ChemicalBook > CAS DataBase List > 3-BROMO-5-METHOXY BENZONITRILE

3-BROMO-5-METHOXY BENZONITRILE

Product Name: 3-BROMO-5-METHOXY BENZONITRILE
CAS No.: 867366-91-4
Chemical Name: 3-BROMO-5-METHOXY BENZONITRILE
Synonyms: 3-Bromo-5-cyanoanisole;3-BROMO-5-METHOXYBENZOTRILE;3-BROMO-5-METHOXY BENZONITRILE;Benzonitrile, 3-bromo-5-methoxy-;3-Bromo-5-methoxybenzonitrile 99%;3-BROMO-5-METHOXYBENZONITRILE,98%;3-Bromo-5-cyanoanisole, 5-Bromo-m-anisonitrile
CBNumber: CB2226606
Molecular Formula: C8H6BrNO
Formula Weight: 212.04
MOL File: 867366-91-4.mol

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3-BROMO-5-METHOXY BENZONITRILE Property

Boiling point:: 253.5±25.0 °C(Predicted)
Density: 1.56±0.1 g/cm3(Predicted)
storage temp.: 2-8°C
form: crystalline solid
color: White

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Safety

RIDADR: UN3439
HazardClass: 6.1
HS Code: 2926907090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Warning
Precautionary statements: P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC

Product number: B699480
Product name: 3-Bromo-5-methoxybenzonitrile
Packaging: 10mg
Price: $45
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4637-9-Y7
Product name: 3-Bromo-5-methoxybenzonitrile
Purity: 99%
Packaging: 1g
Price: $47
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB139554
Product name: 3-Bromo-5-methoxybenzonitrile
Packaging: 1g
Price: $55
Updated: 2021/12/16

AK Scientific

Product number: J55584
Product name: 3-Bromo-5-methoxybenzonitrile
Packaging: 5g
Price: $63
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB139554
Product name: 3-Bromo-5-methoxybenzonitrile
Packaging: 2g
Price: $95
Updated: 2021/12/16

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3-BROMO-5-METHOXY BENZONITRILE Chemical Properties,Usage,Production

Synthesis

867366-90-3

867366-91-4

The general procedure for the synthesis of 3-bromo-5-methoxybenzonitrile from the compound (CAS:867366-90-3) is as follows: a mixed solution of aldehyde 180b (12.0 g, 56 mmol), hydroxylamine hydrochloride (19.4 g, 5 eq.), ethanol (100 mL), and pyridine (10 mL) was heated to 65 °C and reacted for 16 hours. After completion of the reaction, the mixture was cooled to room temperature and extracted by partitioning with 50% ethyl acetate/hexane and water. The organic layer was washed with brine and dried with magnesium sulfate. After evaporation of the volatiles, 12.4 g of the oxime product was obtained (97% yield). The resulting oxime was dissolved in anhydrous dioxane (100 mL) and pyridine (26 mL, 6 eq.), the solution was cooled to 0 °C and trifluoroacetic anhydride (15 mL, 2 eq.) was added slowly. Subsequently, the mixture was gradually warmed to room temperature and stirred continuously for 2 days. After that, the reaction solution was heated to 60 °C and kept for 1 hour. After completion of the reaction, the mixture was cooled to room temperature and carefully poured into ice water. The mixture was extracted with dichloromethane and the combined organic layers were washed sequentially with water, 1 M hydrochloric acid and brine. The organic layer was dried over magnesium sulfate and the solvent was evaporated to give the target product 180c 10.4 g (90% yield).

References

[1] Patent: US2005/239881, 2005, A1. Location in patent: Page/Page column 47-48
[2] Patent: US2008/20981, 2008, A1. Location in patent: Page/Page column 19
[3] Patent: US2008/45511, 2008, A1. Location in patent: Page/Page column 21
[4] Patent: US2008/293664, 2008, A1. Location in patent: Page/Page column 16
[5] Patent: US2008/249151, 2008, A1. Location in patent: Page/Page column 21

3-BROMO-5-METHOXY BENZONITRILE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 3-BROMO-5-METHOXY BENZONITRILE manufacturers

Career Henan Chemical Co

Product: 3-BROMO-5-METHOXY BENZONITRILE 867366-91-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2019-12-30

867366-91-4, 3-BROMO-5-METHOXY BENZONITRILERelated Search:

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867366-91-4

867336-91-4