Reaction
ChemicalBook > CAS DataBase List > (2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate

(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate

Reaction
Product Name
(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
CAS No.
959395-10-9
Chemical Name
(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
Synonyms
Fe(R,R-PDP);Fe(S,S-PDP);White-Chen catalyst;[Fe(S,S-PDP)(CH3CN)2](SbF6)2;[Fe(R,R-PDP)(CH3CN)2](SbF6)2;(2S,2’S)-[N,N’-Bis(2-pyridylmethyl)]-2,2’-bipyrrolidinebis(acetonitrile)iron(II) Hexafluoroantimonate;(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate;(2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate;acetonitrile:hexafluoroantimony(1-):iron(2+):2-[[(2R)-2-[(2R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl]methyl]pyridine;(2S,2'S)-(-)-[N,N'-Bis(2-pyridylmethyl]-2,2'-bipyrrolidinebis(acetonitrile) iron(II) hexafluoroantimonate Fe(S,S-PDP) White-Chen Catalyst
CBNumber
CB22524290
Molecular Formula
C24H32F6FeN6Sb+
Formula Weight
696.16
MOL File
959395-10-9.mol
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(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Property

Melting point:
215-226 °C
form 
Powder
color 
purple
optical activity
[α]20/D 30.0 to 20.0°, c = 0.2 in acetonitrile
Sensitive 
air sensitive
CAS DataBase Reference
959395-10-9
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
26-0060
Product name
(2S,2'S)-(-)-[N,N'-Bis(2-pyridylmethyl]-2,2'-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Fe(S,S-PDP) White-Chen Catalyst
Packaging
100mg
Price
$86
Updated
2024/03/01
Strem Chemicals
Product number
26-0060
Product name
(2S,2'S)-(-)-[N,N'-Bis(2-pyridylmethyl]-2,2'-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Fe(S,S-PDP) White-Chen Catalyst
Packaging
500mg
Price
$383
Updated
2024/03/01
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(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Chemical Properties,Usage,Production

Reaction

Metal complex used in the iron-catalyzed, selective oxidation of C-H bonds.

reaction suitability

core: iron
reagent type: catalyst
reaction type: C-H Activation

(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Preparation Products And Raw materials

Raw materials

Preparation Products

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(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Suppliers

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959395-10-9, (2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonateRelated Search:


  • (2S,2'S)-(-)-[N,N'-Bis(2-pyridylmethyl]-2,2'-bipyrrolidinebis(acetonitrile) iron(II) hexafluoroantimonate Fe(S,S-PDP) White-Chen Catalyst
  • [Fe(S,S-PDP)(CH3CN)2](SbF6)2
  • Fe(S,S-PDP)
  • (2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
  • (2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
  • [Fe(R,R-PDP)(CH3CN)2](SbF6)2
  • Fe(R,R-PDP)
  • Iron(II) (R,R-(2-({(R)-2-[(R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine)(bis-acetonitrile) hexafluoroantimonate
  • White-Chen catalyst
  • acetonitrile:hexafluoroantimony(1-):iron(2+):2-[[(2R)-2-[(2R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl]methyl]pyridine
  • (2S,2''S)-(-)-[N,N''-Bis(2-pyridylmethyl]-2,2''-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Fe(S,S-PDP) White-Chen Catalyst
  • (2S,2’S)-[N,N’-Bis(2-pyridylmethyl)]-2,2’-bipyrrolidinebis(acetonitrile)iron(II) Hexafluoroantimonate
  • 959395-10-9
  • 2C2H3NC20H26N42F6SbFe