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ChemicalBook > CAS DataBase List > SHVO'S CATALYST

SHVO'S CATALYST

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Product Name
SHVO'S CATALYST
CAS No.
104439-77-2
Chemical Name
SHVO'S CATALYST
Synonyms
S CATALYST;Shvo Catalyst;SHVO'S CATALYST;SHVO'S CATALYST ISO 9001:2015 REACH;1-HYDROXYTETRAPHENYL-CYCLOPENTADIENYL(TE;trans-Bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II) |[Hermann’1-HYDROXYTETRAPHENYLCYCLOPENTADIENYL(TETRAPHENYL-2,4-CYCLOPENTADIEN-1-ONE)-HYDROTETRACARBONYLDIRUTHENIUM (II);1-HYDROXYTETRAPHENYLCYCLOPENTADIENYL(TETRAPHENYL-2,4-CYCLOPENTADIEN-1-ONE)-1-HYDROTETRACARBONYLDIRUTHENIUM(II);1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-u-hydrotetracarbonyldiruthenium(II);1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)
CBNumber
CB2246930
Molecular Formula
C62H41O6Ru25*
Formula Weight
1084.13
MOL File
104439-77-2.mol
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SHVO'S CATALYST Property

Melting point:
223-227 °C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
DMSO (Slightly)
form 
Powder
color 
orange
Water Solubility 
Soluble in water and polar organic solvents.
Sensitive 
Moisture Sensitive
Merck 
14,8483
CAS DataBase Reference
104439-77-2
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
2843.90.0000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
668281
Product name
1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)
Purity
98%
Packaging
100mg
Price
$65.6
Updated
2024/03/01
Sigma-Aldrich
Product number
668281
Product name
1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)
Purity
98%
Packaging
500mg
Price
$247
Updated
2024/03/01
TCI Chemical
Product number
H1322
Product name
1-Hydroxytetraphenylcylclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)
Packaging
100mg
Price
$119
Updated
2024/03/01
Alfa Aesar
Product number
046884
Product name
1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II), 98%
Packaging
0.5g
Price
$143
Updated
2024/03/01
Alfa Aesar
Product number
046884
Product name
1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II), 98%
Packaging
2g
Price
$438
Updated
2024/03/01
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SHVO'S CATALYST Chemical Properties,Usage,Production

Reactions

  1. In conjugation with lipase, ruthenium catalyst used in the asymmetric transformation of ketones and enol acetates into chiral acetates.
  2. Dynamic kinetic resolution resulting from the ruthenium catalyzed racemization of enzymatically- resolved substrates.
  3. Conversion of secondary amines to primary amines in the presence of ammonia.
  4. Co-catalyt for aerobic lactonization of diols. 

Uses

The Shvo catalyst is an organoruthenium compound that is used for transfer hydrogenation

Uses

Catalyst in organic syntheses for hydrogen transfers including disproportionation of aldehydes, reduction of ketones and aldehydes, oxidation and/or racemization of alcohols and amines.

SHVO'S CATALYST Preparation Products And Raw materials

Raw materials

Preparation Products

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SHVO'S CATALYST Suppliers

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104439-77-2, SHVO'S CATALYSTRelated Search:


  • 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II)
  • 1-Hydroxytetraphenylcylclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-Mu-hydrotetracarbonyldirutheniuM(II)
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  • Ruthenium,tetracarbonyl-m-hydro[(1,2,3,4,5-h)-1-hydroxylato-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl][(1,2,3,4,5-h)-1-hydroxy-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl]di-
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  • 1-HYDROXYTETRAPHENYLCYCLOPENTADIENYL(TETRAPHENYL-2,4-CYCLOPENTADIEN-1-ONE)-HYDROTETRACARBONYLDIRUTHENIUM (II)
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  • TETRACARBONYL-MU-HYDRO[(1,2,3,4,5-H)-1-HYDROXYLATO-2,3,4,5-TETRAPHENYL-2,4-CYCLOPENTADIEN-1-YL][(1,2,3,4,5-H)-1-HYDROXY-2,3,4,5-TETRAPHENYL-2,4-CYCLOPENTADIEN-1-YL]DIRUTHENIUM
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  • 1-hydroxytetraphenyl -cyclopentadienyl (tetraphenyl-2,4-cyclopentadien -one)-mu -hydrotetracarbonyldiruthenium(II)
  • SHVO'S CATALYST ISO 9001:2015 REACH
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  • 104439-77-2
  • C62H42O6Ru2
  • Catalysis and Inorganic Chemistry
  • Ru Catalysts
  • Ru