3-(BENZYLOXY)AZETIDINE BENZENESULFONATE

Product Name: 3-(BENZYLOXY)AZETIDINE BENZENESULFONATE
CAS No.: 897019-59-9
Chemical Name: 3-(BENZYLOXY)AZETIDINE BENZENESULFONATE
Synonyms: 3-phenylmethoxyazetidine;3-(Benzyloxy)azetidine, HCl;3-(PhenylMethoxy)-azetidine HCl;3-(BENZYLOXY)AZETIDINE BENZENESULFONATE;3-(Phenylmethoxy)-azetidinehydrochloride;3-(Benzyloxy)azetidine benzenesulfonic acid salt
CBNumber: CB22455358
Molecular Formula: C10H14ClNO
Formula Weight: 199.68
MOL File: 897019-59-9.mol

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3-(BENZYLOXY)AZETIDINE BENZENESULFONATE Property

storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
Appearance: White to off-white Solid
InChI: InChI=1S/C10H13NO.ClH/c1-2-4-9(5-3-1)8-12-10-6-11-7-10;/h1-5,10-11H,6-8H2;1H
InChIKey: BQTSSUSLZRYTQB-UHFFFAOYSA-N
SMILES: O(C1CNC1)CC1C=CC=CC=1.Cl

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Safety

HS Code: 2933998090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC

Product number: B288738
Product name: 3-(Benzyloxy)azetidinebenzenesulfonicacidsalt
Packaging: 500mg
Price: $285
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB119630
Product name: 3-(Benzyloxy)azetidine hydrochloride
Packaging: 100mg
Price: $72
Updated: 2021/12/16

ChemScene

Product number: CS-W006055
Product name: 3-(Benzyloxy)azetidinehydrochloride
Purity: >97.0%
Packaging: 1g
Price: $89
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB119630
Product name: 3-(Benzyloxy)azetidine hydrochloride
Packaging: 250mg
Price: $145
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB119630
Product name: 3-(Benzyloxy)azetidine hydrochloride
Packaging: 500mg
Price: $250
Updated: 2021/12/16

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3-(BENZYLOXY)AZETIDINE BENZENESULFONATE Chemical Properties,Usage,Production

Synthesis

1027995-71-6

897019-59-9

General procedure for the synthesis of 3-(benzyloxy)azetidine-1-carboxylic acid tert-butyl ester from 3-(benzyloxy)azetidine-1-carboxylic acid: tert-butyl ester of 3-(benzyloxy)azetidine-1-carboxylic acid (1.0 g) was placed in a round-bottomed flask, methanol-HCl solution (15 ml, 20%) was added, and the reaction was stirred for 1 h at room temperature. The reaction progress was monitored by thin layer chromatography (TLC). After completion of the reaction, the solvent was evaporated under reduced pressure to give the crude product as a white solid. The crude product was washed several times with ethyl acetate and dried thoroughly to afford the target compound 3-(benzyloxy)azetidine hydrochloride as a white solid in 92% yield, which can be used for subsequent reactions without further purification.

References

[1] Patent: WO2012/83246, 2012, A1. Location in patent: Page/Page column 46
[2] Patent: US9388164, 2016, B2. Location in patent: Page/Page column 74; 75
[3] Organic Letters, 2017, vol. 19, # 9, p. 2270 - 2273
[4] Patent: WO2017/202704, 2017, A1. Location in patent: Page/Page column 44; 45

3-(BENZYLOXY)AZETIDINE BENZENESULFONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-(BENZYLOXY)AZETIDINE BENZENESULFONATE Suppliers

China 61 India 1 United Kingdom 2 United States 4 Global 68

Chengdu J&B Technology Co., Ltd.

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897019-59-9, 3-(BENZYLOXY)AZETIDINE BENZENESULFONATERelated Search:

3-Phenoxy-azetidinehydrochloride 2-Methylazetidine HCl 3-[9-(((3-(carboxypropyl)[4-Methxylphenyl]sulfonyl)aMine)carboxyl]-10-acridiniuMyl)-1-propanesulfonate inner salt Ampicillin 3-ETHOXY-AZETIDINE HYDROCHLORIDE 3-(BENZYLOXY)AZETIDINE BENZENESULFONATE

3-(BENZYLOXY)AZETIDINE BENZENESULFONATE

3-(PhenylMethoxy)-azetidine HCl

3-(Benzyloxy)azetidine, HCl

3-(Phenylmethoxy)-azetidinehydrochloride

3-phenylmethoxyazetidine

3-(Benzyloxy)azetidine benzenesulfonic acid salt

897019-59-9

C10H13NOC6H6O3S