2-Amino-6-methylbenzoic acid methyl ester
- Product Name
- 2-Amino-6-methylbenzoic acid methyl ester
- CAS No.
- 18595-13-6
- Chemical Name
- 2-Amino-6-methylbenzoic acid methyl ester
- Synonyms
- methyl 6-amino-2-methylbenzoate;Methyl 2-aMino-6-Methylbenzoate;2-Amino-6-methylbenzoic acid methyl ester;Benzoic acid, 2-aMino-6-Methyl-, Methyl ester;Methyl 6-methylanthranilate, Methyl 6-amino-o-toluate
- CBNumber
- CB22282116
- Molecular Formula
- C9H11NO2
- Formula Weight
- 165.19
- MOL File
- 18595-13-6.mol
2-Amino-6-methylbenzoic acid methyl ester Property
- Boiling point:
- 257.2±20.0 °C(Predicted)
- Density
- 1.132±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- pka
- 2.32±0.10(Predicted)
- Appearance
- Light yellow to yellow Liquid
Safety
- HS Code
- 2922498590
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P330Rinse mouth.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- M331758
- Product name
- Methyl2-Amino-6-methylbenzoate
- Packaging
- 500mg
- Price
- $130
- Updated
- 2021/12/16
- Product number
- J94419
- Product name
- Methyl2-amino-6-methylbenzoate
- Packaging
- 25g
- Price
- $680
- Updated
- 2021/12/16
- Product number
- CHM0094557
- Product name
- 2-AMINO-6-METHYL-BENZOIC ACID METHYL ESTER
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $824.67
- Updated
- 2021/12/16
- Product number
- 4217AJ
- Product name
- Methyl2-amino-6-methylbenzoate
- Packaging
- 25g
- Price
- $870
- Updated
- 2021/12/16
- Product number
- CHM0094557
- Product name
- 2-AMINO-6-METHYL-BENZOIC ACID METHYL ESTER
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $1515.94
- Updated
- 2021/12/16
2-Amino-6-methylbenzoic acid methyl ester Chemical Properties,Usage,Production
Synthesis
61940-22-5
18595-13-6
General procedure for the synthesis of methyl 2-amino-6-methylbenzoate from methyl 2-methyl-6-nitrobenzoate: Methyl 2-methyl-6-nitrobenzoate (3.80 g, 19.5 mmol) was mixed with 10% palladium-carbon catalyst (1.03 g in 50% water) in methanol (20 mL) and the reaction was stirred for 1.5 h at 20-25 °C under hydrogen atmosphere. Upon completion of the reaction, the palladium-carbon catalyst was removed by filtration, followed by distillation under reduced pressure to remove the solvent to afford the target product methyl 2-amino-6-methylbenzoate (3.13 g, 97% yield). The product was characterized by 1H-NMR (CDCl3) with chemical shifts δ: 2.43 (3H, s), 3.88 (3H, s), 6.52 (1H, d, J=7.9 Hz), 6.54 (1H, d, J=7.9 Hz), 7.08 (1H, t, J=7.9 Hz).
References
[1] Chemical Communications, 2005, # 44, p. 5583 - 5585
[2] Chemistry - A European Journal, 2009, vol. 15, # 24, p. 5956 - 5968
[3] Patent: EP1844768, 2007, A1. Location in patent: Page/Page column 27
[4] Bulletin de la Societe Scientifique de Bretagne, 1956, vol. 31, p. Sonderheft S.9,41
[5] Patent: US2002/19414, 2002, A1
2-Amino-6-methylbenzoic acid methyl ester Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-Amino-6-methylbenzoic acid methyl ester manufacturers
- Product
- 2-Amino-6-methylbenzoic acid methyl ester 18595-13-6
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98
- Supply Ability
- KG
- Release date
- 2025-09-17
- Product
- Methyl 2-amino-6-methylbenzoate 18595-13-6
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 10000KG
- Release date
- 2024-11-09
- Product
- 2-Amino-6-methylbenzoic acid methyl ester 18595-13-6
- Price
- US $0.10/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 10
- Release date
- 2024-08-04