin-11-ium chloride;(5aR,10bS)-2-Mesityl-4,5a,6,10b-tetrahydro-2H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazin-11-ium Chloride;(+)-(5aR,10bS)-5a,10b-Dihydro-2-mesityl-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride Bode Catalyst 2;(+)-(5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride;[5a-R,10b-S]-2-(2,4,6-Trimethyl-phenyl)-2,5a,6,10b-tetrahydro-4H-5-oxa-2,3-diaza-10c-azonia-cyclopenta[c]fluorene chloride;(+)-(5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride
- CBNumber
- CB22095844
- Molecular Formula
- C21H22ClN3OH2O
- Formula Weight
- 0
- MOL File
- 903571-02-8.mol
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Bode Catalyst 2 Property
- Melting point:
- 226-230 °C
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- powder to crystal
- color
- White to Gray to Red
- optical activity
- [α]20/D +158°, c = 1 in chloroform
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 683973
- Product name
- (5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate
- Purity
- 93%
- Packaging
- 100mg
- Price
- $90.4
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 683973
- Product name
- (5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate
- Purity
- 93%
- Packaging
- 250mg
- Price
- $214.4
- Updated
- 2024/03/01
TCI Chemical
- Product number
- D3983
- Product name
- (+)-(5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride Monohydrate
- Purity
- >98.0%(HPLC)
- Packaging
- 100mg
- Price
- $260
- Updated
- 2024/03/01
Apolloscientific
- Product number
- OR307709
- Product name
- [5a-R,10b-S]-2-(2,4,6-Trimethyl-phenyl)-2,5a,6,10b-tetrahydro-4H-5-oxa-2,3-diaza-10c-azonia-cyclopenta[c]fluorenechloride
- Packaging
- 250mg
- Price
- $305
- Updated
- 2021/12/16
SynQuest Laboratories
- Product number
- 4H56-5-4J
- Product name
- [5a-R,10b-S]-2-(2,4,6-Trimethylphenyl)-2,5a,6,10b-tetrahydro-4H-5-oxa-2,3-diaza-10c-azoniacyclopenta[c]fluorene chloride
- Packaging
- 250mg
- Price
- $336
- Updated
- 2021/12/16
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Bode Catalyst 2 Chemical Properties,Usage,Production
Uses
(5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate can be used as a catalyst:
- In the preparation of dihydropyridinones by reacting enals or α′-hydroxyenones with vinylogous amides via aza-Claisen annulations.
- In the oxidative coupling reactions of di(hetero)arylmethanes with enals to yield benzimidazole fused lactams.
- In the synthesis of organosilanes by reacting enals with β-silyl enones.
General Description
It is an N-mesityl-substituted chiral triazolium N-heterocyclic carbene (NHC) compound. It was developed as an organocatalyst by the Bode group, for the catalytic generation of reactive species including activated carboxylates, homoenolates, and enolates.
Bode Catalyst 2 Preparation Products And Raw materials
Raw materials
Preparation Products
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- Country
- Switzerland
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