Methyl 4-amino-5-iodo-2-methylbenzoate

Product Name: Methyl 4-amino-5-iodo-2-methylbenzoate
CAS No.: 672293-33-3
Chemical Name: Methyl 4-amino-5-iodo-2-methylbenzoate
Synonyms: 187484;Methyl 4-amino-5-iodo-2-methylbenzoate;4-Amino-5-iodo-2-methyl-benzoic acid methyl ester;Benzoic acid, 4-amino-5-iodo-2-methyl-, methyl ester
CBNumber: CB22534945
Molecular Formula: C9H10INO2
Formula Weight: 291.09
MOL File: 672293-33-3.mol

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Methyl 4-amino-5-iodo-2-methylbenzoate Property

Boiling point:: 367.0±42.0 °C(Predicted)
Density: 1.733±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
pka: 0.53±0.10(Predicted)
Appearance: Light yellow to yellow Solid

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

AK Scientific

Product number: 4724DF
Product name: Methyl4-amino-5-iodo-2-methylbenzoate
Packaging: 1g
Price: $251
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0037325
Product name: METHYL 4-AMINO-5-IODO-2-METHYLBENZOATE
Purity: 95.00%
Packaging: 5G
Price: $909.56
Updated: 2021/12/16

Ambeed

Product number: A248886
Product name: Methyl4-amino-5-iodo-2-methylbenzoate
Purity: 97%
Packaging: 100mg
Price: $32
Updated: 2021/12/16

Ambeed

Product number: A248886
Product name: Methyl4-amino-5-iodo-2-methylbenzoate
Purity: 97%
Packaging: 250mg
Price: $62
Updated: 2021/12/16

Ambeed

Product number: A248886
Product name: Methyl4-amino-5-iodo-2-methylbenzoate
Purity: 97%
Packaging: 1g
Price: $163
Updated: 2021/12/16

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Methyl 4-amino-5-iodo-2-methylbenzoate Chemical Properties,Usage,Production

Synthesis

6933-47-7

672293-33-3

Methyl 2-methyl-4-aminobenzoate (Intermediate 7) (2.9 g, 16.6 mmol) was used as raw material and dissolved in DMF (15 ml), sodium periodate (1.45 g, 6.6 mmol) and iodine (3.4 g, 13.3 mmol) were added sequentially. The reaction mixture was stirred at a constant temperature at 50°C for 2 hours. After the reaction was completed, the mixture was slowly poured into cold water containing NaHSO3 (0.5 g). After stirring and mixing, the mixture was allowed to stand overnight. On the following day, the precipitate was collected by filtration, washed with water and subsequently dissolved with dichloromethane. The resulting solution was dried over anhydrous Na2SO4, filtered and concentrated under reduced pressure to afford the target product methyl 4-amino-5-iodo-2-methylbenzoate as an orange solid (4.1 g, 85% yield). The structure of the product was confirmed by 1H NMR (300 MHz, CDCl3): δ 8.20 (s, 1H), 6.47 (s, 1H), 3.75 (s, 3H), 2.42 (s, 3H).

References

[1] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 3, p. 942 - 945
[2] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 3, p. 946 - 949
[3] Patent: WO2009/47240, 2009, A1. Location in patent: Page/Page column 30
[4] Patent: US2018/291002, 2018, A1. Location in patent: Paragraph 0462; 0463
[5] Patent: US2004/142940, 2004, A1. Location in patent: Page/Page column 42

Methyl 4-amino-5-iodo-2-methylbenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 4-amino-5-iodo-2-methylbenzoate Suppliers

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672293-33-3, Methyl 4-amino-5-iodo-2-methylbenzoateRelated Search:

Methyl 4-amino-5-iodo-2-methylbenzoate

4-Amino-5-iodo-2-methyl-benzoic acid methyl ester

187484

Benzoic acid, 4-amino-5-iodo-2-methyl-, methyl ester

672293-33-3