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(R)-(+)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid

Product Name
(R)-(+)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid
CAS No.
97534-84-4
Chemical Name
(R)-(+)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid
Synonyms
(R)-Z-OXAPROLINE;(R)-CBZ-OXAPROLINE;N-Cbz-R-4-Oxazolidinecarboxylic acid;(R)-(+)-3-Z-4-OXAZOLIDINECARBOXYLIC ACID;(R)-(+)-3-CBZ-4-OXAZOLIDINECARBOXYLIC ACID;(R)-(+)-3-(benzyloxycarbonyl)-4-oxazolid-inecarbo;(R)-3,4-Oxazolidinedicarboxylic acid 3-benzyl ester;(R)-(+)-3-(BENZYLOXYCARBONYL)-4-OXAZOLIDINECARBOXYLIC ACID;(R)-(+)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid,98%;(R)-(+)-3-(Benzyloxycarbonyl)oxazolidine-4-carboxylic acid, 98%
CBNumber
CB2210838
Molecular Formula
C12H13NO5
Formula Weight
251.24
MOL File
97534-84-4.mol
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(R)-(+)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid Property

Melting point:
70-74 °C(lit.)
alpha 
+92°(20℃, c=1, CHCl3)
Boiling point:
454.8±45.0 °C(Predicted)
Density 
1.385
pka
3.51±0.20(Predicted)
optical activity
[α]20/D +92°, c = 1 in chloroform
InChI
InChI=1S/C12H13NO5/c14-11(15)10-7-17-8-13(10)12(16)18-6-9-4-2-1-3-5-9/h1-5,10H,6-8H2,(H,14,15)/t10-/m1/s1
InChIKey
XRRRGBIMHQARMF-SNVBAGLBSA-N
SMILES
O1C[C@H](C(O)=O)N(C(OCC2=CC=CC=C2)=O)C1
CAS DataBase Reference
97534-84-4
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Safety

WGK Germany 
3
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
469475
Product name
(R)-(+)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid
Purity
98%
Packaging
1g
Price
$121
Updated
2024/03/01
Alfa Aesar
Product number
H27240
Product name
(R)-(+)-3-(Benzyloxycarbonyl)oxazolidine-4-carboxylic acid, 98%
Packaging
5g
Price
$193
Updated
2023/06/20
Alfa Aesar
Product number
H27240
Product name
(R)-(+)-3-(Benzyloxycarbonyl)oxazolidine-4-carboxylic acid, 98%
Packaging
1g
Price
$56.9
Updated
2021/12/16
TRC
Product number
B287395
Product name
(R)-(+)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid
Packaging
500mg
Price
$95
Updated
2021/12/16
Apolloscientific
Product number
OR316040
Product name
(R)-CBZ-Oxaproline
Packaging
1g
Price
$102
Updated
2021/12/16
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(R)-(+)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid Chemical Properties,Usage,Production

Chemical Properties

White powder

Uses

Useful chiral synthon (derived from serine) for the asymmetric synthesis of a variety of nitrogen-containing targets.

(R)-(+)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(+)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid Suppliers

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97534-84-4, (R)-(+)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acidRelated Search:

Admire (S)-(-)-3-(BENZYLOXYCARBONYL)-4-OXAZOLIDINECARBOXYLIC ACID 4-OXAZOLIDINECARBOXYLIC ACID N-Cbz-D-Serine Z-D-MEALA-OH (R)-3-BENZYL 4-METHYL 2,2-DIMETHYLOXAZOLIDINE-3,4-DICARBOXYLATE (R)-(+)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid (R)-3-((BENZYLOXY)CARBONYL)-2,2-DIMETHYLOXAZOLIDINE-4-CARBOXYLIC ACID CBZ-O-METHYL-D-SERINE

  • (R)-CBZ-OXAPROLINE
  • (R)-Z-OXAPROLINE
  • (R)-(+)-3-Z-4-OXAZOLIDINECARBOXYLIC ACID
  • (R)-(+)-3-(BENZYLOXYCARBONYL)-4-OXAZOLIDINECARBOXYLIC ACID
  • (R)-(+)-3-CBZ-4-OXAZOLIDINECARBOXYLIC ACID
  • (R)-(+)-3-(Benzyloxycarbonyl)oxazolidine-4-carboxylic acid, 98%
  • (R)-(+)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid,98%
  • N-Cbz-R-4-Oxazolidinecarboxylic acid
  • (R)-(+)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid(R)-CBZ-Oxaproline
  • (R)-(+)-3-(benzyloxycarbonyl)-4-oxazolid-inecarbo
  • (R)-3,4-Oxazolidinedicarboxylic acid 3-benzyl ester
  • 3,4-Oxazolidinedicarboxylic acid, 3-(phenylmethyl) ester, (4R)-
  • 97534-84-4
  • Chiral Auxiliaries
  • Asymmetric Synthesis
  • Oxazolidinone Derivatives
  • CARBOXYLIC ACID
  • Asymmetric Synthesis
  • Chiral Auxiliaries
  • Oxazolidinone Derivatives