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ChemicalBook > CAS DataBase List > (s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine

(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine

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Product Name
(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine
CAS No.
680592-40-9
Chemical Name
(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine
Synonyms
(4S)-2-chloro-3,4-dimethyl-2,5-diphenyl-1,3,2-oxazasilolidine;(2S,4S)-2-chloro-3,4-dimethyl-2,5-diphenyl-1,3,2-oxazasilolidine;(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine;1-Oxa-3-aza-2-silacyclopentane, 2-chloro-3,4-dimethyl-2,5-diphenyl-, (4S,5S)-;(4S,5S)-2-Chloro-3,4-dimethyl-2,5-diphenyl-1-oxa-3-aza-2-silacyclopentane ;(4S,5S)-2-CHLORO-3,4-DIMETHYL-2,5-DIPHENYL-1-OXA-3-AZA-2-SILACYCLOPENTANE,MIN.98%(~2:1MIXTUREOFDIASTEREOMERS);(4S,5S)-2-Chloro-3,4-dimethyl-2,5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)
CBNumber
CB22135092
Molecular Formula
C16H18ClNOSi
Formula Weight
303.86
MOL File
680592-40-9.mol
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(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine Property

Boiling point:
358.9±45.0 °C(Predicted)
Density 
1.146 g/mL at 25 °C
Flash point:
>110℃
pka
3.53±0.60(Predicted)
Specific Gravity
1.016
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
Sensitive 
moisture sensitive, store cold
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
14-1810
Product name
(4S,5S)-2-Chloro-3,4-dimethyl-2,5-diphenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)
Packaging
1g
Price
$92
Updated
2024/03/01
Strem Chemicals
Product number
14-1810
Product name
(4S,5S)-2-Chloro-3,4-dimethyl-2,5-diphenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)
Packaging
5g
Price
$363
Updated
2024/03/01
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(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine Chemical Properties,Usage,Production

Reaction

  1. Reagent used in the enantioselective Friedel-Crafts alkylations with benzoylhydrazones.
  2. Reagent used in highly enantioselective [3+2] acylhydrazone-enol ether cycloadditions.

(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine Preparation Products And Raw materials

Raw materials

Preparation Products

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(s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine Suppliers

J & K SCIENTIFIC LTD.
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86-21-61259102
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Aladdin Scientific
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+1-+1(833)-552-7181
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sales@aladdinsci.com
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680592-40-9, (s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidineRelated Search:


  • (s,s)-2-phenyl-2-chloro-3,4-dimethyl-5-phenyl-[1,3,2]-oxazasilolidine
  • (4S,5S)-2-Chloro-3,4-dimethyl-2,5-phenyl-1-oxa-3-aza-2-silacyclopentane, min. 98% (~2:1 mixture of diastereomers)
  • (4S,5S)-2-Chloro-3,4-dimethyl-2,5-diphenyl-1-oxa-3-aza-2-silacyclopentane
  • (4S,5S)-2-CHLORO-3,4-DIMETHYL-2,5-DIPHENYL-1-OXA-3-AZA-2-SILACYCLOPENTANE,MIN.98%(~2:1MIXTUREOFDIASTEREOMERS)
  • (2S,4S)-2-chloro-3,4-dimethyl-2,5-diphenyl-1,3,2-oxazasilolidine
  • 1-Oxa-3-aza-2-silacyclopentane, 2-chloro-3,4-dimethyl-2,5-diphenyl-, (4S,5S)-
  • (4S)-2-chloro-3,4-dimethyl-2,5-diphenyl-1,3,2-oxazasilolidine
  • 680592-40-9
  • C16H18ClNOSi
  • organosilicon compounds