5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one

Product Name: 5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one
CAS No.: 2292-20-8
Chemical Name: 5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one
Synonyms: Muramine;Cryptopalmatine;5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one;Dibenz[c,g]azecin-13(6H)-one, 5,7,8,14-tetrahydro-3,4,10,11-tetramethoxy-6-methyl-
CBNumber: CB22286497
Molecular Formula: C22H27NO5
Formula Weight: 385.45
MOL File: 2292-20-8.mol

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5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one Property

Melting point:: 148-150 °C
Boiling point:: 555.6±50.0 °C(Predicted)
Density: 1.131±0.06 g/cm3(Predicted)
pka: 7.86±0.20(Predicted)

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Hazard and Precautionary Statements (GHS)

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5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one Chemical Properties,Usage,Production

Description

This alkaloid, sometimes referred to as cryptopalmine, occurs in Papaver nudi-cauZe L. and in Argernone rnunita Dur. & Hilg. subsp. rotunda. When crystallized from Me2CO it forms clusters of colourless crystals. It furnishes a crystalline hydriodide, m.p. 176-7°C (dec.) and a methiodide, m.p. 192-4°C. The struc_x0002_ture has been deduced from the mass spectrum and confirmed by synthesis.

Definition

ChEBI: Muramine is a dibenzazecine alkaloid that is 5,7,8,14-tetrahydrodibenzo[c,g]azecin-13(6H)-one substituted by a methyl group at position 6 and by methoxy groups at positions 3, 4, 10, and 11. It has a role as a plant metabolite. It is a dibenzazecine alkaloid, a tertiary amino compound and an aromatic ether.

References

Boit, Flentje., Naturwiss., 47, 180 (1960)
Preininger et aZ., PZanta Med., 10, 124 (1962)
Mass spectrum: Cross et aZ., Collect. Czech. Chern. Cornrnun., 30, 1335 (1965)
Synthesis: Haworth, Koepfli, Perkin., 1. Chern. Soc., 2261 (1927)
Giacopello, Deulofeu., Tetrahedron Lett., 2859 (1966)

5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one Preparation Products And Raw materials

Raw materials

Preparation Products

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5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one Suppliers

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2292-20-8, 5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-oneRelated Search:

5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one

Cryptopalmatine

Muramine

Dibenz[c,g]azecin-13(6H)-one, 5,7,8,14-tetrahydro-3,4,10,11-tetramethoxy-6-methyl-

2292-20-8