Methyl tetrahydropyran-4-carboxylate

Product Name: Methyl tetrahydropyran-4-carboxylate
CAS No.: 110238-91-0
Chemical Name: Methyl tetrahydropyran-4-carboxylate
Synonyms: THPE;METHYL TETRAHYDRO-2H-PYRAN-4-CARBOXYLATE;Methyl oxane-4-carboxylate;CAS:110238-91-0;2H-Pyran-4-carboxylic aci;Methyl tetrahydropyran-4-...;4-(Methoxycarbonyl)tetrahydropyran;METHYL TETRAHYDROPYRAN-4-CARBOXYLATE;Methyl tetrahydro-2H-pyran-4- carboxyl;Methyltetrahydro-2H-pyran-4-carboxylat
CBNumber: CB2217413
Molecular Formula: C7H12O3
Formula Weight: 144.17
MOL File: 110238-91-0.mol

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Methyl tetrahydropyran-4-carboxylate Property

Melting point:: -33°C
Boiling point:: 197°C
Density: 1.080 g/mL at 20 °C(lit.)
Flash point:: 86°C
storage temp.: Sealed in dry,Room Temperature
form: liquid
color: Clear
BRN: 114974
InChIKey: CNCMVGXVKBJYNU-UHFFFAOYSA-N
CAS DataBase Reference: 110238-91-0(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36-36/37/38
Safety Statements: 26-37/39
RIDADR: 1993
WGK Germany: 2
Hazard Note: Harmful
HS Code: 29329990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Warning
Hazard statements: H319Causes serious eye irritation
Precautionary statements: P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 40199
Product name: Methyl tetrahydro-2H-pyran-4-carboxylate
Purity: produced by BASF, ≥98.0% (GC)
Packaging: 50ml
Price: $82.5
Updated: 2025/07/31

Sigma-Aldrich

Product number: 40199
Product name: Methyl tetrahydro-2H-pyran-4-carboxylate
Purity: produced by BASF, ≥98.0% (GC)
Packaging: 250ml
Price: $547
Updated: 2023/06/20

TRC

Product number: M331503
Product name: Methyl tetrahydro-2H-pyran-4-carboxylate
Packaging: 50mg
Price: $45
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK194872
Product name: Methyltetrahydropyran-4-carboxylate
Purity: 97%
Packaging: 5g
Price: $16
Updated: 2021/12/16

Matrix Scientific

Product number: 083515
Product name: Methyl tetrahydro-2H-pyran-4-carboxylate
Purity: 97%
Packaging: 5g
Price: $20
Updated: 2021/12/16

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Methyl tetrahydropyran-4-carboxylate Chemical Properties,Usage,Production

Chemical Properties

colorless liquid

Uses

Methyl tetrahydro-2H-pyran-4-carboxylate may be used in the following syntheses:

cycloalkylamide derivatives
tetrahydro-2-furoic chloride
tetrahydro-2H-pyran-4-carboxylic chloride

Synthesis

5337-03-1

77-78-1

110238-91-0

Tetrahydropyran-4-carboxylic acid (1.00 g, 7.68 mmol) was slowly added to a stirred suspension of anhydrous potassium carbonate (1.17 g, 8.45 mmol) in acetone (40 mL), followed by the dropwise addition of dimethyl sulfate (0.8 mL, 8.45 mmol). The reaction mixture was stirred under heating conditions for 3 hours. After completion of the reaction, the inorganic salts were removed by filtration and the filter cake was washed with acetone. The filtrates were combined, dried and concentrated to afford methyl tetrahydropyran-4-carboxylate (1.1 g, 99% yield), which was used in the subsequent reaction without further purification. The product was analyzed by GC-MS showing m/z 145 (MH+); 1H NMR (300 MHz, CDCl3) δ 1.70-1.80 (m, 4H), 2.47-2.52 (m, 1H), 3.34-3.43 (m, 2H), 3.65 (s, 3H), 3.88-3.95 (m, 2H).

References

[1] Patent: US2004/224997, 2004, A1. Location in patent: Page 18
[2] Journal of the American Chemical Society, 1993, vol. 115, # 18, p. 8401 - 8408

Methyl tetrahydropyran-4-carboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl tetrahydropyran-4-carboxylate Suppliers

Austria 1 Canada 1 China 182 Europe 1 Germany 4 India 7 Slovakia 1 Switzerland 2 United Kingdom 5 United States 19 Global 223

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View Lastest Price from Methyl tetrahydropyran-4-carboxylate manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Methyl tetrahydropyran-4-carboxylate 110238-91-0
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-22

Hebei Chuanghai Biotechnology Co., Ltd

Product: Methyl tetrahydropyran-4-carboxylate 110238-91-0
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2025-03-10

Henan Aochuang Chemical Co.,Ltd.

Product: Methyl tetrahydropyran-4-carboxylate 110238-91-0
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-29

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CAS:110238-91-0

Methyl tetrahydro-2<i>H</i>-pyran-4-carboxylate

110238-91-0

10238-91-0

Heterocyclic Building Blocks

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