Reaction
ChemicalBook > CAS DataBase List > (R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX

(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX

Reaction
Product Name
(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX
CAS No.
890090-21-8
Chemical Name
(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX
Synonyms
(RA,S,S)-SPIROBOX;(Ra,S,S)-7,7′-bis(4′-phenyloxazol-2-yl)-1,1′-spirobiindane;(R)-7,7-Bis[(4S)-(phenyl)oxazol-2-yl)]-2,2,3,3-tetrahydro-1,1-spirobiindane;(R)-7,7'-Bis[(4S)-(phenyl)oxazol-2-yl)]-2,2'- 3,3'- tetrahydro-1,1 spirobiindane (Ra,S,S)-SpiroBOX;(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX;(4S,4'S)-2,2'-[(1R)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDENE]-7,7'-DIYL]BIS[4,5-DIHYDRO-4-PHENYLOXAZOLE];Oxazole,2,2'-[(1R)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[4,5-dihydro-4-phenyl-,(4S,4'S)-;(4S)-4-phenyl-2-[4'-[(4S)-4-phenyl-4,5-dihydro-1,3-oxazol-2-yl]-3,3'-spirobi[1,2-dihydroindene]-4-yl]-4,5-dihydro-1,3-oxazole
CBNumber
CB22528733
Molecular Formula
C35H30N2O2
Formula Weight
510.62
MOL File
890090-21-8.mol
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(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX Property

Melting point:
130-132°C
alpha 
+93.0° (c 0.5, CH2Cl2)
Boiling point:
712.1±60.0 °C(Predicted)
Density 
1.29±0.1 g/cm3(Predicted)
pka
4.12±0.70(Predicted)
form 
solid
color 
white
Sensitive 
moisture sensitive
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
07-5194
Product name
(R)-7,7-Bis[(4S)-(phenyl)oxazol-2-yl)]-2,2,3,3-tetrahydro-1,1-spirobiindane, min. 97% (Ra,S,S)-SpiroBOX
Packaging
25mg
Price
$65
Updated
2024/03/01
Strem Chemicals
Product number
07-5194
Product name
(R)-7,7-Bis[(4S)-(phenyl)oxazol-2-yl)]-2,2,3,3-tetrahydro-1,1-spirobiindane, min. 97% (Ra,S,S)-SpiroBOX
Packaging
100mg
Price
$191
Updated
2024/03/01
ChemScene
Product number
CS-0037007
Product name
(Ra,S,S)-SpiroBOX
Packaging
50mg
Price
$225
Updated
2021/12/16
ChemScene
Product number
CS-0037007
Product name
(Ra,S,S)-SpiroBOX
Packaging
25mg
Price
$116
Updated
2021/12/16
AK Scientific
Product number
2474AQ
Product name
(Ra,S,S)-SpiroBOX
Packaging
50mg
Price
$545.6
Updated
2021/12/16
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(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX Chemical Properties,Usage,Production

Reaction

  1. Chiral ligand for copper-catalyzed asymmetric insertions of carbenoids into N–H bond of anilines.
  2. Chiral ligand for copper-catalyzed asymmetric insertions of carbenoids into O–H bond of phenols.
  3. Chiral ligand for copper-catalyzed asymmetric insertions of carbenoids into O–H bond of water.
  4. Chiral ligand for copper-catalyzed asymmetric insertions of carbenoids into S–H bonds.
  5. Chiral ligand for copper-catalyzed asymmetric insertions of carbenoids into Si–H bonds.
  6. Chiral ligand used for enantioselective iron-catalyzed intramolecular cyclopropanations.
     


(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX Suppliers

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890090-21-8, (R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOXRelated Search:


  • Oxazole,2,2'-[(1R)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[4,5-dihydro-4-phenyl-,(4S,4'S)-
  • (Ra,S,S)-7,7′-bis(4′-phenyloxazol-2-yl)-1,1′-spirobiindane
  • (R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX
  • (RA,S,S)-SPIROBOX
  • (4S,4'S)-2,2'-[(1R)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDENE]-7,7'-DIYL]BIS[4,5-DIHYDRO-4-PHENYLOXAZOLE]
  • (R)-7,7'-Bis[(4S)-(phenyl)oxazol-2-yl)]-2,2'- 3,3'- tetrahydro-1,1 spirobiindane (Ra,S,S)-SpiroBOX
  • (R)-7,7-Bis[(4S)-(phenyl)oxazol-2-yl)]-2,2,3,3-tetrahydro-1,1-spirobiindane
  • (4S)-4-phenyl-2-[4'-[(4S)-4-phenyl-4,5-dihydro-1,3-oxazol-2-yl]-3,3'-spirobi[1,2-dihydroindene]-4-yl]-4,5-dihydro-1,3-oxazole
  • 890090-21-8